Response surface methodology (RSM) and its application for optimization of ammonium ions removal from aqueous solutions by pumice as a natural and low cost adsorbent

• Autorzy: Moradi M. , Fazlzadehdavil M. , Pirsaheb M. , Mansouri Y. , Khosravi T. , Sharafi K.

Identyfikatory

DOI

10.1515/aep-2016-0018

• Języki publikacji: EN

Abstrakty

EN

This research was conducted to study the adsorption of ammonium ions onto pumice as a natural and low-cost adsorbent. The physico-chemical properties of the pumice granular were characterized by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Modeling and optimization of a NH₄+ sorption process was accomplished by varying four independent parameters (pumice dosage, initial ammonium ion concentration, mixing rate and contact time) using a central composite design (CCD) under response surface methodology (RSM). The optimum conditions for maximum removal of NH₄+ (70.3%) were found to be 100 g, 20 mg/l, 300 rpm and 180 min, for pumice dosage, initial NH₄+ ion concentration, mixing rate and contact time. It was found that the NH₄+ adsorption on the pumice granular was dependent on adsorbent dosage and initial ammonium ion concentration. NH₄+ was increased due to decrease the initial concentration of NH₄ and increase the contact time, mixing rate and amount of adsorbent.

Słowa kluczowe

EN

pumice; ion adsorption; response surface methodology

• Wydawca: Institute of Environmental Engineering, Polish Academy of Sciences
• Czasopismo: Archives of Environmental Protection
• Rocznik: 2016
• Tom: Vol. 42, no. 2
• Strony: 33--43
• Opis fizyczny: Bibliogr. 28 poz., rys., tab., wykr.

Twórcy

autor

Moradi M.

• Iran University of Medical Sciences, Iran School of Public Health, Department of Environmental Health Engineering

autor

Fazlzadehdavil M.

• Ardabil University of Medical Sciences, Iran School of Public Health, Department of Environmental Health Engineering

autor

Pirsaheb M.

• Kermanshah University of Medical Sciences, Iran School of Public Health, Research Centre for Environmental Determinacies of Health

autor

Mansouri Y.

• Kermanshah University of Medical Sciences, Iran School of Public Health, Research Centre for Environmental Determinacies of Health

autor

Khosravi T.

• Kermanshah University of Medical Sciences, Iran School of Public Health, Research Centre for Environmental Determinacies of Health

autor

Sharafi K.

• Kermanshah University of Medical Sciences, Iran School of Public Health, Research Centre for Environmental Determinacies of Health
• Tehran University of Medical Sciences, Iran School of Public Health, Department of Environmental Health Engineering

Bibliografia

• [1]. Akbal, F. (2005) Adsorption of basic dyes from aqueous solution onto pumice powder, Journal of colloid and interface science, 286(2), pp. 455–458.
• [2]. Arslan, A. & Veli, S. (2012) Zeolite 13X for adsorption of ammonium ions from aqueous solutions and hen slaughterhouse wastewaters, Journal of the Taiwan institute of chemical engineers, 43(3), pp. 393–398.
• [3]. Bandosz, T.J. & Petit, C. (2009) On the reactive adsorption of ammonia on activated carbons modified by impregnation with inorganic compounds, Journal of colloid and interface science, 338(2), pp. 329–345.
• [4]. Bardakçi, B. & Bahçeli, S. (2010) FTIR study of modification of transition metal on zeolites for adsorption, Indian Journal of Pure & Applied Physics, 48, pp. 615–620.
• [5]. Baş, D. & Boyacı, İ.H. (2007) Modeling and optimization I: Usability of response surface methodology Journal of Food Engineering, 78(3), pp. 836–845.
• [6]. Bekaroglu, S.K., Yigit, N., Karanfil, T. & Kitis, M. (2010) The adsorptive removal of disinfection by-product precursors in a high-SUVA water using iron oxide-coated pumice and volcanic slag particles, Journal of Hazardous Materials, 183(1), pp. 389–394.
• [7]. Bolen, W.P. (2003) Pumice and pumicite. US Geological Survey Minerals Yearbook.
• [8]. Box, G.E. & Draper, N.R. (1987) Empirical model-building and response surfaces, Wiley New York 1987.
• [9]. Demir, A., Gunay, A. & Debik, E. (2002) Ammonium removal from aqueous solution by ion-exchange using packed bed natural zeolite, Water SA, 28(3), pp. 329–336.
• [10]. Ersoy, B., Sariisik, A., Dikmen, S. & Sariisik, G. (2010) Characterization of acidic pumice and determination of its electrokinetic properties in water, Powder Technology, 197(1), pp. 129–135.
• [11]. Grim, R.E. (1968) Clay mineralogy. McGraw-Hill Book Company, New York, 596.
• [12]. Gunduz, L., Sariisik, A., Tozacan, B., Davraz, M., Ugur, I. & Cankiran, O. (1998) Pumice technology. Skin 1.
• [13]. Karapınar, N. (2009) Application of natural zeolite for phosphorus and ammonium removal from aqueous solutions, Journal of hazardous materials, 170(2), pp. 1186–1191.
• [14]. Khosravi, R., Fazlzadehdavil, M., Barikbin, B. & Taghizadeh, A.A. (2014) Removal of hexavalent chromium from aqueous solution by granular and powdered Peganum Harmala, Applied Surface Science, 292, pp. 670–677.
• [15]. Khuri, A.I. & Cornell, J.A. (1996) Response surfaces: designs and analyses, CRC press 1996.
• [16]. Kusic, H., Koprivanac, N. & Bozic, A.L. (2011) Treatment of chlorophenols in water matrix by UV/ferrioxalate system: Part I. Key process parameter evaluation by response surface methodology, Desalination, 279(1), pp. 258–268.
• [17]. Lee, K.-M. & Gilmore, D.F. (2005) Formulation and process modeling of biopolymer (polyhydroxyalkanoates: PHAs) production from industrial wastes by novel crossed experimental design, Process Biochemistry, 40(1), pp. 229–246.
• [18]. Lura, P., Bentz, D.P., Lange, D.A., Kovler, K. & Bentur, A. (2004) Pumice aggregates for internal water curing, pp. 22–24, RILEM Publications SARL Evanston.
• [19]. Mansouri, Y., Zinatizadeh, A.A., Mohammadi, P., Irandoust, M., Akhbari, A. & Davoodi, R. (2012) Hydraulic characteristics analysis of an anaerobic rotatory biological contactor (AnRBC) using tracer experiments and response surface methodology (RSM), Korean Journal of Chemical Engineering, 29(7), pp. 891–902.
• [20]. Mason, R.L., Gunst, R.F. & Hess, J.L. (2003) Statistical design and analysis of experiments: with applications to engineering and science, John Wiley & Sons 2003.
• [21]. Moraci, N. & Calabrò, P.S. (2010) Heavy metals removal and hydraulic performance in zero-valent iron/pumice permeable reactive barriers, Journal of Environmental Management, 91(11), pp. 2336–2341.
• [22]. Ozturk, B. & Yildirim, Y. (2008) Investigation of sorption capacity of pumice for SO 2 capture, Process Safety and Environmental Protection, 86(1), pp. 31–36.
• [23]. Panuccio, M.R., Sorgonà, A., Rizzo, M. & Cacco, G. (2009) Cadmium adsorption on vermiculite, zeolite and pumice: batch experimental studies, Journal of Environmental Management, 90(1), pp. 364–374.
• [24]. Pirsaheb, M., Dargahi, A., Hazrati, S. & Fazlzadehdavil, M. (2014) Removal of diazinon and 2, 4-dichlorophenoxyacetic acid (2, 4-D) from aqueous solutions by granular-activated carbon, Desalination and Water Treatment, 52(22–24), pp. 4350–4355.
• [25]. Vassileva, P. & Voikova, D. (2009) Investigation on natural and pretreated Bulgarian clinoptilolite for ammonium ions removal from aqueous solutions, Journal of hazardous materials, 170(2), pp. 948–953.
• [26]. Wang, M., Liao, L., Zhang, X., Li, Z., Xia, Z. & Cao, W. (2011) Adsorption of low-concentration ammonium onto vermiculite from Hebei province, China, Clays and Clay Minerals, 59(5), pp. 459–465.
• [27]. Yuan, L. & Kusuda, T. (2005) Adsorption of ammonium and nitrate ions by poly (N-isopropylacrylamide) gel and poly (N-isopropylacrylamide-co-chlorophyllin) gel in different states, Journal of applied polymer science, 96(6), pp. 2367–2372.
• [28]. Zhu, K., Fu, H., Zhang, J., Lv, X., Tang, J. & Xu, X. (2012) Studies on removal of NH4+-N from aqueous solution by using the activated carbons derived from rice husk, Biomass and bioenergy, 43, pp. 18–25.

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.