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Warianty tytułu
Języki publikacji
Abstrakty
The wastewater produced by the metal industry is often present in the form of oil-in-water (O/W) or water-inoil (W/O) emulsions. These fluids contain a certain amount of valuable oil that can be recovered in the recycling process. Therefore, the development of novel, efficient, and low cost processes for the treatment of metalworking fluid is necessary. Demulsification to separate oil/water mixtures is a very interesting option because it allows the recovery and reuse of the lubricant oil and effects in cleaner, easily treatable wastewater.Chemical destabilization is the most common way of demulsification of metalworking fluids. As an example, inorganic salts can be used as demulsifiers. In the presented work the efficiency of treatment of cutting emulsions with chemical demulsification with usage of aluminum sulfate (IV) is described. The emulsion was prepared with Emulgol-ES12 self-emulsyfing oil delivered by Orlen S.A. In the research the feasibility of the demulsifier was checked. The novel in this paper is determination of the optimal dosage of emulsifier using the TurbiscanLab® apparatus. It is relatively quick and precise method that can be applied in the industry.
Wydawca
Czasopismo
Rocznik
Tom
Strony
28--37
Opis fizyczny
Bibliogr. 28 poz., wykr.
Twórcy
autor
- Lodz University of Technology, Faculty of Process Engineering and Environmental Protection, Department of Chemical Engineering, Wolczanska str. 213, 90-924 Lodz, Poland
autor
- Lodz University of Technology, Faculty of Process Engineering and Environmental Protection, Department of Chemical Engineering, Wolczanska str. 213, 90-924 Lodz, Poland
Bibliografia
- [1] Polowski W., Musiałek K., Nowak D. Badania cieczy obróbkowych stosowanych w procesie skrawania metali oraz postępowanie z emulsjami zużytymi, Materiały Konferencyjne Ecofirm, IV Symp. IOS Kraków: (2000)111-115
- [2] Bensadok, K.; Belkacem, M.; Nezzal, G. Treatment of cutting oil/water emulsion by coupling coagulation and dissolved air flotation. Desalination(2007) 206: 440-448
- [3] Cheng, C., Phipps, D., Alkhaddar, R.M. Review treatment of spent metalworking fluids. Water research (2005) 39: 4051-4063
- [4] Komorowicz T., Janusz M., Marta P., Luiza P.Badania rozdziału emulsji olej-woda z zastosowaniem deemulgatorów, Czasopismo Techniczne Wydawnictwo Politechniki Krakowskiej (2007) :48-58
- [5] Rios, G., Pazos, C., Coca, J. Destabilization of cutting oil emulsions using inorganic salts as coagulants. Physicochemical and Engineering Aspects (1998) 138: 383-389
- [6] Bataller, H.; Lamaallam, S.; Lachaise, J.; Gracia, A.; Dicharry, C. Cutting fluid emulsions produced by dilution of a cutting fluid concentrate containing a cationic/nonionic surfactant mixture. Journal of Materials Processing Technology,(2004) 152 : 215-220
- [7] Grzesik, W. Cutting fluids. Advanced machining processes of metallic materials:Theory, modeling, and application. US: Elsevier (2008)
- [8] Bensadok, K., Benammar, S., Lapicque, F., Nezzal, G. Electrocoagulation of cutting oil emulsions using aluminium plate electrodes. Journal of hazardous materials (2008) 152: 423-430
- [9] Kobya ,M., et al, Treatment of potato chips manufacturing wastewater by electro coagulation, Desalination, (2006)190: 201-211
- [10] Occupational safety and health administration (OSHA), Metalworking fluids standardadvisory committee (MWFSAC). Metalworking fluids: safety and health bestpractices manual.(1999)
- [11] Soković, M.; Mijanović, K. Ecological aspects of the cutting fluids and its influence on quantifiable parameters of the cutting processes. Journal of Materials Processing Technology (2001) 109:181-189
- [12] El Baradie, M.A. Cutting fluids: part II. Recycling and clean machining. Journal of Material Processing Technology (1996) 56: 798-806
- [13] Feldman, D. G.; Kessler, M. Fluid qualification tests – evaluation of the lubricating properties of biodegradable fluids. Industrial Lubrication and Tribology, (2002)54, 3: 117-129
- [14] Gierżatowicz R., Pawłowski L., Sposób demulgacji emulsji wodno-olejowych zwłaszcza przepracowanych chłodziw obrabiarkowych, opis patentowy (1994) 165104
- [15] Komorowicz T. Kupiec K., Mółka A. Zastosowanie nowych demulgatorów organicznych do rozdziału emulsji olej-woda (2014) 1/14 1-10
- [16] Chawaloesphonsiya, Nattawin, Séparation d'émulsions par flottation et coalescence pour le traitement d'eaux uses (2015)PhD thesis
- [17] Yang, Hongbin & Kang, Wanli & Wu, Hairong & Yu, Yang & Zhu, Zhou & Wang, Pengxiang & Zhang, Xiangfeng & Sarsenbekuly, Bauyrzhan. Stability, rheological property and oil-displacement mechanism of a dispersed low-elastic microsphere system for enhanced oil recovery. RSC Adv.. 7. 8118-8130 (2017)
- [18] Barad J.M., Chakraborty M., Bart H.J. Stability and performance study of water-in-oil-in-water emulsion: extraction of aromatic amines, Ind. Eng. Chem. Res.(2010) 49: 5808-5815
- [19] Lemarchand C.,Couvreur P., Vauthier C., Costantini D., Gref R. Study of emulsion stabilization by graft copolymers Rusing the optical analyzer Turbiscan, Int. J.Pharm. (2003) 254: 77-82
- [20] Celia C., Trapasso E., Cosco D., Paolino D., Fresta M. TurbiscanLab® Expert analysis of the stability of ethosomes and ultradeformable liposomes containing a bialyer fluidizing agent, Colloid Surf.B (2009) 72:155-160
- [21] Buron H. Mengual O. Meunier G. Cayre I. Snabre P. Optical characterization of concentrated dispersions: applications to laboratory analyses an on-line process monitoring and control, Polym. Int. (2004) 53:1205-1209
- [22] Mengual O. Meunier G. Cayre I., Snabre P. Characterization of instability of concentrated dispersions by a New optical analyser: the TURBISCAN MA 1000, Colloid Surf. A (1999) 152 111-123
- [23] Liu J. Huang X.,LuL.,Li M., Xu J. Deng H. TurbiscanLab®Expert analysis of the biological demulsification of water-in-oil emulsion by two biodemulsifiers Journal of Hazardous Materials (2011) 190:214-221
- [24] Hergert W., Wriedt T.,Mie Theory 1908-2008, Present developments and Interdisciplinary aspects of light scattering, Universität Bremen, Bremen –presentation (2008)
- [25] M. Kobya, C. Ciftci, M. Bayramoglu and M. T. Sensoy, Study on the Treatment of Waste Metal Cutting Fluids Using Electrocoagulation, Separation and Purification Technology, Vol. 60, No. 3, (2008) 285-291
- [26] Lesaint C., Glomm W, Lundgaard L., Sjöblom J., Dehydration efficiency of AC electrical fields on waterin-model-oil emulsions, Colloids and Surfaces A: Physicochemical and Engineering Aspects, Volume 352, Issues 1–3, (2009), 63-69
- [27] Li Z., Wu H., Yang M., Xu D., Chen J., Feng H., Lu Y., Zhang L., Yu Y., Kang W., Stability mechanism of O/W Pickering emulsions stabilized with regenerated cellulose, Carbohydrate Polymers (2017)
- [28] Demirbas E., Kobya M., Operating cost and treatment of metalworking fluid wastewater by chemical coagulation and electrocoagulation processes, Process Safety and Environmental Protection, Volume 105, (2017) 79-90
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d68ce3e5-87ac-4b22-92a1-248f3f613cbd