The influence of the RF PACVD MS process parameters on the physicochemical properties of hydroxyapatite coatings

• Autorzy: Niedzielska A. , Skwierczyński P. , Czerniak-Reczulska M. , Szymański W.

Identyfikatory

DOI

10.1515/adms-2015-0022

• Języki publikacji: EN

Abstrakty

EN

Hydroksyapatite (HAp) as the coating, is produced using different methods of deposition, among others: laser ablation method, sol-gel, electrophoresis, thermal sputtering or magnetron spraying with the usage of high frequency. Attempts to benefit from such a wide spectrum of existing methods are related to the fact that this material possesses many advantages. We have to distinguish, among others, proper biological properties, i.e. both - high bio-tolerance and high osteo-inductivity [1,2]. However, it is worth mentioning that the material also presents disadvantages, i.e. it indicates too quick resorption within the biological environment, depending on its obtained form. In case when HAp is in the amorphous form, it undergoes a very rapid process of dissolving in the tissue environment. [3] In order to prevent the above, it is important to produce the coatings with a regulative level of cristallinity. In the presented research the hydroxyapatite coating produced using RF PACVD MS plasma method (Radio Frequency Plasma Assisted Chemical Vapor Deposition Magnetron Sputtering) possesses the above mentioned amorphous form. Nevertheless, due to the usage of ‘bubbler’, allowing for delivery of hydroxyl groups into the operating chamber, it was possible to receive the Hap coatings in a crystalline form. Changing the operating pressure (the amount of bonds - OH), during sputtering, it was checked what is the influence of that parameter on the physicochemical properties of obtained coatings. Scanning electron microscopy (SEM) was used for the founding research as well as the Roentgen Apparatus Analyser (EDS). The Phase composition of a created coating was researched using the Roentgen diffract-meter (XRD). The measures of thickness were conducted using contact-profilometry. Nano-indentation technique was used to assess the mechanical properties. Obtained results of research encourage for further researches related to the influence of hydroxyl groups on the physicochemical properties of hydroxyapatat coatings.

Słowa kluczowe

EN

magnetron sputtering; hydroxyapatite; coating; radio frequency; water vapour

• Wydawca: Politechnika Gdańska
• Czasopismo: Advances in Materials Science
• Rocznik: 2015
• Tom: Vol. 15, nr 4(46)
• Strony: 52--58
• Opis fizyczny: Bibliogr. 8 poz., rys., tab., wykr.

Twórcy

autor

Niedzielska A.

• Lodz University of Technology, Faculty of Mechanical Engineering, Institute of Materials Science and Engineering, 90-924 Łódź, Stefanowskiego 1/15 Poland

autor

Skwierczyński P.

• Lodz University of Technology, Faculty of Mechanical Engineering, Institute of Materials Science and Engineering, 90-924 Łódź, Stefanowskiego 1/15 Poland

autor

Czerniak-Reczulska M.

• Lodz University of Technology, Faculty of Mechanical Engineering, Institute of Materials Science and Engineering, 90-924 Łódź, Stefanowskiego 1/15 Poland

autor

Szymański W.

• Lodz University of Technology, Faculty of Mechanical Engineering, Institute of Materials Science and Engineering, 90-924 Łódź, Stefanowskiego 1/15 Poland

Bibliografia

• 1. Batory D., Gawroński J., Kaczorowski W., Niedzielska A., C - HAp composite layers deposited onto AISI 316 L austenitic steel. Surf. Coat. Technol. 206(8-9) (2012), 2110.
• 2. Gawroński J.: Wytwarzanie kompozytowych warstw C/HAp na potrzeby medycyny. (Preparation of composite layers C / HA p for the purposes of medicine) PhD thesis, Lodz University of Technology, Lodz (2008).
• 3. Wolke J.G.C., De Groot K., Jansen J.A.: Dissolution and adhesion behaviour of radio-frequency magnetron-sputtered Ca-P coatings. J. Mater. Sci. 33(13) (1998), 3371.
• 4. Ozeki K., Aoki H., Fukui Y.: Dissolution behavior and in vitro evaluation of sputtered hydroxyapatite films subject to a low temperature hydrothermal treatment. J. Biomed. Mater. Res. Part A, 76A (3) (2006), 605.
• 5. Walkowiak-Przybyło M., Okrój W., Walczyńska M., Skwierczyński P., Walkowiak B.: Thrombogenicity of thin layer calcium phosphate created on polished surface of Ti6Al7Nb alloy Eng of Biomater, Vol XIV (109-11), 37, (2011).
• 6. Fernandez-Pradas J.M., Cleries L., Martinez E., Sardin G., Esteve J., Morenza J.L.: Calcium phosphate coatings deposited by laser ablation at 355 nm under different substrate temperatures and water vapour pressures. Appl. Phys. Mater. Sci. Process. 71(1) (2000), 37.
• 7. Kim H., Camata R.P., Vohra Y.K., Lacefield W.R.: Control of phase composition in hydroxyapatite-tetracalcium phosphate biphasic thin coatings for biomedical applications. J Mater Sci Mater Med., 16 (10) (2005),961.
• 8. Hong Z., Luan L., Paik S., Deng B., Ellis D.E., Ketterson J.B., Mello A., Eon J.G., Terra J., Rossi A.: Crystalline hydroxyapatite thin films produced at room temperature - An opposing radio frequency magnetron sputtering approach Thin Solid Films 515 (2007), 6773.