Facile synthesis of preformed mixed nano-carbon structure from low rank coal

• Autorzy: Manoj B. , Raj A. M. , Chirayil G. T.

Identyfikatory

DOI

10.1515/msp-2018-0026

• Języki publikacji: EN

Abstrakty

EN

Coal is a natural energy resource which is mainly used for energy production via combustion. Coal has nanocrystals embedded in it, formed during the coalification process, and is an ideal precursor for nano-carbon dots and diamonds. Herein, we report a facile top-down method to synthesise nanodots and diamonds of the size of 5 nm to 10 nm from three different types of coal by simple chemical leaching. TEM analysis revealed the formation of a mixture of carbon dots, graphene layers, and quantum dots in bituminous coal and sub-bituminous coal. Raman analysis confirmed the existence of synthesized nanodiamond and nano-carbon mixed phase with defects associated with it. It is concluded that graphene quantum dots, nanodiamonds, graphene sheets and carbon dots present in coal can be extracted by simple chemical treatment. These structures can be tuned to photoluminescent material for various optoelectronic applications or energy harvesting devices like super capacitors.

Słowa kluczowe

EN

tertiary coal; Gondwana coal; carbon nanodots; graphene layers; quantum dots; nano-diamonds; mixed structure

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2018
• Tom: Vol. 36, No. 1
• Strony: 14--20
• Opis fizyczny: Bibliogr. 20 poz., rys., tab.

Twórcy

autor

Manoj B.

• Department of Physics, Christ University, Bangalore, 560029, Karnataka, India

autor

Raj A. M.

• Department of Physics, Christ University, Bangalore, 560029, Karnataka, India

autor

Chirayil G. T.

• Department of Physics, Christ University, Bangalore, 560029, Karnataka, India

Bibliografia

• [1] RAO C.N.R., SOOD A.K., SUBRAHMANYAM K.S., GOVINDARAJ A.L., Angew. Chem. Int. Edit., 48 (2009), 7752.
• [2] MANOJ B., Russ. J. Phys. Chem. A, 89 (2015), 2438.
• [3] KANIYOOR A., RAMAPRABHU S., AIP Adv., 2 (2012), 13.
• [4] RAMYA A.V., MOHAN A.N., MANOJ B., Mater. Sci.- Poland, 34 (2016), 330.
• [5] MANOJ B., J. Environ. Res. Develop., 9 (1) (2014), 209.
• [6] XIAO J., LIU P., YANG G.W., Nanoscale, 7 (2015), 6114.
• [7] BALACHANDRAN M., Am. J. Appl Chem., 7 (2014), 367.
• [8] MANOJ B., Int. J. Min. Met. Mater., 21 (2014), 940.
• [9] YE R., XIANG C., LIN J., PENG Z., HUANG K., YAN Z., COOK N.P., SAMUEL E.L.G., HWANG C.C., RUAN G., Nat. Commun., 4 (2013), 2.
• [10] DONG Y., LIN J., CHEN Y., FU F., CHI Y., CHEN G., Nanoscale, 6 (2014), 7410.
• [11] MANOJ B., Res. J. Biotechnol., 8 (3) (2013), 49.
• [12] MANOJ B., RAJ A.M., CHIRAYIL G.T., Sci. Rep-UK, 7 (2017), 18012.
• [13] FERRARI A.C., ROBERTSON J., Physical Review B, 61 (20) (2000), 14095.
• [14] RAMYA A.V., ANU N.M., MANOJ B., Asian J. Chem., 28 (7) (2016), 1501.
• [15] ANU N.M., MANOJ B., Res. J. Chem. Environ., 21 (2) (2017), 1.
• [16] MANOJ B., Int. J. Coal. Sci. Tech., 3 (2016), 123.
• [17] MANOJ B., Asian J. Chem., 3 (15) (2014), 4553.
• [18] ILYIN A., GUSEINOV N., NIKITIN A., TSYGANOV I., Physica E, 42 (2010), 2078.
• [19] KUNJOMANA A.G., MANOJ B., Russ. J. Appl. Chem.+, 87 (11) (2014), 1726.
• [20] ELCEY C.D., MANOJ B., Asian J. Chem., 28 (2016), 1557.

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).