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Effect of Magnet Scrap Size on the Extraction Behavior of Heavy Rare Earth Elements by Liquid Metal Extraction

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Języki publikacji
EN
Abstrakty
EN
Liquid metal extraction (LME) process results in 100% neodymium (Nd) extraction but the highest extraction efficiency reportedfor Dysprosium (Dy) so far is 74%. Oxidation of Dy is the major limiting factor for incomplete Dy extraction. In order to enhance the extraction efficiency and to further investigate the limiting factors for incomplete extraction, experiments were carried out on six different particle sizes of under 200 μm, 200-300 μm, 300-700 μm, 700-1000 μm, 1000-2000 μm and over 2000 μm at 900°C with magnesium-to-magnet scrap ratio of 15:1 for 6, 24 and 48 hours, respectively. This research identified Dy2 Fe17 in addition toDy2 O3 phase to be responsible for incomplete extraction. The relationship between Dy2 Fe17 and Dy2O3 phase was investigated, and the overall extraction efficiency of Dy was enhanced to 97%.
Twórcy
autor
  • Korea Institute for Rare Metals, Korea Institute of Industrial Technology, 12 Get-beol Rd., Songdo-dong, Incheon, 21999
  • Yonsei University, Department of Materials Science and Engineering, Seoul, 03722, Republic of Korea
  • Korea Institute for Rare Metals, Korea Institute of Industrial Technology, 12 Get-beol Rd., Songdo-dong, Incheon, 21999
  • Korea Institute for Rare Metals, Korea Institute of Industrial Technology, 12 Get-beol Rd., Songdo-dong, Incheon, 21999
  • Korea Institute for Rare Metals, Korea Institute of Industrial Technology, 12 Get-beol Rd., Songdo-dong, Incheon, 21999
autor
  • Yonsei University, Department of Materials Science and Engineering, Seoul, 03722, Republic of Korea
autor
  • Korea Institute for Rare Metals, Korea Institute of Industrial Technology, 12 Get-beol Rd., Songdo-dong, Incheon, 21999
  • University of Science and Technology, Daejeon, Republic of Korea
Bibliografia
  • [1] J. D. Widmer, R. Martin, M. Kimiabeigi, SM&T. 3, 7 (2015), DOI: 10.1016/j.susmat.2015.02.001.
  • [2] G. J. Simandl, C. Akam, S. Paradis, Which materials are ‘critical’ and ‘strategic’. in: Simandl, G. J. and Neetz, M., (Eds.), Symposium on Strategic and Critical Materials Proceedings 2015, British Columbia Ministry of Energy and Mines (2015).
  • [3] S. Kruse, K. Raulf, T. Pretz, B. Friedrich, J. Sustain. Metall. 3, 168 (2017).
  • [4] N. Haque, A. Hughes, S. Lim, C. Vernon, Resources 3, 614 (2014).
  • [5] T. H. Okabe, O. Takeda, K. Fukuda, Y. Umetsu, Mater. Trans. 44, 4, 798 (2003), DOI: 10.2320/matertrans.44.798
  • [6] Y. Xu, L. S. Chumbley, F. C. Laabs, J. Mat. Res. 15, 2296 (2000).
  • [7] H. J. Chae, Y. D. Kim, B. S. Kim, J. G. Kim, T. S. Kim, J. Alloys Compd. 586, 143 (2014).
  • [8] T. Akahori, Y. Miyamoto, T. Saeki, M. Okamoto, T. H. Okabe, J. Alloys Compd. 703, 337 (2017).
  • [9] H. W. Na, Y. H. Kim, H. T. Son, I. H. Jung, H. S. Choi, T. B. Kim, Curr. Nanosci. 10, 128 (2014).
  • [10] A. Takeychi, A. Inoue, Mater. Trans. 46, 2817, (2005).
Uwagi
EN
1. This research was supported by a grant from project of development of environment friendly pyrometallurgy process for high purity HREE and materialization (Project number: 20000970) by Korea evaluation Institute of Industrial Technology (KEIT) in Republic of Korea.
PL
2. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d9aa0e29-c787-4cd2-9983-970d89f825e3
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