Superhydrophobic MWCNTs/PDMS-nanocomposite materials: Preparation and characterization

• Autorzy: Sulym Iryna , Kubiak Adam , Jankowska Katarzyna , Sternik Dariusz , Terpilowski Konrad , Sementsov Yuriy , Borysenko Mykola , Derylo-Marczewska Anna , Jesionowski Teofil

Identyfikatory

DOI

10.5277/ppmp19057

• Języki publikacji: EN

Abstrakty

EN

The surface morphology, structure and hydrophobicity of low-and high-molecular weight poly(dimethylsiloxane) (PDMS) fluids physically adsorbed onto multi-walled carbon nanotubes (MWCNTs) at different weight percentages (5, 10, 20 and 40 wt.%), were studied employing X-ray diffraction (XRD), attenuated total reflectanceFouriertransforminfrared spectroscopy (ATR-FTIR), scanning electron microscopy (SEM) and measurements of contact angle with water. It was found that MWCNTs agglomerate forming voids between tubes of a broad range, while adsorption of the polymer from a hexane solution results in the expected wrapping of nanotubes withPDMS chains and, further, in filling voids, as represented by SEM data. ATR-FTIR was used to investigate the possible structural changes in the polymer nanocomposites. Based on the contact anglemeasurementsvia water drop shape analysis,MWCNTs/PDMS nanocomposites were characterizedas astable,superhydrophobic materials with the maximum contact angle (CA) equal to 152°at C_PDMS=40wt.%.

Słowa kluczowe

EN

poly(dimethylsiloxane); carbon nanotube; polymer nanocomposites; superhydrophobicity

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2019
• Tom: Vol. 55, iss. 6
• Strony: 1394--1400
• Opis fizyczny: Bibliogr. 25 poz., rys.

Twórcy

autor

Sulym Iryna

• Chuiko Institute of Surface Chemistry of NASU, 17 General Naumov Str., 03164 Kyiv, Ukraine

autor

Kubiak Adam

• Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Berdychowo 4, PL-60965 Poznan, Poland

autor

Jankowska Katarzyna

• Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering,Berdychowo 4, PL-60965 Poznan, Poland

autor

Sternik Dariusz

• Maria Curie-Sklodowska University, Faculty of Chemistry, M.Curie-Sklodowska Sq.3, PL-20031 Lublin, Poland

autor

Terpilowski Konrad

• Maria Curie-Sklodowska University, Faculty of Chemistry, M.Curie-Sklodowska Sq.3, PL-20031 Lublin, Poland

autor

Sementsov Yuriy

• Chuiko Institute of Surface Chemistry of NASU, 17 General Naumov Str., 03164 Kyiv, Ukraine

autor

Borysenko Mykola

• Chuiko Institute of Surface Chemistry of NASU, 17 General Naumov Str., 03164 Kyiv, Ukraine

autor

Derylo-Marczewska Anna

• Maria Curie-Sklodowska University, Faculty of Chemistry, M.Curie-Sklodowska Sq.3, PL-20031 Lublin, Poland

autor

Jesionowski Teofil

• Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Berdychowo 4, PL-60965 Poznan, Poland

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Uwagi

1. Polish Ministry of Science and Higher Education (Grant No. 03/32/SBAD/0906)

2. Visegrad Fund (Contract number 51910525)

3. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).