Enrichment, Separation, and Recovery of Phosphorus from Dephosphorization Slag

Yan-Ling, Z.; Ming, G.; Feng-Shan, L.; Kan, Y.

doi:10.24425/amm.2018.125104

Artykuł - szczegóły

Tytuł artykułu

Enrichment, Separation, and Recovery of Phosphorus from Dephosphorization Slag

Autorzy

Yan-Ling Z. , Ming G. , Feng-Shan L. , Kan Y.

Treść / Zawartość

Pełne teksty:

Pobierz

Identyfikatory

DOI

10.24425/amm.2018.125104

Warianty tytułu

Języki publikacji

Abstrakty

A better understanding of phosphorus distribution in slag is necessary to develop an effective way to treat dephosphorization slag formed during steelmaking. Here, previous studies on the enrichment, separation, and recovery of phosphorus from dephosphorization slag are reviewed, along with their influencing factors. The results suggest that a proper heat treatment can promote the selective enrichment and growth of P-rich phases. Further, adding P₂O₅ and Fe_tO facilitates phosphorus enrichment. Also, Ca₃(PO₄)₂ is precipitated from slag containing 18 wt% P₂O₅. MnO and MgO in the slag barely affect the phosphorus recovery. In contrast, the addition of Al₂O₃ and TiO₂ significantly affects phosphorus enrichment and magnetic separation. A phosphorus recovery rate of more than 70% is achieved with the addition of 10 wt% Al₂O₃ or 10 wt% TiO₂. New phases (Na₂Ca₄(PO₄)₂SiO₄, Na₃PO₄, and Ca₅(PO₄)₃F) tend to be formed on the addition of Na₂O and CaF₂, which promote phosphorus enrichment. However, the addition of Na₂O and CaF₂ results in the incomplete separation of phosphorus and iron, as CaF₂ and Na₂O improve slag metallization and the magnetism of iron-rich phases.

Słowa kluczowe

phosphorus enrichment selective enrichment and growth P-rich phase magnetic separation

Wydawca

Institute of Metallurgy and Materials Science of Polish Academy of Sciences
Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences

Czasopismo

Archives of Metallurgy and Materials

Rocznik

2018

Tom

Vol. 63, iss. 4

Strony

1769--1783

Opis fizyczny

Bibliogr. 63 poz., fot., rys., wzory

Twórcy

autor

Yan-Ling Z.

University of Science and Technology Beijing, State Key Laboratory of Advanced Metallurgy Beijing 100083, China

autor

Ming G.

gaoming0309@163.com

University of Science and Technology Beijing, State Key Laboratory of Advanced Metallurgy Beijing 100083, China

autor

Feng-Shan L.

University of Science and Technology Beijing, State Key Laboratory of Advanced Metallurgy Beijing 100083, China

autor

Kan Y.

University of Science and Technology Beijing, State Key Laboratory of Advanced Metallurgy Beijing 100083, China

Bibliografia

[1] S. Jung, Y. Do, J. Choi, Steel Res. Int. 77 (2006).
[2] H. Ono, A. Inagaki, T. Masui, N. Hiroshi, N. Shoji, ISIJ Int. 21 (2), 135-144 (1980).
[3] H. J. Li, ISIJ Int. 35 (9), 1079-1088(1995).
[4] Z. J. Wang, Investigation on Physical and Chemical Properties of P-bearing Steelmaking Slags during the Selective Enrichment Process of Phosphorus. PhD thesis, University of Science & Technology Beijing, June.
[5] Z. T. Sui, B. C. Chen, in: Proceedings of the National Powder Engineering Conference, China 1998.
[6] Z. T. Sui, T. P. Lou, N. X. Fu, CN1253185, China 2000.
[7] J. Y. Li. Selective enrichment and phase separation of phosphate in steelmaking slags. PhD thesis, University of Science & Technology Beijing, December.
[8] L. Lin, Y. P. Bao, M. Wang, Ironmaking and Steelmaking 40 (7), 521-527 (2013).
[9] H. M. Zhou, Y. P. Bao, L. Lin, China Metall. 23 (1), 45-49 (2013).
[10] S. Ken-Ichi, K. Shin-Ya, H. Shibata, Tetsu-to-Hagane 49 (49), 505-511(2009).
[11] H. M. Zhou, Y. P. Bao, L. Lin, Steel Res. Int. 84 (9), 863-869 (2013).
[12] L. Lin, Y. P. Bao, M. Wang, Ironmaking and Steelmaking 21 (5), 496-502 (2014).
[13] L. C. He, Y. M. Wang, Fertilizer industry knowledge, 1975, Fuel Chemical Industry Press, Beijing(in Chinese).
[14] H. G. Jin, L. B. Yu, China Res. Comp. Util. 3, (1999).
[15] L. Lin, Y. P. Bao, M. Wang, High Temp. Mater. Proc. 35 (4), 425-432 (2016).
[16] L. Lin, Y. P. Bao, M. Wang, ISIJ Int. 54 (12), 2746-2753 (2014).
[17] J. Diao, L. Jiang, Y. Wang, Phosphorus Sulfur 190 (3), 387-395 (2014).
[18] L. S. Li, X. F. Yu, X. R. Wu, P. Soc. Photo-Opt. Ins. 10 (1), 78-81 (2006).
[19] L. S. Li, X. F. Yu, China Metal. 17 (1), 42-45 (2007).
[20] S. Fukagai, T. Hamano, F. Tsukihashi, ISIJ Int. 47 (1), 187-189 (2007).
[21] X. Yang, H. Matsuura, F. Tsukihashi, Metal. Mater. Trans. B 51 (9), 1298-1307 (2010).
[22] H. J. Guo, Metallurgical Physical Chemistry Tutorial, 2006, Metallurgical Industry Press, Beijing (in Chinese).
[23] X. G. Wu, J. N. An, J. Anhui Univ. Technology 27 (3), 233-237(2010).
[24] H. Ono, Tetsu-to-Hagane 3, (1980).
[25] K. Ito, M. Yanagisawa, N. Sano, Tetsu-to-Hagane 68 (2), 342-344 (1982).
[26] N. Wang, Z. G. Liang, M. Chen, Northeast Univ. J. 32 (6), 814-817 (2011).
[27] X. F. Dou, M. M. Zhu, T. C. Lin, Chongqing Univ. J. 38 (5), 78-82 (2015).
[28] X. Yang, H. Matsuura, F. Tsukihashi, ISIJ Int. 49 (9), 1298-1307 (2009).
[29] X. Yang, H. Matsuura, F. Tsukihashi, ISIJ Int. 50 (5), 702-711 (2010).
[30] X. Yang, H. Matsuura, F. Tsukihashi, Tetsu-to-Hagane 95 (95), 268-274 (2009).
[31] H. Suito, R. Inoue, T. Iron Steel I. Jpn. 46 (2), 180-187 (2006).
[32] R. Inoue, H. Suito, ISIJ Int. 46 (2), 174-179 (2006).
[33] C. Su, L. Z. Chang, in: Proceedings of the National Metallurgical Energy Environmental Protection Production Technology Association, China 2014.
[34] M. C. Jha, G. R. Wicker, US4110400, US 1978.
[35] P. Zhang, Z. Sui, Metall. Metal. Mater. Trans. B 26 (2), 345-351 (1995).
[36] P. K. Son, Y. Kashiwaya, Tetsu-to-Hagane 48 (9), 1165-1174 (2008).
[37] X. M. Yang, J. P. Duan, C. B. Shi, Metal. Mater. Trans. B 42 (4), 738-770 (2011).
[38] X. M. Yang, C. B. Shi, Z. Meng, Metal. Mater. Trans. B 42 (1), 951-977 (2011).
[39] Y. Liu, Q. F. Shu, Nonferrous Metal. Sci. Eng. 7 (3), 29-34 (2016).
[40] L. Lin, Y. P. Bao, Q. Yang, Ironmaking and Steelmaking 42 (3), 331-338 (2015).
[41] L. Lin, Y. P. Bao, W. Jiang, ISIJ Int. 55 (3), 552-558 (2015).
[42] L. Jiang, J. Diao, X. M. Yan, Proceedings of the National Powder Engineering Conference, China 2014.
[43] X. L. Pan, J. Y. Li, M. Guo, J. Iron Steel Res. 29 (6), 474-480 (2017).
[44] L. Jiang, J. Diao, X. M. Yan, ISIJ Int. 55 (3), 564-569 (2015).
[45] L. Lin, Y. P. Bao, M. Wang, Chinese J. Eng. 8 (1), 1013-1019 (2014).
[46] Z. M. Wang. The Study on the Separation and Growing up of Perovskite Phase from the Blast Furnace Slag Containing Titanium. PhD thesis, Northeastern University, June.
[47] G. M. Yang, X. R. Wu, L. S. Li, Can. Metall. Quart. 51 (2), 150-156 (2012).
[48] H. Ono, A. Inagaki, T. Masui, ISIJ Int. 21 (2), 135-144 (1980).
[49] H. Ono, A. Inagaki, T. Masui, H. Narita, Tetsu-to-Hagane 66 (9), 1317-1326 (1980).
[50] C. Li, J. T. Gao, F. Q. Wang, Ironmaking and Steelmaking, 1-6 (2016).
[51] C. Li, J. Gao, Z. Wang, ISIJ Int. 57 (4), 4 (2017).
[52] C. Li, J. Gao, Z. C. Guo, Metal. Mater. Trans. B 47 (3), 1516-1519 (2016).
[53] J. Gao, Y. Zhong, L. Guo, Metal. Mater. Trans. B 47 (2), 1080-1092 (2016).
[54] K. Yokoyama, H. Kubo, K. Mori, T. Iron Steel I. Jpn. 47 (10), 1541-1548 (2007).
[55] H. Kubo, M. Y. Kazuyo, T. Nagasaka, T. Iron Steel I. Jpn. 50 (1), 59-64 (2009).
[56] X. R. Wu, G. M. Yang, L. S. Li, Ironmaking and Steelmaking 41 (5), 335-341(2014).
[57] M. Y. Kazuyo, Trans. T. Iron Steel I. Jpn. 50 (3), 306-312 (2010).
[58] J. Diao, B. Xie, Y. Wang, ISIJ Int. 52 (6), 955-959 (2012).
[59] Y. H. Wang, B. Xie, J. Diao, Chinese J. Eng. 33 (3), 323-327 (2011).
[60] Z. H. Xu, Steel slag phosphate fertilizer production, 1962, China Industry Press, Beijing (in Chinese).
[61] F. S. Li, X. Li, Y. L. Zhang, Metal. Mater. Trans. B 48 (5), 1-12 (2017).
[62] F. S. Li, Y. L. Zhang, Z. Guo, JOM-Us 69 (2), 1624-1631 (2017).
[63] F. S. Li, Y. L. Zhang, Z. Guo, JOM-Us 69 (9), 1632-1638 (2017).

Uwagi

The authors would like to thank the National Natural Science Foundation of China (No. 51474021) for financial support.

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-d3f97c60-828b-4fc2-8720-cc0adb964b47