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Fluid inclusions in celestine and their significance in the study of the formation of the native sulphur deposits in the Carpathian Foredeep

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EN
Abstrakty
EN
Celestine is a rather common mineral in epigenetic native sulphur deposits and seems to be a very valuable indicator of some of the geological processes forming these deposits. This paper presents the results of investigation of fluid inclusions in celestine from the Tarnobrzeg native sulphur deposits (SE Poland). Several different morphological types of celestine were selected from Machów open-pit mine. Study of the fluid inclusions has been carried out using microscopic and microthermometic methods. The data show that two types of chloride fluids were responsible for the formation of celestine and native sulphur and further transformation of the native sulphur deposits. The first type of fluid, containing a relatively higher salt content and lower NaCl/CaCl2 ratio, also points to the role of hydrocarbons during the formation of native sulphur deposits. The second type of fluid contains a relatively lower amount of salt and a higher NaCl/CaCl2 proportion and reflects the subsequent evolution of the chemistry of the fluids forming the deposits. The results of the study of fluid inclusions in celestine are in good agreement with its stable isotope composition.
Rocznik
Strony
art. no. e42
Opis fizyczny
Bibliogr. 28 poz., rys., tab., wykr.
Twórcy
  • Department of Geology, University of Warsaw
  • Institute of Ceramics and Building Materials, Warsaw, Poland
  • Department of Geology, University of Warsaw
Bibliografia
  • 1. Bąbel, M. 2004. Badenian evaporate basin of the northern Carpathian Foredeep as a drawdown salina basin. Acta Geologica Polonica, 54, 313–337.
  • 2. Bottcher, M. and Parafiniuk, J. 1998. Methane-derived carbonates in a native sulfur deposit: stable isotope and trace element discrimination related to the transformation of aragonite to calcite. Isotopes Environmental Health Studies, 34, 177–190.
  • 3. Gąsiewicz, A. 2000a. Sedimentology and diagenesis of gypsum-ghost limestones and origin of Polish native sulphur deposits. Prace Instytutu Geologicznego, 172, 1–143. [In Polish]
  • 4. Gąsiewicz, A. 2000b. Comparative study of major element geochemistry of gypsum-ghost limestones and selenite lithofacies from the Miocene of northern Carpathian Foredeep: implication to the model of massive replacement of solid sulphates by calcium carbonates. Chemical Geology, 164, 183–218.
  • 5. Goldstein, R.H. 2001. Fluid inclusions in sedimentary and diagenetic systems. Lithos, 55, 159–193.
  • 6. Kasprzyk, A., Pueyo, J., Hałas, S. and Fuenlabrada, J. 2007. Sulphur, oxygen and strontium isotope compositions of Middle Miocene (Badenian) calcium sulphates from the Carpathian Foredeep, Poland: palaeoenvironmental implications. Geological Quarterly, 51, 285–294.
  • 7. Klimchouk, A. 1997. The role of karst in the genesis of sulphur deposits, Pre-Carpathian region, Ukraine. Environmental Geology, 31, 1–20.
  • 8. Kozłowski, A. 1984. Calcium-rich inclusion solutions in fluorite from the Strzegom pegmatites. Lower Silesia. Acta Geologica Polonica, 34, 131–138.
  • 9. Kowalski, W., Osmólski, T. and Pilichowska, E. 1980. Strontianite from the sulphur deposit of the Machów mine (SE Poland). Archiwum Mineralogiczne, 36, 29–50. [In Polish]
  • 10. Krouse, H.R. and McCready, R.G.L. 1979. Reductive reactions in the sulfur cycle. In: Trudinger, P.A. and Swaine, D.J. (Eds), Biogeochemical cycling of mineral-forming elements, 315–368. Elsevier, Amsterdam, New York.
  • 11. Majka-Smuszkiewicz, A. 1969. Chemical composition of Tertiary waters in the region of Machów. Kwartalnik Geologiczny, 13, 629–642. [In Polish]
  • 12. Nieć, M. and Sermet, E. 2023. Discovery, geological investigation, mining and future of sulphur deposits in Poland. Przegląd Geologiczny, 71, 631–638. [In Polish]
  • 13. Osmólski, T. 1976. Karst and genesis of Polish sulphur deposits. Kwartalnik Geologiczny, 17, 310–325. [In Polish]
  • 14. Parafiniuk, J. 1989a. Strontium and barium minerals in the sulphur deposits from Tarnobrzeg region (SE Poland). Archiwum Mineralogiczne, 43 (2), 41–64. [In Polish]
  • 15. Parafiniuk, J. 1989b. Oxidation of native sulfur in the Fore-Carpathian sulfur deposits in the light of isotopic and mineralogical data. Acta Geologica Polonica, 39, 113–122.
  • 16. Parafiniuk, J. 2023. Minerals of the Tarnobrzeg native sulphur deposit. Przegląd Geologiczny, 71, 605–613. [In Polish]
  • 17. Parafiniuk, J and Hałas, S. 1997. Sulfur- and oxygene-isotope composition as the genetic indicator for celestine from the Miocene evaporates of the Carpathian Foredeep. Slovak Geological Magazine, 3, 131–134.
  • 18. Parafiniuk, J., Kowalski, W. and Hałas, S. 1994. Stable isotope geochemistry and the Genesis of the Polish native sulphur deposits – a review. Geological Quarterly, 38, 473–496.
  • 19. Parnell, J., Honghan, C., Middleton, D., Haggan, T. and Carey, P. 2000. Significance of fibrous mineral veins in hydrocarbon migration: fluid inclusion studies. Journal of Geochemical Exploration, 69–70, 623–627.
  • 20. Pawlikowski, M. 2023. Formation of the sulfur deposit. Tarnobrzeskie zagłębie siarkowe od odkrycia złóż siarki do cudu ekologii. Konferencja historyczno-ekologiczna, 29–34. Muzeum – Zamek Tarnowskich w Tarnobrzegu; Tarnobrzeg. [In Polish]
  • 21. Pawłowski, S., Pawłowska, K. and Kubica, B. 1985. Geology of the Tarnobrzeg native sulphur deposit. Prace Instytutu Geologicznego, 114, 1–109. [In Polish]
  • 22. Peryt, T.M., Szaran, J., Jasionowski, M., Hałas, S., Peryt, D., Poberezezhsky, A., Karoli, S. and Wójtowicz, A. 2002. S and Oisotope composition of the Badenia (Middle Miocene) sulphates In the Carpathian Foredeep. Geologica Carpathica, 53, 391–398.
  • 23. Pilichowska, E. 1984. Crystallography of celestine from the sulphur deposit at Machów, south-central Poland. Archiwum Mineralogiczne, 40, 23–40. [In Polish]
  • 24. Pobierizski, A. 1993. Use of thermobarogeochemical methods for the fluid inclusion studies in minerals of the sulfur deposits of the Carpathian Foredeep, West Ukraine. Przegląd Geologiczny, 41, 835–841.
  • 25. Roedder, E. 1984. Fluid inclusions: M.S.A. Reviews in Mineralogy, 12, 1–644.
  • 26. Ślączka, A. and Oszczypko, N. 2002. Paleogeography of the Badenian Salt Basin (Carpathian Foredeep, Poland and Ukraine). Geologica Carpathica, special issue, 53, 17–19.
  • 27. Van den Kerkhof, A. and Hein, U. 2001. Fluid inclusions petrography. Lithos, 55, 27–47.
  • 28. Williams-Jones, A. and Samson, I. 1990. Theoretical estimation of halite solubility in the system NaCl-CaCl2-H2O: Application to fluid inclusions. Canadian Mineralogist, 28, 299–304.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2026).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d711b563-ba18-4dbd-8aad-d4fa8937bfed
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