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Purpose: Nitrides are compound semiconductor nanomaterials that are suitable for use in light-emitting diodes. It has been desired to grow high quality gallium nitride crystal thin film on silicon substrates because silicon substrates have the advantages of low cost, large wafer size, and good electrical and thermal conductivity. However, the higher defect density can limit the industrial applications due to lower quantum efficiency. The purpose of this study has been to investigate the crystal defect structure within InGaN/GaN multiple quantum wells on Si(111) substrates. In addition, the variation in quantum well thickness was also explained by the selective area growth model. Design/methodology/approach: InGaN/GaN nano-structures were prepared by metal-organic chemical vapor phase epitaxy (MOVPE) using composite buffer layers. The crystal defect structures in the buried multiple quantum wells on both (0001) and {10-11} sidewalls were carefully studied by transmission electron microscopy. Previous studies on sapphire substrates have been compared and discussed. Findings: The V defect structures have been found in InGaN/GaN multiple quantum wells on Si(111) substrates. A simplified structural model with increasing barrier thickness has been reported. The barrier thickness increased on both (0001) and {10-11} facets along thin film growth. A decreased fill factor based on the selective area growth model was proposed. In addition, the average thin film growth rate was found to be four times higher along (0001) than that along {10-11} facet. As the number of multiple quantum wells increased, the barier thickness increasing was also intensified. Research limitations/implications: The understanding in defect structure could help to modify the processing and design parameters. Originality/value: The V-defect structure and model were reported for the first time using silicon substrates. The different growth rates along defect structures were quantified. High quality gallium nitride crystal could be manufactured along with better substrate design.
Wydawca
Rocznik
Tom
Strony
195--198
Opis fizyczny
Bibliogr. 13 poz., rys., tab., wykr.
Twórcy
autor
- Advanced Materials Laboratory and Institute of Electro-Optical Engineering, Chang Gung University, Kweisan, Taoyuan 333, Taiwan R.O.C.
autor
- Advanced Materials Laboratory and Institute of Electro-Optical Engineering, Chang Gung University, Kweisan, Taoyuan 333, Taiwan R.O.C.
Bibliografia
- [1] A. Cahill and M. A. El Baradie, LED-based fibre-optic sensor for measurement of surface roughness, Journal of Material Processing Technology, 119 (2001) 299-306.
- [2] A. N. Gulluoglu and C. T. Tsai, Dislocation generation in GaAs crystals grown by the vertical gradient freeze method, Journal of Material Processing Technology, 102 (2000) 179-187.
- [3] N. Subramanyam and C. T. Tsai, Dislocation reduction in GaAs crystal grown from the Czochralski process, Journal of Material Processing Technology, 55 (1995) 278-287.
- [4] G. M. Wu and T. H. Hsieh, Crystal quality and electrical properties of p-type GaN thin film on Si(111) substrate by metal-organic chemical vapor deposition MOCVD, Journal of Material Processing Technology, (2006) in press.
- [5] G. Cong, Y. Lu, W. Peng, X. Liu, X. Wang and Z. Wang, Design of the low temperature AlN interlayer for GaN grown on Si (111) substrate, Journal of Crystal Growth, 276 (2005) 381-388.
- [6] X. H. Wu, C. R. Elsass, A. Abare, M. Mack, S. Keller, P. M. Petroff, S. P. Denbaars, J. S. Speck and S. J. Rosner, Structural origin of V-defects and correlation with localized excitonic centers in InGaN/GaN multiple quantum wells, Applied Physics Letters, 72 (1998) 692-694.
- [7] N. Duxbury, U. Bangert, P. Dawson, E. J. Thrush, W. van der Stricht, K. Jacobs and I. Moerman, Indium segregation in InGaN quantum-well structures, Applied Physics Letters, 76 (2000) 1600-1602.
- [8] K. Watanabe, J. R. Yang, S. Y. Huang, K. Inoke, J. T. Hsu, R. C. Tu, T. Yamazaki, N. Nakanishi and M. Shiojiri, Formation and structure of inverted hexagonal pyramid defects in multiple quantum wells InGaN/GaN, Applied Physics Letters, 82 (2003) 718-720.
- [9] N. Sharma, P. Thomas, D. Tricker and C. Humphreys, Chemical mapping and formation of V-defects in InGaN multiple quantum wells, Applied Physics Letters, 77 (2000) 1274-1276.
- [10] S. J. Lee, S. H. Jang, S. S. Lee and C. R. Lee, Growth and characterization of In0.28Ga0.72N/GaN multiple-quantum wells on Si(111), Journal of Crystal Growth, 249 (2003) 65-71.
- [11] C. J. Sun, M. Z. Anwar, Q. Chen, J. W. Yang, M. A. Khan, M. S. Shur, A. D. Bykhovski, Z. Liliental-Weber, C. Kisielowski, M. Smith, J. Y. Lin and H. X. Xiang, Quantum shift of band-edge stimulated emission in InGaN-GaN multiple quantum well light-emitting diodes, Applied Physics Letters, 70 (1997) 2978-2980.
- [12] J. S. Im, H. Kollmer, J. Off, F. Scholz and A. Hangleiter, Carrier confinement in GaInN/AlGaN/GaN quantum wells with asymmetric barriers: direction of the piezoelectric field, Materials Science and Engineering B: Solid-State Materials for Advanced Technology, 59 (1999) 315-318.
- [13] S. Mahanty, M. Hao, T. Sugahara, R. S. Q. Fareed, Y. Morishima, Y. Naoi, T. Wang and S. Sakai, V-shaped defects in InGaN/GaN multiquantum wells, Materials Letters, 41 (1999) 67-71.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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