Structural and conductivity studies of LiNi0.5Mn0.5O2 cathode materials for lithium-ion batteries

Murali, N.; Babu, K. V.; Babu, K. E.; Veeraiah, V.

doi:10.1515/msp-2016-0038

Artykuł - szczegóły

Tytuł artykułu

Structural and conductivity studies of LiNi0.5Mn0.5O2 cathode materials for lithium-ion batteries

Autorzy

Murali N. , Babu K. V. , Babu K. E. , Veeraiah V.

Wybrane pełne teksty z tego czasopisma

Identyfikatory

DOI

10.1515/msp-2016-0038

Warianty tytułu

Języki publikacji

Abstrakty

Layered oxide LiMO₂ (Ni, Co, Mn) have been proposed as cathode materials for lithium-ion batteries. Mainly LiNiO₂ is accepted as an attractive cathode material because of its various advantages such as low cost, high discharge capacity, good reversibility. The LiNi_0.5 Mn_0.5 O₂ powders are synthesized by a sol-gel method using citric acid as a chelating agent. The structure of the synthesized material is analyzed by using XRD, FT-IR and the microstructures of the samples are observed by using FESEM. The intensities and positions of the peaks are in a good agreement with the previous results. The morphological changes are clearly observed as a result of manganese substitution. The Fourier transform infrared (FT-IR) spectra obtained with KBr pellet data reveal the structure of the oxide lattice constituted by LiO₆ and NiO₆ octahedra. The conductivity studies are characterized by (EIS) in the frequency range of 42 Hz to 1 MHz at room temperature to 120 °C. The dielectric properties are analyzed in the framework of complex dielectric permittivity and complex electric modulus formalisms. It indicates that the conductivity increases with increasing temperature. The fitting data of EIS plots replicate the non-Debye relaxation process with negative temperature coefficient of resistance (NTCR) behavior.

Słowa kluczowe

layered structure FESEM impedance electric modulus

Wydawca

De Gruyter

Czasopismo

Materials Science Poland

Rocznik

2016

Tom

Vol. 34, No. 2

Strony

404--411

Opis fizyczny

Bibliogr. 49 poz., rys., tab.

Twórcy

autor

Murali N.

muraliphdau@gmail.com

Advanced Analytical Laboratory, Andhra University, Visakhapatnam-530003, India

autor

Babu K. V.

Advanced Analytical Laboratory, Andhra University, Visakhapatnam-530003, India

autor

Babu K. E.

Department of Physics, Andhra University, Visakhapatnam-530003, India

autor

Veeraiah V.

Department of Physics, Andhra University, Visakhapatnam-530003, India

Bibliografia

[1] Ohzuku T., Makimura Y., Chem. Lett., 30 (2001), 744.
[2] Park S.M., Cho T.H., Yoshio M., Chem. Lett., 33 (2004), 6.
[3] Rossen E., Jones C.D.W., Dahn J.R., Solid State Ionics, 57 (1992), 311.
[4] Caurant D., Baffler N., Bianchi V., Gregoire G., Bach S., J. Mater. Chem., 6 (1996), 1149.
[5] Spahr M.E., Novak P., Haas O., Nesper R., J. Power Sources, 68 (1997), 629.
[6] Lu Z., Beaulieu L.Y., Donaberger R.A., Thomas C.L., Dahn J.R., J. Electrochem. Soc., 149 (2002), A778.
[7] Wang X., Hao H., Liu J., Huang T., Yu A., Electrochim. Acta, 56 (2011), 4065.
[8] Xiao L., Liu X., Zhao X., Liang H., Liu H., Solid State Ionics, 192 (2011), 335.
[9] Manikandan P., Ananth M.V., Prem Kumar T., Raju M., Periyasamy P., Manimaran K., J. Power Sources, 196 (2011), 10148.
[10] Lu Z., Macneil D.D., Dahn J.R., Electrochem. Solid State Lett., 4 (2001), A191.
[11] Shin S.S., Sun Y.K., Amine K., J. Power Sources, 112 (2002), 634.
[12] K. Mizushima, Jones P.C., Wisemen P.J., Goodenough J.B., Mater. Res. Bull., 15 (1980) 783.
[13] Nagaura T., Ozawa T., Progr. Batteries Sol. Cells.,9 (1990), 20.
[14] Spahr M.E., Novak P., Schnyder B., Hass O., Nesper R., J. Power Sources, 68 (1997), 629.
[15] Makimura Y., Ohzuku T., J. Power Sources, 119 (1997), 156.
[16] Lu Z., Macneil D.D., Dahn J.R., Electrochem. Solid State Lett., 4 (2001), A191.
[17] Lu Z., Baulieu L.Y., Donaberger R.A., Thomas C.L., Dahn J.R., J. Electrochem. Soc., 149 (2002), A778.
[18] Reed J., Ceder G., Electrochem. Solid State Lett.,5 (2002), A145.
[19] Grey C.P., Yoon W.S., Reed J., Ceder G., Electrochem. Solid State Lett., 7 (2004), A290.
[20] Spahr M.E., Novak P., Schnyder B., Hass O., Nesper R., J. Electrochem. Soc., 145 (1998), 1113.
[21] Unit-Cell Software For Cell Refinement Method Of Tjb Holland & Sat Redfern, 1995.
[22] Li D., Sasaki Y., Kageyama M., Kobayakawa K., Sato Y., J. Power Sources., 148 (2005), 85.
[23] Li D., Muta T., Noguchi H., J. Power Sources, 135 (2004), 262.
[24] Li D., Noguchi H., Yoshio M., Electrochim. Acta, 50 (2004), 425.
[25] Sun Y., Ouyang C., Wang Z., Huang X., Chen L., J. Electrochem. Soc., 151 (2004), A504.
[26] Lu Z., Macneil D.D., Dahn J.R., Electrochem. Solid State Lett., 4 (2001), A200.
[27] Macneil D.D., Lu Z., Dahn J R., J. Electrochem. Soc., 149 (2002), A1332.
[28] Jouanneau S., Macneil D.D., Lu Z., Beattie S.D., Murphy G., Dahn J.R., J. Electrochem. Soc., 150 (2003), A1299.
[29] Bin Z., Gang C., Ping X., Zushun L., Solid State Ionics, 178 (2007) 1230.
[30] Spahr M.E., Novak P., Schnyder B., Haas O., Nesper R., J. Power Sources, 68 (1997), 629.
[31] Murali N., Vijaya B.K., Ephraim B.K., Veeraiah V., Chem. Sci. Trans., 3 (2014), 1317.
[32] Kang K., Meng Y.S., Br´ J., Grey C.P., Eger Ceder G., Science, 311 (2006), 977.
[33] Venkateswara R.A., Veeraiah V., Prasada R.A.V., Kishore B.B., Vijaya K.K., Ceram Int., 40 (2014),13911.
[34] Das T., Das B.K., Parashar K., Parashar S.K.S., Nagamalleswara R.A., Adv. Mat. Res., 938 (2014), 63.
[35] Martha S.K., Sclar H., Framowitz Z.S., Kovacheva D., Saliyski N., Gofer Y., Sharon P., Golik E., Markovsky B., Aurbach D., J. Power Sources, 189 (2009), 248.
[36] Murali N., Vijaya B.K., Ephraim B.K., Veeraiah V., Aip Conf. Proc., 1665 (2015), 140057-1.
[37] Senthil K.P., Sakunthala A., Prabu M., Reddy M.V., Joshi R., Solid State Ionics, 267 (2014), 1.
[38] Sun Y.K., Myung S.T., Bang H.J., Park B.C., Park S.J., Sung N.Y., J. Electrochem. Soc., 154 (2007), A937.
[39] Prabakaran S.R.S., Michael M.S., Radhakrishnan S., Julien C., J. Mater. Chem., 7 (1997), 1791.
[40] Prabu M., Selvasekarapandian S., Kulkarni A.R., Hirankumar G., Sanjeeviraja C., J. Rare Earth, 28 (2010), P 435.
[41] Rout S.K., Hussain A., Sinha E., Ahn C.W., Kim I.W., Solid State Sci., 11 (2009), 1144.
[42] Sahoo P.S., Panigrahi A., Patri S.K., Choudhary R.N.P., Bull. Mater. Sci., 33 (2010), 129.
[43] Padhy R., Rao N., Parashar S.K.S., Parashar K., Chaudhuri P., Solid State Ionics, 256 (2014), 29.
[44] Jha P.A., Jha P.K., Jha A.K., Dwivedi R.K., Mater Res Bull., 48 (2013), 101.
[45] Kumar P., Singh B.P., Sinha T.P., Singh N.K., Adv. Mater. Lett., 3 (2012), 143.
[46] Orliukas A., Dindune A., Kanepe Z., Solid State Ionics, 157 (2003), 177.
[47] Sambasivarao K., Madhava P.D., Murali K.P., Lee J.H., Physica B, 403 (2008), 2079.
[48] Dridi N., Boukhari A., Reau J.M., Arbib E., Holt E.M., Solid State Ionics, 127 (2000), 141.
[49] Rosaiah P., Hussain O M., Adv. Mat. Lett., 4 (2013), 288.

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-d465a826-06b1-4f53-a3b4-4ce456e4f029