The 61Π u state of Na2 molecule

• Autorzy: Grochola A. , Kubkowska M. K. , Jastrzębski W. , Kowalczyk P.
• Języki publikacji: EN

Abstrakty

EN

Excitation spectra of sodium dimer were analysed within the range 34200–36400 cm–1. The experiment was done using polarisation labelling spectroscopy technique. In the spectral region under investigation we found several vibrational progressions belonging to a single band system having the ground state of Na2 as the lower state. The upper state was of 1Π u symmetry as indicated by the presence of Q lines in the spectrum and basing on theoretical calculations it was identified as the 61Π u (3s+4f ) state. The Dunham coefficients and potential curve characterising this state were deduced from the observed spectra.

Słowa kluczowe

EN

Na2 molecule; laser spectroscopy; electronic states; potential energy curves

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2006
• Tom: Vol. 36, nr 4
• Strony: s. 469--473
• Opis fizyczny: Bibliogr. 10 poz., rys., tab., wyk.

Twórcy

autor

Grochola A.

• Institute of Experimental Physics, Warsaw University, ul. Hoża 69, 00-681 Warszawa, Poland

autor

Kubkowska M. K.

• Institute of Experimental Physics, Warsaw University, ul. Hoża 69, 00-681 Warszawa, Poland

autor

Jastrzębski W.

• Institute of Physics, Polish Academy of Sciences, al. Lotników 32/46, 02-668 Warszawa, Poland

autor

Kowalczyk P.

• Institute of Experimental Physics, Warsaw University, ul. Hoża 69, 00-681 Warszawa, Poland

Bibliografia

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• [2] GROCHOLA A., Ph.D. Thesis, Warsaw University, Poland 2004.
• [3] GROCHOLA A., JASTRZĘBSKI W., KOWALCZYK P., New analysis of the D(4)1Πu state of Na2 using polarization labelling spectroscopy, Molecular Physics 104(15), 2006, pp. 2569–73.
• [4] LI J., ZHANG J., WANG H., KIM J.T., STWALLEY W.C., Observation of the 51Π u, and states of Na2 through a Franck–Condon window by all-optical triple resonance spectroscopy, Journal of Chemical Physics 109(1), 1998, pp. 102–7.
• [5] MAGNIER S., MILLIÉ Ph., DULIEU O., MASNOU-SEEUWS F., Potential curves for the ground and excited states of the Na2 molecule up to the (3s+5p) dissociation limit: Results of two different effective potential calculations, Journal of Chemical Physics 98(9), 1993, pp. 7113–25.
• [6] MAGNIER S., Ph.D. Thesis, Université Paris-Sud, France 1993.
• [7] JASTRZĘBSKI W., KOWALCZYK P., 31Π u and states of K2 studied by a polarization-labeling spectroscopy technique, Physical Review A 51(2), 1995, pp. 1046–51.
• [8] GROCHOLA A., JASTRZĘBSKI W., KOWALCZYK P., The C1Π u state of Na2 revisited: a comprehensive study by polarization labeling spectroscopy technique, Journal of Molecular Spectroscopy 232(2), 2005, pp. 291–5.
• [9] LEFEBVRE-BRION H., FIELD R.W., Perturbations in the Spectra of Diatomic Molecules, Academic Press, Orlando 1986.
• [10] GROCHOLA A., JASTRZĘBSKI W., KOWALCZYK P., The 31Π u state in Na2, Chemical Physics Letters, 394(4–6), 2004, pp. 383–6.