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Solid heterogeneous rocket propellants (SHRPs) are increasingly used, mainly in the armaments industry. SHRPs are usually based on an inert binder - hydroxy-terminated polybutadiene (HTPB). The use of an inert polymer reduces the performance of the propellants, therefore this paper presents the preparation of propellants with different contents of the previously synthesized azide-HTPB and the results of research on their properties, such as density, calorific value, mechanical and thermal parameters and burning rate. An improvement in the tested parameters was noted in comparision to the properties of propellants without azide-HTPB. An increase in the calorific value of the propellants with the addition of azide-HTPB was noted, with a simultaneous reduction in the amount of oxidant in the SHRP composition. Azide-HTPB as a rocket propellant component has a significant impact on the mechanical properties of the propellant and also increases the propellant’s burning rate and the maximum pressure in the motor chamber.
Słowa kluczowe
Rocznik
Tom
Strony
392--407
Opis fizyczny
Bibliogr. 28 poz., rys., tab., wykr.
Twórcy
autor
- Warsaw University of Technology, Faculty of Chemistry, 3 Noakowskiego St., 00-664 Warsaw, Poland
autor
- Military Institute of Armament Technology, 7 Prym. Stefana Wyszyńskiego St., 05-220 Zielonka, Poland
autor
- Military Institute of Armament Technology, 7 Prym. Stefana Wyszyńskiego St., 05-220 Zielonka, Poland
autor
- Military Institute of Armament Technology, 7 Prym. Stefana Wyszyńskiego St., 05-220 Zielonka, Poland
Bibliografia
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- [5] DeLuca, L.T.; Galfetti, L.; Maggi, F.; Colombo, G.; Merotto, L.; Boiocchi, M.; Paravan, C.; Reina, A.; Tadini, P.; Fanton, L. Characterization of HTPB-based Solid Fuel Formulations: Performance, Mechanical Properties, and Pollution. Acta Astronaut. 2012, 92(2): 150-162;DOI: 10.1016/j.actaastro.2012.05.002.
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- [7] Florczak, B. Heterogeneous Solid Rocket Propellants on HTPB Rubber Base. (in Polish) Institute of Industrial Organic Chemistry, Warsaw, 2016, pp. 15-40; ISBN 9788391492246.
- [8] Ang, H.G.; Pisharath, S. Energetic Polymer. Binders and Plasticizers for Enhancing Performance. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2012, pp. 5-19; ISBN: 978-3-527-33155-0.
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- [11] Ashrafi, M.; Fakhraian, H.; Dehnavi, M.A. Synthesis, Characterization and Properties of Nitropolybutadiene as Energetic Plasticizer for NHTPB Binder. Propellants Explos. Pyrotech. 2017, 42(3): 269-275; DOI: 10.1002/prep.201600057.
- [12] Ghayeni, H.R.; Razeghi, R.; Kazemi, F.; Olyaei, A. An Efficient Synthesis, Evaluation of Parameters and Characterization of Nitro-Hydroxyl-Terminated Polybutadiene (Nitro-HTPB). Propellants Explos. Pyrotech. 2018, 43(6): 574-582; DOI: 10.1002/prep.201700315.
- [13] Ghayeni, H.R.; Razeghi, R.; Kazemi, F.; Olyaei, A. Synthesis and Characterization of Nitro-functionalized Hydroxyl-Terminated Polybutadiene Using N-Iodosuccinimide. Polym. Bull. 2020, 77: 4993-5004; DOI: 10.1007/s00289-019-03004-6.
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- [15] Florczak, B.; Bogusz, R.; Skupiński, W.; Chmielarek, M.; Dzik, A. Study of the Effect of Nitrated Hydroxyl-Terminated Polybutadiene (NHTPB) on the Properties of Heterogeneous Rocket Propellants. Cent. Eur. J. Energ. Mater. 2015, 12(4): 841-854.
- [16] Lillya, C.P.; Juang, R.H.; Chien, J.C. Synthesis of Azido-Polymers of Butadiene. J. Polym. Sci., Polym. Chem. Ed. 1982, 20(6): 1505-1516; DOI: 10.1002/pol.1982.170200612.
- [17] Pant, C.S.; Mada, S.S.N.M. Santosh; Mehilal; Banerjee, S.; Khanna, P.K. Synthesis of Azide Functionalized Hydroxyl-Terminated Polybutadiene. J. Energ. Mater. 2016, 34(4): 440-449; DOI: 10.1080/07370652.2015.1119915.
- [18] Ghayeni, H.R.; Razeghi, R.; Olyaei, A.; Roosta, S.T. An Efficient Synthesis of New Azide-Nitrato-Hydroxyl-Terminated Polybutadiene by NaN₃ and (NH₄)₂Ce(NO₃)₆. Propellants Explos., Pyrotech. 2018, 43(10): 1065-1069; DOI: 10.1002/prep.201800106.
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- [21] Sankar, R.M.; Roy, T.K.; Jana, T. Functionalization of Terminal Carbon Atoms of Hydroxyl Terminated Polybutadiene by Polyazido Nitrogen Rich Molecules. Bull. Mater. Sci. 2011, 34(4): 745-754; DOI: 10.1007/s12034-011-0190-5.
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- [26] Zieliński, W. Spectroscopic Methods and Their Application to the Identification of Organic Compounds. (in Polish) WNT, Warsaw, 1995, pp. 594-622; ISBN 83-204-1922-0.
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- [28] NATO, Standardization Agreement, STANAG 4147 Explosives, Chemical Compatibility with Munition Components (Non-nuclear Applications). 3rd Ed., 2001, pp. 12-16.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d9cb0eed-7d35-4bfc-8195-f5f18fd1f79c