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The article presents the results of research on the processing of such wastes of titanium-magnesium production as sludge from sludge dumps and fine dump dusts from the electric smelting of ilmenite concentrates. The results of nitric acid leaching of sludge with the transfer of calcium into solution and the production of calcium nitrate are given. Titanium-containing cake after nitric acid leaching of sludge and electric smelting dust cannot be returned to the technological process due to its high silica content, so the silicon impurity was removed from their composition. Silicon removal was performed by fluoroammonium processing with sublimation of hexafluorosilicate compounds. An amorphous silicon dioxide product was obtained, after ammonia hydrolysis of silicon-containing sublimations and appropriate treatment of the sediment. The residue from the sublimation of silicon fluorides consists mainly of titanium-containing phases and can be suitable for return for electrofusion after ammonia treatment.
Czasopismo
Rocznik
Tom
Strony
215--225
Opis fizyczny
Bibliogr. 31 poz., rys., tab.
Twórcy
autor
- Institute of Metallurgy and Ore Benefication, Satbayev University, JSC, Shevchenko St., 29/133, KR 050010, Almaty, Kazakhstan
autor
- Institute of Metallurgy and Ore Benefication, Satbayev University, JSC, Shevchenko St., 29/133, KR 050010, Almaty, Kazakhstan
autor
- Institute of Metallurgy and Ore Benefication, Satbayev University, JSC, Shevchenko St., 29/133, KR 050010, Almaty, Kazakhstan
autor
- Institute of Metallurgy and Ore Benefication, Satbayev University, JSC, Shevchenko St., 29/133, KR 050010, Almaty, Kazakhstan
autor
- Institute of Metallurgy and Ore Benefication, Satbayev University, JSC, Shevchenko St., 29/133, KR 050010, Almaty, Kazakhstan
Bibliografia
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- 2. Akcil A., Karshigina Z.B., Bochevskaya Y.G., Abisheva Z.S. 2018. Conditions of nitric acid treatment of phosphorus slag for REMs recovery and production of precipitated silicon dioxide. Kompleksnoe Ispolʹzovanie Mineralʹnogo syrʹâ, 305(2), 28–38. https://doi.org/10.31643/2018/6445.4
- 3. Andreev A.A., Dyachenko A.N. 2009. Method of processing of raw materials containing titanium. Patent RU 2365647. 2009-08-27.
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- 8. Chervony I.F., Listopad D.A., Ivashchenko V.I., Sorokina L.V. 2008. On the physical and chemical laws of the formation of titanium sponge. Scientific works “Donetsk National Technical University”. Metallurgy, Donetsk, 10(141), 37–46. (in Russian)
- 9. Diachenko A.N. 2006. Fluoroammonium method for producing titanium dioxide. Technical science. Bulletin of Tomsk Polytechnic University, Tomsk, 309(3), 99–102.
- 10. Dmitriev A.N., Smorokov A.A., Kantaev A. S. 2021. Fluoroammonium method of titanium slag processing. Ferrous metallurgy, 64(3), 178–183. (in Russian)
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- 12. Gao F., Nie Z., Yang D., Sun B., Liu Y., Gong X., Wang Z. 2018. Environmental impacts analysis of titanium sponge production using Kroll process in China. Journal of Cleaner Production, 174, 771–779. DOI: 10.1016/j.jclepro.2017.09.240
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- 14. Helmboldt I.N., Ganin E.V., Sergienko V.S., Minacheva L.Kh. 2004. An unusual way to obtain and the crystal structure of hydroxonium hexafluorosilicate - the simplest “hydrate” of fluorosilicic acid. Coordinating chemistry, 30(9), 720. (in Russian)
- 15. Jorjani E., Bagherieh A.H., Chelgani S.C. 2011. Rare earth elements leaching from Chadormalu apatite concentrate: Laboratory studies and regression predictions. Korean Journal of Chemical Engineering, 28(2), 557–562.
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- 21. Monir A.M., Nabawia Mohammed A. 1999. Recovery of lanthanides from Abu Tartur phosphate rock, Egypt. Hydrometallurgy, 52, 199–206.
- 22. Mukhanova A., Tussupbayev N., Turysbekov D., Yessengaziyev A. 2022. Improvement of the selection technology of copper-molybdenum concentrate with the use of modified flotoragents. Metalurgija, 1, 221–224.
- 23. Nasekan Y.P., Chervony I.F., Kolyada V.P., Mezentseva E.V. 2011. On the hydrochemical opening of silica from kaolin by the fluoride method. Metallurgist, 5, 25–30. (in Russian)
- 24. Ospanov K., Kuldeyev E., Kenzhaliyev B., Korotunov A. 2022. Wastewater Treatment Methods and Sewage Treatment Facilities in Almaty, Kazakhstan. Journal of Ecological Engineering, 23(1), 240–251. https://doi.org/10.12911/22998993/143939
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- 27. Teploukhov A.S. 2005. Prevention of water bodies pollution by waste products of titanium-magnesium production. Abstract of diss. cand. tech. Sciences, Ural State Forest Engineering University, Yekaterinburg, 143. (in Russian)
- 28. Ultarakova А., Kenzhaliyev B., Onayev M., Yessengaziyev A., Kassymzhanov K. 2019. Investigations of Waste Sludge of Titanium Production and Its Leaching by Nitric Acid. 19th International Multidisciplinary Scientific GeoConference, Science and Technologies in Geology, Exploration and Mining – SGEM 2019. Albena, Bulgaria 2019, 19(1.3), 861–868.
- 29. Weintraub G. 1912. Process of obtaining titanic oxid. US Patent 1014793A. IPC C22B34/125 (EP, US); Y10S423/02 (EP), 1912-01-16.
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- 31. Yessengaziyev A., Ultarakova А., Lokhova N., Karshigina Z., Kassymzhanov K. 2021. Study of the Alkaline Treatment Effect on Separation of Silica from the Electric Melting Dust of Ilmenite Concentrates. XXIth International Multidisciplinary Scientific GeoConference, Science and Technologies in Geology, Exploration and Mining – SGEM 2021. Albena, Bulgaria 2021, 1.1, 601-609. DOI: 10.5593/sgem2021/1.1/s04.073
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-da83a5d6-6cb2-47d8-80ee-d7684a5a99c8