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The influence of metal impurities to a-C:H films

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Warianty tytułu
PL
Wpływ metalowych zanieczyszczeń do filmów a-C:H
Języki publikacji
EN
Abstrakty
EN
The carbon coatings on the silicon substrate by chemical vapour phase precipitation as the insertion of platinum and copper impurities were observed in this paper. It was obtained that growing films are more polymeric like. The refractive index of all films are similar and varies from 1,6 to 1,75 and does not depend on nature of metal. Analysis of Raman spectra showed that typical for amorphous carbon G peaks become dominant and move to the lower means (from 1682 cm-¹ to approximately 1553 cm-1) and then metal impurities were introduced to the film. Also a new peak at about 1800 cm-¹ was obtained there. Typical D peak in films with platinum impurities is less intensive and disappears when Cu impurities are involved in film.
PL
Analizowano powłokę węglową na podłożu krzemowym poprzez chemiczne rozpuszczanie domieszek platyny i miedzi. Stwierdzono że współczynnik odbicia warstw był podobny dla wszystkich warstw i wynosił 1,6 do 1,75 niezależnie od domieszek. Spektralna analiza Ramanowska wykazała dominujące i zmniejszała się do ok 1553 cm-¹ przy wprowadzaniu domieszek
Rocznik
Strony
288--290
Opis fizyczny
Bibliogr. 16 poz., il., tab., wykr.
Twórcy
  • Physics Department, Kaunas University of Technology, Studentu 50, LT-51368, Kaunas Lithuania
autor
  • hysics Department, Kaunas University of Technology, Studentu 50, LT-51368, Kaunas Lithuania
  • hysics Department, Kaunas University of Technology, Studentu 50, LT-51368, Kaunas Lithuania
Bibliografia
  • [1] Kudoyarova V.Kh., Chernyshow A.V., Zvonareva T.K., Dzhelepova N.B., Tsolov M.B., Study of diamond–like carbon films for protective coatings, Surface and Coatings Technology, 100-101 (1998), 192-195
  • [2] Sun Z., Lin C.H., Lee L., Shi J.R., Tay B.K., Shi X. , Properties and structures of diamond-like carbon film deposited using He, Ne, Ar/methane mixture by plasma enhanced chemical vapor deposition, J. Appl. Phys., 87 (2000), No. 11, 8122-8129
  • [3] Kukielka S., Gulbiński W., Pauleau Y., Dub S.N., Grob J.J., Nikel/Hydrogenated amorphous carbon composite films deposited in acetylene/argon microwave plasma discharge, Rev. Adv. Mater. Sci., 15 (2007), 127-133
  • [4] Balden M., Adelhelm C., Köck T., Herrmann A., Jaimerena-Muga J., Thermal nanostructuring of metal–containing carbon films and their nanoindentation testing, Reviews on Advanced Materials Science, 15 (2007), 95-104
  • [5] Corbella C., Vives M., Pinyol A., Bertran E., Canal C., Polo M.C., Andújar J.L., Preparation of metal (W, Mo, Nb, Ti) containing a–C:H films by reactive magnetron sputtering, Surface and Coatings Technology, 177-178 (2004), 409-414
  • [6] Gampp R., Gantenbei n P., Oelhafen P., Preparation and characterization of chromium containing amorphous hydrogenated carbon films (a–C:H/Cr) Material research society Mat. Res. Soc. Symp. Proc., 388 (1995), 305-310
  • [7] Ionecu V., Lungu C.P., Osiac M., Ciupină V., Silver containing carbon amorphous nanocomposite films deposited by termionic vacuum arc technique, Rom. Journ. Phys., 55 (2010), 119-126
  • [8] Zhang G., Yuan P., Wang P., Chen Y., Zhang J., The preaparation and mechanical properties of Al–containing a–C:H thin films, J. Phys. D: Appl. Phys., 40 (2007) 6748-6753
  • [9] Cheng H.Y., Wu W.Y., Ting J .M., Microstructure and optical properties of chromium containing amorphous hydrogenated carbon thin films (a-C:H/Cr), Thin Solid Films, 517 (2009), 4724-4727
  • [10] Matenoglou G., Evangelakis G.A., Kosmidis C., Foulias S. , Papadimi t r iou D., Patsalas P., Pulsed laser deposition of amorphous carbon/silver nanocomposites, Applied Surface Science, 253 (2007) 8155-8159
  • [11] Ménard-Moyon C., Izard N., Doris E., Mioskowski Ch., Separation of Semiconducting from Metallic Carbon Nanotubes by Selective Functionalization with Azomethine Ylides, J. Am. Chem. Soc., 128 (2006), 6552-6553
  • [12] Pimenta M.A., Marucci A., Empedocles S.A., Bawendi M.G., Raman modes of metallic carbon nanotubes, Physical Review, 58 (1998), No. 24, R160116–R16020
  • [13] Frost R.L., Soisnard A., Voyer N., Palmer S.J., Martens W.N., Thermo-Raman spectroscopy of selected layered double hydroxides of formula Cu6Al2(OH)16CO3 and Zn6Al2(OH)16CO3, Journal of Raman Spectroscopy, 40 (2009), No. 6, 645-649
  • [14] Rahmani A., Sauvajol J.-L., Rols S., Benoit C., Nonresonant Raman spectrum in infinite and finite single-wall carbon nanotubes, Physical Review B, 66 (2002), 125404
  • [15] Nishi tani-Gamo M., Ando T., Yamamoto K., Watanabe K., Dennig P.A., Sato Y., Sekita M., A nondiamond phase at the interface between oriented diamond and Si(100) observed by confocal Raman spectroscopy, Appl. Phys. Lett., 70 (1997), 1530-1532
  • [16] Davidson G., Spectroscopic properties of inorganic and organometalic compounds, The Royal Society of chemistry, 33 (2000), 218
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d7d95d55-47bd-4c36-b838-f54139fe278f
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