Efficient method for Knoevenagel condensation in aqueous solution of amino acid ionic liquids (AAILs)

• Autorzy: Ossowicz P. , Rozwadowski Z. , Gano M. , Janus E.

Identyfikatory

DOI

10.1515/pjct-2016-0076

• Języki publikacji: EN

Abstrakty

EN

This work reports on the use of the amino acid ionic liquids (AAILs) which have been used as catalysts in Knoevenagel condensation of various aldehydes with malononitrile. For research we use tetrabutylammonium ionic liquids based on eight natural amino acids. The reaction was carried out in an aqueous medium. Using water as solvent provided efficient and simple method of isolation of pure product with high yield. Moreover, amino acid ionic liquid dissolved in water could be reused many times without any loss of its catalytic activity. The influence of the anion was studied. Moreover the effect of technological parameters such as: the temperature, the catalyst content, and the reaction time on yield of reaction were investigated.

Słowa kluczowe

EN

recycling; catalysis in water; amino acid ionic liquids; Knoevenagel reaction

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2016
• Tom: Vol. 18, nr 4
• Strony: 90--95
• Opis fizyczny: Bibliogr. 33 poz., rys., tab.

Twórcy

autor

Ossowicz P.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland

autor

Rozwadowski Z.

• West Pomeranian University of Technology, Szczecin, Department of Inorganic and Analytical Chemistry, al. Piastów 42, 70-065 Szczecin, Poland

autor

Gano M.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland

autor

Janus E.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, ul. Pulaskiego 10, 70-322 Szczecin, Poland

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).