Removal of acid, direct and reactive dyes on thepolyacrylic anion exchanger

• Autorzy: Polska-Adach Ewelina , Wawrzkiewicz Monika , Hubicki Zbigniew

Identyfikatory

DOI

10.5277/ppmp19075

• Języki publikacji: EN

Abstrakty

EN

In the present studythe polyacrylic anion exchanger Amberlite IRA 478 (IRA 478) was used forremoval of textile dyes such as C.I. Acid Red 18 (AR18), C.I. Reactive Blue 21 (RB21) and C.I. Direct Yellow 142 (DY142) from aqueous solutions. Sorption of the above-mentioned dyes was carried out by the static and dynamic methods. The obtained results were analyzed by determining the adsorption isothermparameters using the Langmuir and Freundlichmodels. Kinetic parameters of dyessorption were calculated from the pseudo-first order, pseudo-second order and intraparticle diffusion models. The monolayer sorption capacities of IRA 478 determined from the Langmuir isotherm were found to be 1098.5 mg/g for AR18 (R²=0.994), 46.8 mg/g for DY142 (R²=0.820) and 23.5 mg/g for RB21 (R²=0.987).Kinetic studies revealed that effectiveness of AR18, DY142 and RB21 uptakeincreases with increasing phase contact time and initial dyesconcentration.The kinetics of the dyessorption process on the anion exchanger is best described by the pseudo-second order model (PSO) due to the high values of the determination coefficients R² (linearity condition of the plot t/q_t vs.t). The rate constantsof the pseudo-second order kinetics k₂are reduced from 0.1001 to 0.0008 g/mg·min for AR18, from 0.0147 to 0.0112 g/mg·min for DY142 and 0.0489 to 0.0072 g/mg·min for RB21 with an increase of initial concentration of dyes.The presence of salts and surfactants had an impact on the retention of direct and reactive dyes.

Słowa kluczowe

EN

dye removal; polyacrylic anion exchanger; reactive dye; direct dye; acidic dye

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Physicochemical Problems of Mineral Processing
• Rocznik: 2019
• Tom: Vol. 55, iss. 6
• Strony: 1496--1508
• Opis fizyczny: Bibliogr. 35 poz., rys., tab., wykr., wz.

Twórcy

autor

Polska-Adach Ewelina

• Maria Curie-Sklodowska University, Faculty of Chemistry, Department of Inorganic Chemistry, M. Curie-Sklodowska Sq. 2, 20-031 Lublin, Poland

autor

Wawrzkiewicz Monika

• Maria Curie-Sklodowska University, Faculty of Chemistry, Department of Inorganic Chemistry, M. Curie-Sklodowska Sq. 2, 20-031 Lublin, Poland

autor

Hubicki Zbigniew

• Maria Curie-Sklodowska University, Faculty of Chemistry, Department of Inorganic Chemistry, M. Curie-Sklodowska Sq. 2, 20-031 Lublin, Poland

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).