Simultaneous determination of 11 preservatives in cosmetics and pharmaceuticals by matrix solid-phase dispersion coupled with gas chromatography

• Autorzy: Liu Yun-feng , Zhang Jia-ling , Nie Xue-fei , Zhang Ping , Yan Xiao-qing , Fu Ke-feng

Identyfikatory

DOI

10.1556/1326.2019.00700

• Języki publikacji: EN

Abstrakty

EN

A convenient method was developed for simultaneous determination of 11 preservatives in cosmetics and pharmaceuticals. Matrix solid-phase dispersion had been optimized as the sample pretreatment technology, using Florisil as a dispersant, anhydrous sodium sulfate as a dehydrant, formic acid as an additive, and n-hexane and ethyl acetate as eluents successively, and followed by gas chromatography–flame ionization detection on a TR-5 capillary column. Experimental results showed that 11 preservatives were baseline separated within 22 min. Good linearities were observed in the concentration range of 0.53–250 μg/mL for all analytes, and there were also minor differences. All correlation coefficients (r) were more than 0.995. The average recoveries at 3 levels of spiked samples ranged from 80% to 124% with 0.9–12% intra-day RSD and 1.8–12% inter-day RSD. The limits of detection were less than 0.18 μg/mL for all analytes. Besides, there was no obvious matrix effect on the analytes. The conclusion was that the developed method was simple, cheap, accurate, precise, and environment-friendly, in addition to existing little matrix effects. It could be recommended to determine 11 preservatives individually or in any their combinations to not only in liquid and gel cosmetics but also in liquid medicine and ointment.

Słowa kluczowe

EN

matrix solid-phase dispersion; gas chromatography; cosmetics; pharmaceuticals

• Wydawca: University of Silesia in Katowice ; Akademiai Kiado
• Czasopismo: Acta Chromatographica
• Rocznik: 2020
• Tom: Vol. 32, no. 3
• Strony: 203--209
• Opis fizyczny: Bibliogr. 29 poz., rys.

Twórcy

autor

Liu Yun-feng

• Shanxi Medical University, No. 56 Xinjian South Road, Taiyuan 030001, Shanxi, China

autor

Zhang Jia-ling

• Shanxi Medical University, No. 56 Xinjian South Road, Taiyuan 030001, Shanxi, China

autor

Nie Xue-fei

• Shanxi Medical University, No. 56 Xinjian South Road, Taiyuan 030001, Shanxi, China

autor

Zhang Ping

• Shanxi Medical University, No. 56 Xinjian South Road, Taiyuan 030001, Shanxi, China

autor

Yan Xiao-qing

• Shanxi Medical University, No. 56 Xinjian South Road, Taiyuan 030001, Shanxi, China

autor

Fu Ke-feng

• Shanxi Medical University, No. 56 Xinjian South Road, Taiyuan 030001, Shanxi, China

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Uwagi

PL

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).