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X-ray diffraction studies of rapid cooled Al-V and Al-Fe-V alloys

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: of this paper is to deep and more complete knowledge about the features of phase and structure formation in Al-based alloys with transition metals (TM) Fe and V at rapid cooling from melt. It is known, that nonequilibrium synthesis conditions of such alloys lead to quasicrystalline, amorphous or metastable phases formation, which can significantly improve the physical-chemical properties and first of all the mechanical ones. But understanding of compositional dependences of structure features at formation under nonequilibrium conditions and the correlation of these dependences with physical properties of alloys is far to be clear. Design/methodology/approach: Structure of Al-enriched Al-V, Al-V-Fe rapid cooled alloys was studied by X-ray diffraction method. In order to estimate the influence of structural state of alloy on the mechanical properties the integral microhardness was studied by Vickers method. Findings: Two quasicrystalline icosaedral phases with different cell parameters are revealed in ternary alloys Al100-3xV2xFex (x=2-4). Increasing of transition metal content promotes the formation of phase with higher quasicell parameter embedded in amorphous matrix. With increasing of the transition elements total content from 6 up to 12 at. % the microhardness of alloys increased gradually from 867 to 3050 MPa. Research limitations/implications: Research of nonequilibrium alloys revealed crystalline structure of Al-V alloys and quasicrystalline embedded in amorphous matrix of Al-Fe-V ternary alloys. Obtained results suppose that further structure and physical properties studies of Al-Fe-V alloys will allows to find the conditions to control the producing of materials with desired properties. Practical implications: Using of rapid cooling method for synthesis of Al-enriched Al-Fe-V alloys give an opportunity to produce alloys with significantly improved mechanical properties. Originality/value: Nonequilibrium conditions of cooling allow significantly changes the structure and properties.
Rocznik
Strony
5--11
Opis fizyczny
Bibliogr. 22 poz., tab., wykr.
Twórcy
autor
  • Physics of Metals Department, I. Franko Lviv National University, Kyrylo and Mephodiy str. 8, 79005 Lviv, Ukraine
autor
  • Physics of Metals Department, I. Franko Lviv National University, Kyrylo and Mephodiy str. 8, 79005 Lviv, Ukraine
autor
  • Physics of Metals Department, Zaporizhzhia National University, Zhukovsky str. 66, 69063 Zaporizhzhia, Ukraine
autor
  • Physics of Metals Department, Zaporizhzhia National University, Zhukovsky str. 66, 69063 Zaporizhzhia, Ukraine
Bibliografia
  • [1] R.A. Dunlap, K. Dini, Amorphization of rapidly quenched quasicrystalline Al-transition metal alloys by the addition of Si, Journal of Materials Research 1/3 (1986) 415-419, DOI: https://doi.org/10.1557/JMR.1986.0415.
  • [2] D.L. Skinner, K. Okazaki, High strength Al-Fe-V alloys at elevated temperatures produced by rapid quenching from the melt, Scripta Metallurgica 18/9 (1984) 905-909, DOI: https://doi.org/10.1016/00369748(84)90258-8.
  • [3] A. Inoue, H. Kimura, T. Zhang, High-strength aluminum- and zirconium-based alloys containing nanoquasicrystalline particles, Materials Science and Engineering: A 294-296 (2000) 727-735, DOI: https://doi.org/10.1016/S0921-5093(00)01307-1.
  • [4] H.M. Kimura, K. Sasamori, A. Inoue, Al–Fe-based bulk quasicrystalline alloys with high elevated temperature strength, Journal of Materials Research 15/12 (2000) 2737-2744, DOI: https://doi.org/10.1557/JMR.2000.0392.
  • [5] J.L. Murray, Al-V (aluminum-vanadium), Bulletin of Alloy Phase Diagrams 10/4 (1989) 351-357, DOI: https://doi.org/10.1007/BF02877591.
  • [6] L.F. Mondolfo, Aluminum-Vanadium System, in: Aluminium Alloys: Structure and Properties, Butterworths, London, 1976, 392-394.
  • [7] E.M. Sokolovskaya, L.M. Badalova, E.F. Kazakova, Phase Composition of Rapidly Quenched Alloys of the System Al-Fe-V, Izvestija Akademiji Nauk SSSR, Met. 5 (1987) 212-215.
  • [8] P. Ramachandrarao, G.V.S. Sastry, A basis for the synthesis of quasicrystals, Pramana 25/2 (1985) L225L230, DOI: https://doi.org/10.1007/BF02847665.
  • [9] A.J. Drehman, A.R. Pelton, M.A. Noack, Nucleation and growth of quasicrystalline Pd-U-Si from the glassy state, Journal of Materials Research 1/6 (1986) 741-745, DOI: https://doi.org/10.1017/S0884291400120047.
  • [10] V.V. Girzhon, A.V. Smolyakov, I.V. Tantsyura, Structural State of Surface Layers of Aluminum after Laser Alloying Using a Mixture of Copper and Iron Powders, The Physics of Metals and Metallography 106/4 (2008) 384-388, DOI: https://doi.org/10.1134/S0031918X08100086.
  • [11] H. Chen, Q. Wang, Y. Wang, J. Qiang, C. Dong, Composition rule for Al–transition metal binary quasicrystals, Philosophical Magazine A 90/30 (2010) 3935-3946, DOI: https://doi.org/10.1080/14786435.2010.502144.
  • [12] D.W. Lawther, R.A. Dunlap, V. Sriniva, On the question of stability and disorder in icosahedral aluminum - transition metal alloys, Canadian Journal of Physics 67/5 (1989) 463-467, DOI: https://doi.org/10.1139/p89-082.
  • [13] R.A. Dunlap, K. Dini, Structure and stability of quasicrystalline aluminium transition-metal alloys, Journal of Physics F: Metal Physics 16/1 (1986) 11-16, DOI: https://doi.org/10.1088/0305-4608/16/1/008.
  • [14] D.J. Skinner, V.R.V. Ramanan, M.S. Zedalis, N.J. Kim, Stability of Quasicrystalline Phases in AI-Fe-V Alloys, Materials Science and Engineering 99/1-2 (1988) 407-411, DOI: https://doi.org/10.1016/00255416(88)90366-7.
  • [15] A. Inoue, H. Kimura, K. Sasamori, T. Masumoto, High Strength Al-V-M (M=Fe, Co, or Ni) Alloys Containing High Volume Fraction of Nanoscale Amorphous Precipitates, Materials Transitions: JIM 36/10 (1995) 1219-1228.
  • [16] H. Kimura, A. Inoue, K. Sasamori, Microstructure and Mechanical Properties of P/M Al-V-Fe and Al-Fe-MTi (M=V, Cr, Mn) Alloys Containing Dispersed Quasicrystalline Particles, Materials Transactions: JIM 41/11 (2000) 1550-1554.
  • [17] C.H. Shek, G. He, Z. Bian, G.L. Chen, J.K.L. Lai, Effect of composition and cooling rate on structures and properties of quenched or cast Al-V-Fe alloys, Materials Science and Engineering: A 357/1-2 (2003) 20-26, DOI: https://doi.org/10.1016/S0921-5093(02) 00869-9.
  • [18] J. Rodriguez-Carvajal, Recent developments of the program FULLPROF, Newsletter in Commission on Powder Diffraction (IUCr) 26 (2001) 12-19.
  • [19] H. Okamoto, Al-V (Aluminum-Vanadium), Journal of Phase Equilibria and Diffusion 33/6 (2012) 491, DOI: https://doi.org/10.1007/s11669-012-0090-4.
  • [20] J.R. Wilson, Structure of Liquid Metals and Alloys, Metallurgical Reviews 10/1 (1965) 381-590, DOI: https://doi.org/10.1179/mtlr.1965.10.1.381.
  • [21] J.W. Cahn, D. Shechtman, D. Gratias, Indexing of icosahedral quasiperiodic crystals, Journal of Materials Research 1/1 (1986) 13-26, DOI: https://doi.org/10.1557/JMR.1986.0013.
  • [22] V. Elser, Indexing problems in quasicrystal diffraction, Physical Review B 32/8 (1985) 48924898, DOI: https://doi.org/10.1103/PhysRevB.32.4892.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d6cb1ebf-27de-4ef9-bd15-bee621224c4e
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