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Study of the Thermal Decomposition and Combustion of Guanidinium 5,5’-Azotetrazole Salt

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The thermal decomposition and combustion of guanidinium 5,5’-azotetrazole salt (Gu2AzT) have been investigated. Temperature profiles in the Gu2AzT combustion wave were measured using thin tungsten-rhenium micro thermocouples. It was shown that combustion of the salt obeys the condensedphase mechanism. The high burning rate of Gu2AzT is connected with the high decomposition rate in the melt. The kinetic parameters of the controlling chemical reaction have been estimated, and a detailed combustion mechanism for Gu2AzT has been proposed.
Rocznik
Strony
529--539
Opis fizyczny
Bibliogr. 17 poz., rys.
Twórcy
  • Department of Chemical Engineering, Mendeleev University of Chemical Technology 9 Miusskaya Sq., 125047, Moscow, Russia
  • Department of Chemical Engineering, Mendeleev University of Chemical Technology 9 Miusskaya Sq., 125047, Moscow, Russia
  • Department of Chemical Engineering, Mendeleev University of Chemical Technology 9 Miusskaya Sq., 125047, Moscow, Russia
Bibliografia
  • [1] Walsh C.M., Knott C.D., Leveritt C.S., Reduced Erosion Additive for a Propelling Charge, Patent US 6,984,275 B1, Jan. 10, 2006.
  • [2] Steinhauser G., Klapötke T.M., Pyrotechnik mit dem ‘Okosiegel’: eine chemische herausforderung, Angew. Chem., 2008, 120, 3376-3394.
  • [3] Bucerius K.M., Wasmann Fr.W., Menke K., Stable, Nitrogen-rich Composition, Patent US 5,198,046, Mar. 30, 1993.
  • [4] Neutz J., Eisenreich H., Fischer Th., Thermoanalyse stickstoffreicher Gasgeneratorbrennstoffe, 30th Int. Annu. Conf. of ICT, Karlsruhe, FRG, 1999.
  • [5] Sivabalan R., Talawar M.B., Senthilkumar N., Kavitha B., Asthana S.N., Studies on Azotetrazolate Based High Nitrogen Content High Energy Materials Potential Additives for Rocket Propellants, J. Therm. Anal. Calorim., 2004, 78, 781-791.
  • [6] Abe M., Ogura T., Miyata Ya., Okamoto K., Date Sh., Kohga M., Hasue K., Evaluation of Gas Generating Ability of some Tetrazoles and Copper (II) Oxide Mixtures through Closed Vessel Test and Theoretical Calculation, Sci. Tech. Energetic Materials, 2008, 69(6), 183-190.
  • [7] Hiskey M.A., Goldman N., Stine J.R., High Nitrogen Energetic Materials Derived from Azotetrazolate, J. Energ. Mater., 1998, 16, 119-127.
  • [8] Hammerl A., Hiskey M.A., Holl G., Klapötke T.M., Polborn K., Stierstorfer J., Weigand J.J., Azidoformamidinium and Guanidinium 5,5‘-Azotetrazolate Salts, Chem. Mater., 2005, 17, 3784-3793.
  • [9] Tappan B.C., Ali A.N., Son S.F., Brill T.B., Decomposition and Ignition of the Highnitrogen Compound Triaminoguanidinium Azotetrazolate (TAGzT), Propellants Explos. Pyrotech., 2006, 31(3), 163-168.
  • [10] Belov G.B., Thermodynamic Analysis of Combustion Products at High Temperature and Pressure, Propellants Explos. Pyrotech., 1998, 23, 86-89.
  • [11] Kissinger H.E., Reaction Kinetics in Differential Thermal Analysis, Anal. Chem., 1957, 29(11), 1702-1706.
  • [12] Prokudin V.G., Poplavsky V.S., Ostrovskii V.A., Mechanism of Monomolecular Thermal Decomposition of Tetrazole and 5-Substituted Tetrazoles, Rus. Chem. Bull., 1996, 45(9), 2101-2104.
  • [13] Sinditskii V.P., Egorshev V.Yu., Levshenkov A.I., Serushkin V.V., Ammonium Nitrate: Combustion Mechanism and the Role of Additives, Propellants Explos. Pyrotech., 2005, 30(4), 269-280.
  • [14] Sinditskii V.P., Egorshev V.Yu., Fogelzang A.E., Serushkin V.V., Kolesov V.I., Combustion Mechanism of Tetrazole Derivatives, Chemical Physics Reports, 2000, 18(8), 1569 -1583.
  • [15] Sinditskii V.P., Egorshev V.Yu., Serushkin V.V., Levshenkov A.I., Berezin M.V., Filatov S.A., Smirnov S.P., Evaluation of Decomposition Kinetics of Energetic Materials in the Combustion Wave, Thermochim. Acta, 2009, 496(1-2), 1-12.
  • [16] Zeldovich Y.B., Theory of Combustion of Propellants and Explosives, Zh.Eksperimentalnoy i Teoreticheskoi Fiziki (Russ. J. Exper. and Theor. Physics), 1942, 12(11-12), 498-524.
  • [17] Sinditskii V.P., Vu M.C., Sheremetev A.B., Alexandrova N.S., Study on Thermal Decomposition and Combustion of Insensitive Explosive 3,3’-Diamino-4,4’-azofurazan (DAAzF), Thermochim. Acta, 2008, 473(1-2), 25-31.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d50ac003-a8fa-407d-a197-0e3e5d4f1b43
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