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The potential of Georgian natural Mordenite has been studied as a low-cost, eco-friendly adsorbent for the removal of lead (II) ions from aqueous solutions in various experimental environments. The natural and modified Mordenite structural characterization was carried out using XRD, SEM-EDS, XRF, methods. The following parameters were studied for adsorption: dependence of solution pH, adsorbent dose, and initial concentration of lead (II) ions. The results of the optimization study showed that a high dose of adsorbent and a low concentration of Pb (II) ion increase the sorption. The optimum pH was found to be 6-8. Sorption capacity increased along with pH. Langmuir and Freundlich isotherms were used to model the adsorption data. Correlation coefficient values (R2) were 0.975 and 0.922, respectively. Isotherm studies showed that the uptake equilibrium is best described by the Langmuir adsorption isotherm. The maximum sorption capacity was found to be 11.439 mg/g. The research results showed that natural Georgian Mordenite can be used to remove Pb (II) ions from aqueous solutions.
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130--138
Opis fizyczny
Bibliogr. 21 poz., rys., tab.
Twórcy
autor
- Department of Physical and Analytical Chemistry, Faculty of Exact and Natural Sciences, Tbilisi State University, 1, Chavchavadze av. 0179, Tbilisi, Georgia
autor
- Department of Physical and Analytical Chemistry, Faculty of Exact and Natural Sciences, Tbilisi State University, 1, Chavchavadze av. 0179, Tbilisi, Georgia
Bibliografia
- 1. Ahmadi, H., Hafiz, S.S., Sharifi, H., Rene, N.N., Habibi, S.S., Hussain, S. 2022. Low cost biosorbent (Melon Peel) for effective removal of Cu (II), Cd (II), and Pb (II) ions from aqueous solution. Case Studies in Chemical and Environmental Engineering, 6. https://doi.org/10.1016/j.cscee.2022.100242
- 2. Amy, G., Ghaffour, N., Li, Z., Francis, L., Linares, R.V., Missimer, T. Lattemann, S. 2017. Membrane-based seawater desalination: Present and future prospects. Desalination, 401, 16–21. https://doi.org/10.1016/J.DESAL.2016.10.002
- 3. Arshadi, M., Amiri, M.J., Mousavi, S. 2014. Kinetic, equilibrium and thermodynamic investigations of Ni(II), Cd(II), Cu(II) and Co(II) adsorption on barley straw ash. Water Resources and Industry, 6, 1–17. https://doi.org/10.1016/J.WRI.2014.06.001
- 4. Ayodhya, D. 2023. Recent progress on detection of bivalent, trivalent, and hexavalent toxic heavy metal ions in water using metallic nanoparticles: A review. Results in Chemistry, 5. https://doi.org/10.1016/j.rechem.2023.100874
- 5. DeMessie, J.A., Sorial, G.A., Sahle-Demessie, E. 2022. Removing chromium (VI) from contaminated water using a nano-chitosan–coated diatomaceous earth. Separation Science and Technology (New York), 15, 163–176. https://doi.org/10.1016/B978-0-323-90763-7.00005-6
- 6. Fawcett-Hirst, W., Temple, T.J., Ladyman, M.K., Coulon, F. 2021. A review of treatment methods for insensitive high explosive contaminated wastewater. Heliyon, 7(7), e07438. https://doi.org/10.1016/j.heliyon.2021.E07438
- 7. Georgescu, A.M., Nardou, F., Zichil, V., Nistor, I.D. 2018. Adsorption of lead(II) ions from aqueous solutions onto Cr-pillared clays. Applied Clay Science, 152, 44–50. https://doi.org/10.1016/j.clay.2017.10.031
- 8. Guo, X., Wang, J. 2019a. Comparison of linearization methods for modeling the Langmuir adsorption isotherm. Journal of Molecular Liquids, 296, 111850. https://doi.org/10.1016/J.MOLLIQ.2019.111850
- 9. Guo, X., Wang, J. 2019b. Comparison of linearization methods for modeling the Langmuir adsorption isotherm. Journal of Molecular Liquids, 296, 111850. https://doi.org/10.1016/J.MOLLIQ.2019.111850
- 10. Hu, H., Xu, K. 2020. Physicochemical technologies for HRPs and risk control. High-Risk Pollutants in Wastewater, 169–207. https://doi.org/10.1016/B978-0-12-816448-8.00008-3
- 11. Huang, Y., Wang, W., Feng, Q., Dong, F. 2017. Preparation of magnetic clinoptilolite/CoFe2O4 composites for removal of Sr2+ from aqueous solutions: Kinetic, equilibrium, and thermodynamic studies. Journal of Saudi Chemical Society, 21(1), 58–66. https://doi.org/10.1016/J.JSCS.2013.09.005
- 12. Huntley, G.M., Luck, R.L., Mullins, M.E., Newberry, N.K. 2021. Hydrochloric acid modification and lead removal studies on naturally occurring zeolites from Nevada, New Mexico, and Arizona. Processes, 9(7). https://doi.org/10.3390/pr9071238
- 13. Khan, S., Idrees, M., Bilal, M. 2021. Revealing and elucidating chemical speciation mechanisms for lead and nickel adsorption on zeolite in aqueous solutions. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 623. https://doi.org/10.1016/j.colsurfa.2021.126711
- 14. Li, X., Zhang, D., Sheng, F., Qing, H. 2018. Adsorption characteristics of Copper (II), Zinc (II) and Mercury (II) by four kinds of immobilized fungi residues. Ecotoxicology and Environmental Safety, 147, 357–366. https://doi.org/10.1016/J.ECOENV.2017.08.058
- 15. Manyangadze, M., Chikuruwo, N.M.H., Narsaiah, T.B., Chakra, C.S., Charis, G., Danha, G., Mamvura, T.A. 2020. Adsorption of lead ions from wastewater using nano silica spheres synthesized on calcium carbonate templates. Heliyon, 6(11). https://doi.org/10.1016/j.heliyon.2020.e05309
- 16. Matouq, M., Jildeh, N., Qtaishat, M., Hindiyeh, M., Al Syouf, M.Q. 2015b. The adsorption kinetics and modeling for heavy metals removal from wastewater by Moringa pods. Journal of Environmental Chemical Engineering, 3(2), 775–784. https://doi.org/10.1016/J.JECE.2015.03.027
- 17. Ofudje, E.A., Adeogun, I.A., Idowu, M.A., Kareem, S.O., Ndukwe, N.A. 2020. Simultaneous removals of cadmium(II) ions and reactive yellow 4 dye from aqueous solution by bone meal-derived apatite: kinetics, equilibrium and thermodynamic evaluations. Journal of Analytical Science and Technology, 11(1). https://doi.org/10.1186/s40543-020-0206-0
- 18. Ogunlalu, O., Oyekunle, I.P., Iwuozor, K.O., Aderibigbe, A.D., Emenike, E.C. 2021. Trends in the mitigation of heavy metal ions from aqueous solutions using unmodified and chemically-modified agricultural waste adsorbents. In Current Research in Green and Sustainable Chemistry. Elsevier B.V., 4. https://doi.org/10.1016/j.crgsc.2021.100188
- 19. Sahu, J.N., Kapelyushin, Y., Mishra, D.P., Ghosh, P., Sahoo, B.K., Trofimov, E., Meikap, B.C. 2023. Utilization of ferrous slags as coagulants, filters, adsorbents, neutralizers/stabilizers, catalysts, additives, and bed materials for water and wastewater treatment: A review. Chemosphere, 325, 138201. https://doi.org/10.1016/j.chemosphere.2023.138201
- 20. Zhang, Y., Alessi, D.S., Chen, N., Luo, M., Hao, W., Alam, M.S., Konhauser, K.O., Ok, Y.S., Al-Tabbaa, A. 2021. Spectroscopic and Modeling Investigation of Sorption of Pb(II) to ZSM-5 Zeolites. ACS Environmental Science and Technology Water, 1(1), 108–116. https://doi.org/10.1021/acsestwater.0c00010
- 21. Zhu, P., Meier, S., Saravanamurugan, S., Riisager, A. 2021. Modification of commercial Y zeolites by alkaline-treatment for improved performance in the isomerization of glucose to fructose. Molecular Catalysis, 510. https://doi.org/10.1016/j.mcat.2021.111686
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d2b9fb7f-433b-4ec8-a8d3-e52aff335506