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Abstrakty
More than 20 kg of dust and sludge per 1 ton of produced metal are generated in the basic oxygen furnaces used in steel metallurgy. In this type of waste there may be many non-ferrous metals, including also zinc. The content of this metal in dusts ranges from 1 to 6%. After lowering the zinc content to a level of about 1%, such type of waste may become a full-fledged iron-bearing material used in ferrous metallurgy. There is also a possibility to recover and manage the zinc removed from waste materials. Recycling of these materials also reduces the risk to the natural environment, resulting from e.g. the transition of metal compounds contained in stored waste materials into the groundwater and soil. The article presents the results of ammonia leaching of wastes from basic oxygen furnaces where the zinc content is 2.82%. Ammonia leaching allows the turn zinc into the liquid phase with minimal loss of iron in this process. The examinations apply three compounds of ammonia (NH4Cl, (NH4)2CO3 and NH4OH) to analyze the efficiency of the leaching process at different times, temperatures, concentrations of applied compounds and ratios of liquid phase to the solid phase.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
179--187
Opis fizyczny
Bibliogr. 13 poz., rys., tab., wykr.
Twórcy
autor
- Department of Physical Chemistry and Metallurgy of Non-Ferrous Metals, AGH University of Science and Technology, Faculty of Non-Ferrous Metals, al. A. Mickiewicza 30, 30-059 Krakow, Poland
autor
- Department of Metal Working and Physical Metallurgy of Non-Ferrous Metals, AGH University of Science and Technology, Faculty of Non-Ferrous Metals, al. A. Mickiewicza 30, 30-059 Krakow, Poland
Bibliografia
- [1] World steel association, Steel industry by-products. Fact sheet. Available: http://www.worldsteel.org/pictures/ programfiles/Fact%20sheet_By-products.pdf [12/30, 2011].
- [2] Chapter 8: Metallurgical slags, dust and fumes, S.R. Rao (Ed.), Waste Management Series: Resource Recovery and Recycling from Metallurgical Wastes2006, 269–327.
- [3] L.-M. WU, Characteristic of steelmaking flue dust, Ironmaking and Steelmaking 26 (5) (1999) 372–377.
- [4] G. Orhan, Leaching and cementation of heavy metals from electric arc furnace dust in alkaline medium, Hydrometallurgy 78 (2005) 236–245.
- [5] R.L. Nyirenda, The processing of steelmaking flue-dust: a review, Minerals Engineering 4 (7–11) (1991) 1003–1025.
- [6] Steel Technology Roadmap. Chapter 4: Environmental Leadership. Report, 2001, 83–120.
- [7] EN 12457/1-4/2002, Leaching—Compliance Test for Leaching of Granular Waste Materials and Sludges, CEN (European Committee for Standardization), 2002.
- [8] U.S. Environmental Protection Agency (EPA), Washington, DC, Test Methods for Evaluating Solid Waste, Physical/ Chemical Methods. Document no. SW-846, 3rd ed., 2008.
- [9] V.I. Rodionova, On the Dissolution of Zinc in Alkalis, National Aeronautics and Space Administration, Washington, 1965.
- [10] P. Kapias, R. Stelmach, J. Gazda, Rozpoznanie metod odzysku cynku i ołowiu z pyłów powstających w procesie przerobu złomów stali, Rudy i Metale Nieżelazne 44 (6) (1999) 280–286 (in Polish).
- [11] M. Olper, The EZINEX process – a new and advanced way for electrowinning zinc from a chloride solution, in: I.G. Matthew (Ed.), World Zinc '93,, Australas. Inst. Min. Metall., Parkville, Australia, 1993, pp. 491–494.
- [12] M. Olper, Zinc extraction from EAF dust with EZINEX process, in: P.B. Queneau, R.D. Peterson (Eds.), Recycling of Metals and Engineered Materials, Minerals, Metals & Materials Society, Warrendale, USA, 1985, pp. 563–578.
- [13] A.J.B. Dutra, P.R.P. Paiva, L.M. Tavares, Alkaline leaching of zinc from electric arc furnace steel dust, Minerals Engineering 19 (2006) 478–485.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d5bec4b0-e456-43f8-8513-fa8b75837230