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As heavy metals are commonly found in water bodies today, the need for an efficient method to remove these pollutants simultaneously has become increasingly important. This research involved coating sand with Fe/Ni nanoparticles created through an environmentally friendly method using eucalyptus leaf extract. Green synthesis of Fe/Ni coated sand was characterized using Fourier transform-infrared spectrometry (FT-IR) analysis. The resulting Fe/Ni nanocomposite coated sand was then used to copper (Cu(II)) removal from water in batch experiments. The study examined five factors namely pH of solution, Cu(II) concentration, contact time, Fe/Ni coated sand dosage, and agitation speed that affected on the Cu(II) removal efficiency. Optimal values of this factors were found to be 200 rpm, pH 6, 130 minutes, 50 mg/L for Cu(II), and 0.5 g/50 mL Fe/Ni coated sand. The findings revealed that over 80% of Cu(II) was removed until the fifth cycle. This work could open up new possibilities for treating water contaminated with copper ions using eco-friendly composites made from waste.
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219--224
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Bibliogr. 28 poz., rys., tab.
Twórcy
autor
- Department of Vocational Education of Babylon,Ministry of Education, Babylon, Iraq
- College of Dentistry, University of Karbala, Karbala, Iraq
autor
- Nursing Department, Al Safwa University College, Karbala, Iraq
autor
- College of Dentistry, Al-Farahidi University, Baghdad , Iraq
autor
- Chemical Engineering and Petroleum Industries Department, Al-Mustaqbal University, Babylon, Iraq
Bibliografia
- 1. Zamora-Ledezma, C., Negrete-Bolagay, D., Figueroa, F., Zamora-Ledezma, E., Ni, M., Alexis, F., Guerrero, V.H. 2021. Heavy metal water pollution: A fresh look about hazards, novel and conventional remediation methods. Environmental Technology & Innovation, 22, 101504.
- 2. Priti, P., Paul, B. 2016. Assessment of heavy metal pollution in water resources and their impacts: A review. Journal of Basic and Applied Engineering Research, 3(8), 671–675.
- 3. Zaynab, M., Al-Yahyai, R., Ameen, A., Sharif, Y., Ali, L., Fatima, M., Khan K.A., Li, S. 2022. Health and environmental effects of heavy metals. Journal of King Saud University-Science, 34(1), 101653.
- 4. Abd Ali, Z.T. 2021. Green synthesis of graphene-coated sand (GCS) using low-grade dates for evaluation and modeling of the pH-dependent permeable barrier for remediation of groundwater contaminated with copper. Separation Science and Technology, 56(1), 14–25.
- 5. Lin, Y., Jin, X., Owens, G., Chen, Z. 2019. Simultaneous removal of mixed contaminants triclosan and copper by green synthesized bimetallic iron/ nickel nanoparticles. Science of the total environment, 695, 133878.
- 6. Qin, Q., Wu, X., Chen, L., Jiang, Z., Xu, Y. 2018. Simultaneous removal of tetracycline and Cu (II) by adsorption and coadsorption using oxidized activated carbon. RSC advances, 8(4), 1744–1752.
- 7. Saleh, T.A., Ali, I. 2018. Synthesis of polyamide grafted carbon Environmental Chemical Engineermicrospheres for removal of rhodamine B dye and heavy metals. Journal of ing, 6(4), 5361–5368.
- 8. Gopal, G., Natarajan, C., Mukherjee, A. 2022. Synergistic removal of tetracycline and copper (II) by in-situ B-Fe/Ni nanocomposite—A novel and an environmentally sustainable green nanomaterial. Environmental Technology & Innovation, 25, 102187.
- 9. Weng, X., Sun, Q., Lin, S., Chen, Z., Megharaj, M., Naidu, R. 2014. Enhancement of catalytic degradation of amoxicillin in aqueous solution using clay supported bimetallic Fe/Ni nanoparticles. Chemosphere 103, 80– 85. https://doi.org/10.1016/j.chemosphere.2013.11.033
- 10. Gautam, R.K., Rawat, V., Banerjee, S., Sanroman, M.A., Soni, S., Singh, S.K., Chattopadhyaya, M.C. 2015. Synthesis of bimetallic Fe-Zn nanoparticles and its application towards adsorptive removal of carcinogenic dye malachite green and Congo red in water. J. Mol. Liq. 212, 227–236. https://doi.org/10.1016/j.molliq.2015.09.006
- 11. Fang, L., Xu, C., Zhang, W., Huang, L.-Z. 2018. The important role of polyvinylpyrrolidone and Cu on enhancing dechlorination of 2,4-dichlorophenol by Cu/Fe nanoparticles: performance and mechanism study. Appl. Surf. Sci. 435, 55–64. https://doi.org/10.1016/J.APSUSC.2017.11.084
- 12. Jiang, D., Huang, D., Lai, C., Xu, P., Zeng, G., Wan, J., Tang, L., Dong, H., Huang, B., Hu, T. 2018. Difunctional chitosan-stabilized Fe/Cu bimetallic nanoparticles for removal of hexavalent chromium wastewater. Sci. Total Environ. 644, 1181–1189. https://doi.org/10.1016/J.SCITOTENV.2018.06.367
- 13. Kadu, B.S., Wani, K.D., Kaul-Ghanekar, R., Chikate, R.C. 2017. Degradation of doxorubicin to non-toxic metabolites using Fe-Ni bimetallic nanoparticles. Chemical Engineering Journal, 325, 715–724.
- 14. Dong, H., Jiang, Z., Deng, J., Zhang, C., Cheng, Y., Hou, K., Zhang, L., Tang, L., Zeng, G. 2018a. Physicochemical transformation of Fe/Ni bimetallicnanoparticles during aging in simulated groundwater and theconsequent effect on contaminant removal. Water Research, 129, 51–57.
- 15. Lin, Y., Jin, X., Owens, G., Chen, Z. 2019. Simultaneous removal of mixed contaminants triclosan and copper by green synthesized bimetallic iron/ nickel nanoparticles. Science of the total environment, 695, 133878.
- 16. Xue, C., Cai, W., Weng, X., Owens, G., Chen, Z. 2021. A one step synthesis of hybrid Fe/Ni-rGO using green tea extract for the removal of mixed contaminants. Chemosphere, 284, 131369.
- 17. Hwang, Y.H., Kim, D.G., Shin, H.S. 2011. Effects of synthesis conditions on the characteristics and reactivity of nano scale zero valent iron, Appl. Catal. B. 105, 144–150.
- 18. Ravikumar, K.V.G., Sudakaran, S.V., Ravichandran, K., Pulimi, M., Natarajan, C., Mukherjee, A. 2019. Green synthesis of NiFe nano particles using Punica granatum peel extract for tetracycline removal. J. Clean. Prod. 210, 767–776. https://doi.org/10.1016/j.jclepro.2018.11.108
- 19. Ravikumar, K.V.G., Mrudula, P., Chandrasekaran, N., Amitava, M. 2020. In situ formation of bimetallic FeNi nanoparticles on sand through green technology: Application for tetracycline removal. Frontiers of Environmental Science & Engineering, 14, 1–13.
- 20. Rocha, V., Lago, A., Silva, B., Barros, Ó., Neves, I. C., Tavares, T. 2024. Immobilization of biogenic metal nanoparticles on sustainable materials–green approach applied to wastewater treatment: a systematic review. Environmental Science: Nano.
- 21. Gopal, G., Sankar, H., Natarajan, C., Mukherjee, A. 2020. Tetracycline removal using green synthesized bimetallic nZVI-Cu and bentonite supported green nZVI-Cu nanocomposite: A comparative study. Journal of Environmental Management, 254, 109812.
- 22. Osman, A.M., Hendi, A.H., Saleh, T.A. 2020. Simultaneous adsorption of dye and toxic metal ions using an interfacially polymerized silica/polyamide nanocomposite: Kinetic and thermodynamic studies. Journal of Molecular Liquids, 314, 113640.
- 23. Abd Ali, Z.T., Naji, L.A., Almuktar, S.A., Faisal, A.A., Abed, S.N., Scholz, M., Naushad M., Ahamad, T. 2020. Predominant mechanisms for the removal of nickel metal ion from aqueous solution using cement kiln dust. Journal of Water Process Engineering, 33, 101033.
- 24. Ezzat, M.N., Abd Ali, Z.T. 2022. Green approach for fabrication of graphene from polyethylene terephthalate (PET) bottle waste as reactive material for dyes removal from aqueous solution: Batch and continuous study. Sustainable Materials and Technologies, 32, e00404.
- 25. Ravikumar, K.V.G., Mrudula, P., Chandrasekaran, N., Amitava, M. 2020. In situ formation of bimetallic FeNi nanoparticles on sand through green technology: Application for tetracycline removal. Frontiers of Environmental Science & Engineering, 14, 1–13.
- 26. Jin, J., Yang, Z., Xiong, W., Zhou, Y., Xu, R., Zhang, Y., Cao, J., Li, X., Zhou, C. 2019. Cu and Co nanoparticles co-doped MIL-101 as a novel adsorbent for efficient removal of tetracycline from aqueous solutions. Science of the total environment, 650, 408–418.
- 27. Kango, S., Kumar, R. 2016. Magnetite nanoparticles coated sand for arsenic removal from drinking water. Environmental Earth Sciences, 75, 1–12.
- 28. Chen Y.-N., Chai L.-Y., and Shu Y.-D. 2008, Study of arsenic (V) adsorption on bone char from aqueous solution, Journal of Hazardous Materials, 160, 168–172.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d949ce57-347f-4fde-bfeb-86667dcfef2d