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This paper is a part of a natural dye solar cell project. Conductive transparent oxide (CTO) films have been deposited onto preheated glass substrates using a spray pyrolysis technique. The optical, electrical, structural properties as well as thermal annealing and gamma radiation response were studied. The average optical energy gap of doped films for direct allowed and direct forbidden transitions were found to be 3.92 and 3.68 eV, respectively. The plasmon frequency and plasmon energy after doping were found to be 3.48 x 1014 s-1 and 0.23 eV. The negative absorbance of the doped film was observed in UV-Vis range after applying both thermal annealing and ϒ-dose irradiation with 22 kGy. The negative refractive index of the doped film in UV range (220 – 300 nm) is promising for optical applications. The electron mobility μe reached a maximum of 27.4 cm2·V-1·s-1for Sb concentration of 10 %. The corresponding resistivity ρ and sheet resistance Rs reached their minimum values of 1.1 x 10-3 Ω·cm and 35 Ω·sq-1, respectively. The dopant concentration has been increased from 4.13 x 1019 to 2.1 x 1020cm-3. The doped film was found to exhibit three diffraction peaks associated with (2 2 2), (2 0 0), and (2 1 1) reflection planes, of which the peak of (2 2 2) of Sb2O3 and the peak of (2 0 0) were very close.
Słowa kluczowe
Wydawca
Czasopismo
Rocznik
Tom
Strony
62--72
Opis fizyczny
Bibliogr. 86 poz., rys.
Twórcy
autor
- National Center for Radiation Research and Technology, (NCRRT), EAEA, Cairo, Egypt
autor
- Cairo University, Faculty of Science, Physics Department, Giza, Egypt
autor
- Cairo University, Faculty of Science, Physics Department, Giza, Egypt
autor
- National Center for Radiation Research and Technology, (NCRRT), EAEA, Cairo, Egypt
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Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-da476bad-8524-4d4d-a15b-00b37efe7bef