EMR-related problems at the interface between the crystal field Hamiltonians and the zero-field splitting Hamiltonians

Rudowicz, Cz.; Karbowiak, M.

doi:10.1515/nuka-2015-0067

Artykuł - szczegóły

Tytuł artykułu

EMR-related problems at the interface between the crystal field Hamiltonians and the zero-field splitting Hamiltonians

Autorzy

Rudowicz Cz. , Karbowiak M.

Treść / Zawartość

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Identyfikatory

DOI

10.1515/nuka-2015-0067

Warianty tytułu

Konferencja

III Electron Magnetic Resonance Forum EMR-PL (3 ; 23-25.05.2014 ; Kraków, Poland)

Języki publikacji

Abstrakty

The interface between optical spectroscopy, electron magnetic resonance (EMR), and magnetism of transition ions forms the intricate web of interrelated notions. Major notions are the physical Hamiltonians, which include the crystal field (CF) (or equivalently ligand field (LF)) Hamiltonians, and the effective spin Hamiltonians (SH), which include the zero-fi eld splitting (ZFS) Hamiltonians as well as to a certain extent also the notion of magnetic anisotropy (MA). Survey of recent literature has revealed that this interface, denoted CF (LF) ↔ SH (ZFS), has become dangerously entangled over the years. The same notion is referred to by three names that are not synonymous: CF (LF), SH (ZFS), and MA. In view of the strong need for systematization of nomenclature aimed at bringing order to the multitude of different Hamiltonians and the associated quantities, we have embarked on this systematization. In this article, we do an overview of our efforts aimed at providing a deeper understanding of the major intricacies occurring at the CF (LF) ↔ SH (ZFS) interface with the focus on the EMR-related problems for transition ions.

Słowa kluczowe

crystal/ligand field (CF/LF) Hamiltonian electron magnetic resonance (EMR) magnetism optical spectroscopy transition (3dN and 4fN) ions zero-field splitting (ZFS)

Wydawca

Institute of Nuclear Chemistry and Technology

Czasopismo

Nukleonika

Rocznik

2015

Tom

Vol. 60, No. 3, part 1

Strony

377--383

Opis fizyczny

Bibliogr. 66 poz., rys.

Twórcy

autor

Rudowicz Cz.

crudowicz@zut.edu.pl; czerud@amu.edu.pl

Institute of Physics, West Pomeranian University of Technology, 17 Piastów Ave., 70-310 Szczecin, Poland
Faculty of Chemistry, Adam Mickiewicz University, 89B Umultowska Str., 61-614 Poznań, Poland

autor

Karbowiak M.

Faculty of Chemistry, University of Wrocław, 14 F. Joliot-Curie Str., 50-383 Wrocław, Poland

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