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The aim of the research was the evaluation of the potential contamination with heavy metals in Fluvisols, used as grasslands and arable soils of Vistula River floodplain in the area of the Chełmiński and Nadwiślański Complex of Landscape Parks. The indicators proposed by Håkanson allow to evaluate the potential ecological risk of the contamination with heavy metals associated with the accumulation of one metal or a combination of multiple metals. The mean total content of Cd, Pb, Ni Cu, Zn, Mn, as well as Fe in Fluvisols at the depth of 120–150 cm was assumed as the content of the local geochemical background and it was: 1.0 mg·kg-1, 22.8 mg·kg-1, 26.9 mg·kg-1, 1.4 mg·kg-1, 60.8 mg·kg-1, 591 mg·kg-1, and 17.6 g·kg-1, respectively. The values of the indicators such as contamination factor (CF), enrichment factor (EF) revealed higher levels of the accumulation of heavy metals in the soils of grasslands, which shows that the method of their use has a significant effect on the total metal content. Contamination with heavy metals in the surface layer of the investigated Fluvisols was found, and in terms of the content with cadmium a moderate and considerable potential ecological risk was reported. Due to the fact that no unfavourable effect of trace elements on the riverside environment was proved and that the floodplain areas are under agricultural use, to evaluate the contamination with metals, the limit values for the soils of agricultural land were assumed as stipulated in the Regulation of Minister of the Environment of September 9, 2002. According to that criterion, the soils studied do not qualify as contaminated with metals. Only in one of the soil sampling points the total content of zinc was higher than the one determined as the maximum for agricultural land soils, namely 350 mg·kg-1. A significantly positive correlation was noted between the content of C org and the total content of metals as well as very numerous interactions between metals. The results of cluster analysis confirm that the method of use determines the concentration of metals in the surface layer of the Fluvisols studied.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
23--31
Opis fizyczny
Bibliogr. 24 poz., tab.
Twórcy
autor
- Department of Soil Science and Soil Protection, University of Technology and Life Sciences in Bydgoszcz, Bernardyńska 6/8, 85-029 Bydgoszcz, Poland
Bibliografia
- 1. Crock J.G., Severson R. 1980. Four reference soil and rock samples for measuring element availability in the western energy regions. U.S. Geological Survey circular 841, 16.
- 2. Czarnowska K., Broda D., Chojnicki J., Turemka E. 1995. Heavy metals in illuvial soils of the Vistula valley. Roczn. Glebozn. 46, 3/4, 5–18 [in Polish].
- 3. Dąbkowska-Naskręt H., Kobierski M., Różański S. 2000. Trace elements distribution and mobility in alluwial soils of the Wisła River Valley, Poland. Mengen und Spurenelemente, 20. Arbeitstagung. Jena, 152–157.
- 4. Dziennik Ustaw 2002. Rozporządzenie Ministra Środowiska w sprawie standardów jakości gleby oraz jakości ziemi. Nr 165, poz. 1359. [in Polish]
- 5. Gervais-Beaulac V., Saint-Laurent D., Berthelot J.S., Mesfioui M. 2013. Organic carbon distribution in alluvial soils according to different flood risk zones. J. Soil Sci. Environ. Manage., 4, 8, 169–177.
- 6. Håkanson L. 1980. An ecological risk index for aquatic pollution control – a sedimentological approach. Water Research 14, 975–1101.
- 7. Harmsen J. 2007. Measuring bioavailability: from a scientific approach to standard methods. J. Environ. Qual., 36, 5, 1420–1428.
- 8. Hoffmann T, Glatzel S, Dikau R. 2009. A carbon storage perspective on alluvial sediment storage in the Rhine catchment. Geomorphology 108, 127–137.
- 9. ISO 10390: 2005. Soil quality – Determination of pH.
- 10. Józefowska A., Miechówka A., Gąsiorek M., Zadrożny P. 2014. Content of zinc, lead and cadmium in selected agricultural soils in the area of the Śląskie and Ciężkowickie foothills. J. Ecol. Eng., 15, 1, 74–80.
- 11. Kabata-Pendias A. 2004. Soil-plant transfer of trace elements – an environmental issue. Geoderma 122. 143–149.
- 12. Kabata-Pendias A., Pendias H. 2001. Trace elements in soils and plants. Boca Raton. London. New York. Washington DC, 1–331.
- 13. Kobierski M., Piotrowska A. 2010. Profile distribution of heavy metals and enzymatic activity in Fluvisols of the Vistula River Valley, Poland. Fressenius Environ. Bulletin 19, No 2b, 303–311.
- 14. Kordowski J. 2003. Internal structures and granulometry of lower Vistula valley over bank deposits in the Toruń and Unisław Basins. Przegląd Geograficzny 75, 4, 601–621.
- 15. Macklin M.G., Klimek K. 1992. Dispersal, storage and transformation of metal contaminated alluvium in the Upper Vistula basin, southwest Poland. Appl. Geogr., 12, 7–30.
- 16. Martin J.-M., Meybeck M. 1979. Elemental mass-balance of material carried by major world rivers. Marine Chemistry 7, 3, 173–206.
- 17. Martin J.-M., Whitfield M. 1983. The significance of the river input of chemical elements to the ocean. [In:] Trace metals in seawater. Wong C.S., Boyle E., Bruland K.W., Goldberg E.D. (Editors), Plenum, New York. 265–296.
- 18. PN-ISO–11277: 2005. Soil quality – Determination of particle size distribution in mineral soil material – Method by sieving and sedimentation.
- 19. Saint-Laurent D., St-Laurent J., Lavoie L., Drouin A., Ghaleb B. 2010. Floodplain sedimentation rates, soil properties and recent flood history in Southern Québec. Global. Planetary Change 70, 76–91.
- 20. Singh K., Malik A., Sinha S., Singh V., Murthy R. 2005. Estimation of source of heavy metal contamination in sediments of Gomti river (India) using principal component analysis. Water Air Soil Pollut., 166, 321–341.
- 21. Skorbiłowicz E., Samborska A. 2014. Content of copper and nickel in soils of Vistula River catchment. J. Ecol. Eng., 15, 2, 53–59.
- 22. Sutherland R.A., Tolosa C.A, Tack F.M.G., Verloo M.G. 2000. Characterization of selected element concentration and enrichment ratios in background and anthropogenically impacted roadside areas. Arch. Environ. Contam. Toxicol., 38, 428–438.
- 23. Van Gestel C.A.M. 2008. Physico-chemical and biological parameters determine metal bioavailability in soils. Sci. Total Environ., 406, 385–395.
- 24. Wyżga B., Ciszewski D. 2010. Hydraulic controls on the entrapment of heavy metal-polluted sediments on a floodplain of variable width, the upper Vistula River, southern Poland. Geomorphology 117, 272–286.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d5e00ec8-f783-4329-91a3-72a45a5c5963