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Evaluation the Solidification/Stabilization of Heavy Metals by Portland Cement

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Numerous solutions are used in the site to treat pollution, including remediation of heavy metals and hazardous wastes by solidification/stabilization (S/S) with cement as a binder. S/S is one of the most commonly methods used for treating inorganic wastes. The objective of this research was using unconfined compressive strength test, and EPA Toxicity Leaching Procedure TCLP method 1313, to test the effectiveness performance, and efficiency of the solidification/stabilization method for treatment of some heavy metals (Fe, Zn, Mn, Cr) contaminated sands using ordinary locally produced Portland Cement type A. In this study, three loads of pollution in three mix designs by contaminated sands were used. As a result of the unconfined compression test, it was observed that the value 1–15 MPa with OPC cement content 25% in the solidification/stabilization process was good enough to comply with the limited value set by the (US EPA). In addition, the concentration of zinc ions was 500 kg/mg, 1500 kg/mg, and 3000 kg/mg, which caused an increase in compressive strength in the early period of age, and a decrease at a later age. An increase in the iron ion concentration caused an increase in the compressive strength at a later age, the effective retention percentages were (97, 93.5, 96 and 92) for iron, zinc, manganese and chromium ions, respectively, which exceeded 3000 mg/kg initially. The high effectiveness in holding and retaining metals within the matrix of solidification/stabilization at the particle size above 9.5 mm was found as well. The samples (Mn and Cr) with the low amount of cement in the mix treatment were not able to retain the required TCLP regulatory limits value, and the initial extraction pH 4.9. However, the final pH 9.5 is alkanet and stabilization effects of the cement matrix.
Rocznik
Strony
91--100
Opis fizyczny
Bibliogr. 30 poz., rys., tab.
Twórcy
  • Sanitary and Environmental Branch, University of Technology, 10009, Baghdad, Iraq
Bibliografia
  • 1. ASTM C31/C31M-09 (2009) Standard Practice for Making and Curing Concrete Test Specimens in the Field American Society for Testing and Materials.
  • 2. ASTM C39 / C39M-14a, Standard Test Method for Compressive Strength of Cylindrical Concrete Specimens, ASTM International, West Conshohocken, PA, 2014,
  • 3. Balamohan Balakrishnan, A.S.M. Abdul Awal, Abdul Halid B. Abdullah and M.Z. Hossain 2017. Flow Properties And Strength Behaviour Of Masonry Mortar Incorporating High Volume Fly Ash. International Journal of GEOMATE, March, 2017, Vol. 12, Issue 31, pp. 121-126, doi: http://dx.doi.org/10.21660/2017.31.19763.
  • 4. Bone, B.D. Barnard, L.H. Boardman, D,I,. Carey, P.J,. Hills, C,D,. Jones, H.M,. Macleod, C,. and Tyrer, M. 2004. Review of scientific literature on the use of stabilization/solidification for the treatment of contaminat soil, solid waste and sludges. Environment Agency, Bristol.
  • 5. Borowski G., Hycnar J.J. 2016. The effect of granulated fly ashes with phosphogypsum on the hardening of cement mortar. Technical Transactions – Civil Engineering, Vol. 113, Iss. 2-B (7), 37-45.
  • 6. Chen Q.Y., 2004. Examination of Hydrated and Accelerated Carbonated Cement - Heavy Metal Mixtures. P.hD. Thesis, University of Greenwich, London, UK.
  • 7. Chen Q.Y, Tyrer M., Hills C.D., Yang X.M. and Carey P. 2009. Immobilization Of Heavy Metals In Cement - Based Solidification / Stabilization: A review. Journal of Waste Management 29, 390-403.
  • 8. Cheng L., Wei Z., d Jie H. 2013. Strength and Leachability of Solidified Sewage Sludge With Different Additives. J. Matter Civ Eng, 25, 1594-1601.
  • 9. Cioffi R, Lavorgna M, Santoro L 2002. Environmental and technological effectiveness of a process for the stabilization of a galvanic sludge. J Hazard Mater B89(2–3),165–175.
  • 10. Conner J.R. and Hoeffner S.L. 1998. The history of stabilization/solidification technology. Crit. Rev. Env. Sci. Technol. 28, 325–396.
  • 11. Coz A, Andres A, Soriano S, Irabien A. 2004. Environmental behaviourof stabilised foundry sludge. J Hazard Mater B109(1–3), 95–104.
  • 12. EPA, 2014, National waste Management plan 2014-2020.
  • 13. Giergiczny Z., Król A. 2008. Immobilization of heavy metals (Pb, Cu, Cr, Zn, Cd, Mn) in the mineral additions containing concrete composites. J Hazard Mater. 160(2-3), 247-55. doi: 10.1016/j.jhazmat.2008.03.007.
  • 14. Hansen L.G and Chaney R.L. 1984. Environmental And Food Chain Effects Of The Agricultural Use Of Sewage Sludges. Rev Environ Toxicol, Vol. 1, 103-110.
  • 15. Kimbrough D.E., Cohen Y., Winer A.M., Creelman L., Mabuni C, 1999. A Critical Assessment of Chromium in the Environment. Crit Rev Environ Sci Technol 29(1), 1-46.
  • 16. Kitamura M., Konno H., Yasui A., Masuoka H. 2002. Controlling Factors and Mechanism of Reactive Crystallization of Calcium Carbonate Polmorphs from Calcium Hydroxide Suspension. Journal of Crystal Growth 236, 323-332.
  • 17. La Grega M.D., Buckingham P.L., Evans J.C., 1994. Hazardous Waste Management, McGrawHill, New York.
  • 18. Malviya R., Chaudhary R., 2006. Factors Affecting Hazardous Waste Solidification/Stabilization: A Review. Journal of Hazardous Materials 137, 267-276.
  • 19. Winter N.B., 2009. Understanding Cement: An Introduction to Cement Production, Cement Hydration and Deleterious Processes in Concrete. WHD Microanalysis Consultants Ltd Woodbridge, United Kingdom.
  • 20. NRC-U.S. Nuclear Regulatory Commission, 1991. Waste Forms Technical Position, Revision 1. U.S Nuclear Regulatory Commission. Washington .D.C.
  • 21. Yilmaz O., Unlu K., Cokca E. 2003. Solidification / Stabilization Of Hazardous Wastes Containing Metals And Organic Contaminants. J. Environ. Eng, 129, 366-376.
  • 22. Rijkenberg M.J., Depree C.V. 2010. Heavy Metal Stabilization in Contaminated Road-Derived Dediments. Sci Total Environ 408, 1212–1220.
  • 23. Russell C.H. 2004. Mechanics of Materials. 6th ed., Verlag: Prentice Hall .Germany.
  • 24. Silva MAR, Mater L, Souza-Sierra MM, Correˆa AXR, Sperb R, Radetski CM. 2007. Small hazardous waste generators in developing countries: use of stabilization/solidification process as an economic tool for metal wastewater treatment and appropriate sludge disposal. J Hazard Mater 147(3), 986–990.
  • 25. Shi C., Spence R., 2004. Designing of Cement - Based Formula for Solidification/Stabilization of Hazardous, Radioactive, and Mixed Wastes. Crit. Rev. Env. Sci.Technol. 34, 391-417.
  • 26. Tomasevic D.D., Dalmacija M.B., Prica M.D., Dalmacija B.D., Kerkez D.V., Bečelić-Tomin M.R., Roncevic S.D. 2013. Use of Fly Ash for Remediation of Metals Polluted sediment. Green Remediation. Chemosphere 92, 1490–1497.
  • 27. USEPA 1990, USEPA Method 1311, EPA 1990. Test method.
  • 28. U.S. EPA. 1992. Method 1311: toxicity characteristic leaching procedure. In EPA SW-846: test methods for evaluating solid waste, physical/chemical methods, July 1992.
  • 29. U.S EPA 2004. Treatment Technologies For Site Cleanup, Annual status report (eleventh edition), EPA-542-R-03-009.
  • 30. Wiles C.C., 1987. A Review of Solidification / stabilization technology. J. Haz. Mat., 14(1), 5-21.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d8941ba3-7e3e-4397-b924-b14a46904d34
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