Photocrosslinkable polymer based on 4-(3-(2,4-dichlorophenyl)-3-oxoprop-1-enyl) phenylacrylate: synthesis, reactivity ratio, and crosslinking studies

• Autorzy: Suresh J. , Karthik S. , Arun A.

Identyfikatory

DOI

10.1515/msp-2016-0117

• Języki publikacji: EN

Abstrakty

EN

The acrylate monomer was synthesized by two step process. 2,4-dichloro-1-ene(4-hydroxyphenyl)phenone (DHP) was synthesized using 4-hydroxy benzaldehyde and 2,4-dichloro acetophenone. 4-[3-(2,4-dichloro-phenyl)3-oxoprop-1-en-1-yl]phenylacrylate (DCP) was prepared by reacting DHP with acryloyl chloride. The synthesized monomer was copolymerized with 2-hydroxyethyl acrylate and styrene using solution polymerization technique. Monomer and polymers were characterized by IR, NMR and UV techniques. The average molecular weight of the polymer was around 4000 g/mol. First and second decomposition temperature of the polymers was around 320 °C and 430 °C, respectively. The reactivity ratio of the polymers was calculated by Fineman-Ross, Kelen-Tudos and extended Kelen-Tudos methods. The synthesized monomer has been less reactive than the commercial monomer. The rate of photocrosslinking increased from 39 % to 99 % due to the using of copolymerization technique.

Słowa kluczowe

EN

chalcone; acrylate; reactivity ratio; photocrosslinking; copolymer

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2016
• Tom: Vol. 34, No. 4
• Strony: 834--844
• Opis fizyczny: Bibliogr. 25 poz., rys., tab.

Twórcy

autor

Suresh J.

• PG & Research Department of Chemistry, Government Arts College, Thiruvannamalai-606603. Tamilnadu, India.

autor

Karthik S.

• PG & Research Department of Chemistry, Government Arts College, Thiruvannamalai-606603. Tamilnadu, India.

autor

Arun A.

• PG & Research Department of Chemistry, Government Arts College, Thiruvannamalai-606603. Tamilnadu, India.

Bibliografia

• [1] REHAB A., SALAHUDDIN N., Polymer, 40 (1999), 2197.
• [2] KAWATZWKI N., YAMANOTO T., ONO H., Appl. Phys. Lett., 74 (1999), 935.
• [3] QI Y.H., DING J.F., MICHAEL D., JIA J., CALLENDER C.L., Polymer, 47 (2006), 8263.
• [4] CHEN H., YIN J., J. Polym. Sci. Pol. Chem., 42 (2004), 1735.
• [5] LI X.D., ZHONG Z.X., JIN G., LEE S.H., LEE M.H., Macromol. Res., 14 (2006), 257.
• [6] OHE Y., ITO H., WATANABE N., ICHIMURA K., J. Appl. Polym. Sci., 77 (2000), 2189.
• [7] PRIYAREGA S., MUTHUSAMY A., KANIAPPAN K., MURUGAVEL S.C., Des. Monomers Polym., 6 (2003), 187.
• [8] SUBRAMANIAN K., KRISHNASAMY V., NANJUNDAN S., RAMI REDDY A.V., Eur. Polym. J., 36 (2000), 2343.
• [9] BALAJI R., NANJUNDAN S., React. Funct. Polym., 49 (2001), 77.
• [10] NISHIKUBO T., KAMEYAMA A., TSUTSUI K., J. Polym. Sci. Polym. Chem., 39 (2001), 1169.
• [11] PERNY S., BARNY P.L., DELAIRE J., DOZOV I., FORGET S., AUROY P., Liq. Cryst., 27 (2000), 349.
• [12] SUBRAMANIAN K., KRISHNASAMY V., NANJUNDAN S., RAMI REDDY A.V., Eur. Polym. J., 36 (2000), 2343.
• [13] PERNY S., BARNY P.L., DELAIRE J., BUFFETEAN T., SOURISSEAN C., DOZOV I., FORGET S., MARTIENLGARDE P., Liq. Cryst., 27 (2000), 329.
• [14] XU J., RONG X., CHI T., WANG M., WANG Y., YANG D., QIU F., J. Appl. Polym. Sci., 130 (2013), 3142.
• [15] SHIRAI M., Polym. J., 46 (2014), 859.
• [16] ARUN A., REDDY B.S.R., J. Polym. Sci. Polym. Chem., 41 (2003), 1632.
• [17] ARUN A., REDDY B.S.R., J. Polym. Sci. Polym. Chem., 42 (2004), 3433.
• [18] STAMPEL G.M., CROSS R.P., MALLIELLA R.P., J. Am. Chem. Soc., 72 (1950), 2899.
• [19] SURESH J., VAKEES E., KARTHIK S., KAYALVIZHI M., ARUN A., Des. Monomers Polym., 17 (2014), 753.
• [20] ARUN A., REDDY B.S.R., Eur. Polym. J., 40 (2004), 589.
• [21] ESQUIVEL-GUZMAN ´ J.A., ZARAGOZA-GALAN ´ G., ORT´ IZ-PALACIOS J., RIVERA E., Des. Monomers Polym., 15 (2012), 561.
• [22] VIJAYANAND P.S., KATO S., KOYAMA M., SATOKAWA S., KOJIMA T., Des. Monomers Polym., 10 (2007), 375.
• [23] NISHIKUBO T., IIZAWA T., TAKAHASHI E., FUMIHIKO N., Macromolecules, 18 (1985), 2131.
• [24] LAMAITRE E., COQUERET K., MERUIER R., COMBIER A.L., LOUCHEUX C., J. Appl. Polym. Sci., 33 (1987), 2189.
• [25] RAMI REDDY A.V., SUBRAMANIAN K., SESHA SAINATH A.V., J. Appl. Polym. Sci., 70 (1998), 2111.

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).