Microwave Assisted Synthesis and Characterization of Glycidyl Azide Polymers Containing Different Initiating Diol Units

• Autorzy: Kshirsagar A. , Gite V. , Hundiwale D. , Mahulikar P.
• Języki publikacji: EN

Abstrakty

EN

Glycidyl azide polymers (GAPs), containing different initiating diol units were prepared by treating the corresponding poly(epichlorohydrins) (PECHs) with sodium azide under microwave irradiation (600 W power) at 80 °C, during 12 min. The PECHs containing different diol units were synthesized by the polymerization of epichlorohydrin using borontrifluoride etherate as initiator in the presence of small amounts of low molecular weight diols. The synthesized PECHs and GAPs, containing different initiating diol units, were characterized by various spectroscopic techniques and by thermal analysis (DSC). These results are reported and discussed.

Słowa kluczowe

EN

glycidyl azide polymer; poly(epichlorohydrin); cationic ring opening polymerization; microwave irradiation; thermal properties

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2015
• Tom: Vol. 12, no. 4
• Strony: 757--767
• Opis fizyczny: Bibliogr. 21 poz., rys., tab.

Twórcy

autor

Kshirsagar A.

• School of Chemical Sciences, North Maharashtra University, P.B. No.80, Jalgaon − 425 001, (M.S.) India

autor

Gite V.

• School of Chemical Sciences, North Maharashtra University, P.B. No.80, Jalgaon − 425 001, (M.S.) India

autor

Hundiwale D.

• School of Chemical Sciences, North Maharashtra University, P.B. No.80, Jalgaon − 425 001, (M.S.) India

autor

Mahulikar P.

• School of Chemical Sciences, North Maharashtra University, P.B. No.80, Jalgaon − 425 001, (M.S.) Indi

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