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Influence of pH in AOP on Humic Compounds Removal from Municipal Landfill Leachate Concentrate after Reverse Osmosis

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The choice of the optimal method of municipal waste landfill leachate treatment should take into account such factors as: the variability of their composition and quantity over time, requirements for effluent or economic capacity. Due to the variety of compounds found in landfill leachate, it is advised to use a combination of different treatment processes. Biological methods are effective in the treatment of leachates from young landfills, but generally their efficiency declines significantly with the age of the landfill. Therefore, the physicochemical methods, i.e. advanced oxidation, adsorption, membrane methods or a combination of the mentioned, are preferred. The aim of the study was the assessment of the Fenton’s reagent utilization to process reverse osmosis concentrate of leachates collected from municipal non-hazardous waste landfill. The research was focused on the influence of pH on the process. Additionally, the effectiveness of organic compounds removal, increasing the biodegradability, as well as humic substances transformations were determined. The concentrations of humic compounds were measured by means of optical density at the wavelengths: 254, 265, 280, 320, 465 and 665 nm. In the experiment, the H2O2/Fe2+ 10: 1 ratio was tested at with a dose of H2O2 equal to 3.4 g/l (0.1 M). It was found that the pH affects the efficiency of COD removal and the increase of the biodegradability of the landfill leachate retentate, as well as the removal of humic substances and its transformation. It was found that at pH 3, the highest removal of COD occurs, with simultaneous increase in biodegradability, and decrease of absorbance caused by humic compounds.
Słowa kluczowe
Rocznik
Strony
161--168
Opis fizyczny
Bibliogr. 20 poz., rys.
Twórcy
  • University of Rzeszow, Faculty of Biology and Agriculture, Department of Biological Basis of Agriculture and Environmental Education, ul. Cwiklinskiej 1a, 35-601 Rzeszow, Poland
  • University of Rzeszow, Faculty of Biology and Agriculture, Department of Biological Basis of Agriculture and Environmental Education, ul. Cwiklinskiej 1a, 35-601 Rzeszow, Poland
Bibliografia
  • 1. Chai X.L., Hao Y.Z., Liu G.X., Zhao X., Zhao Y.C. 2013. Spectroscopic studies of the effect of aerobic conditions on the chemical characteristics of humic acid in landfill leachate and its implication for the environment. Chemosphere, 91, 1058–1063.
  • 2. Chen J., Gu B., LeBooeuf E., Pan H., Dai S. 2002. Spectroscopic characterization of the structural and functional properties of natural organic matter fractions. Chemosphere, 48, 59–68.
  • 3. Chmiel A. 2009. The influence of biochemical transformations on their susceptibility to coagulation. PhD thesis (in Polish). Politechnika Wrocławska, Wydział Inżynierii Środowiska, Wrocław.
  • 4. DIN EN 26777, Water Quality – Determination of Nitrite – Molecular Adsorption Spectiometric Method, Beuth Verlag, Berlin, Germany 1993.
  • 5. Gracia R., Aragues J.L., Ovelleiro J.L. 1996. Study of the catalytic ozonation of humic substances in water and their ozonation byproducts. Ozone: Science & Engineering, 18, 195–208.
  • 6. Helms J.R., Stubbins A., Ritchie J.D., Minor E.C., Kieber D.J., Mopper K. 2008. Absorption spectral slopes and slope ratios as indicators of molecular weight, source, and photobleaching of chromophoric dissolved organic matter. Limnology & Oceanography, 53, 955–969.
  • 7. Hermanowicz W., Dojlido J., Dożańska W., Koziorowski B., Zerbe J. 1999. Physico-chemical exam ination of water and sewage (in Polish). Arkady, Warszawa.
  • 8. Huang C.P., Dong C., Tang Z. 1993. Advance chemical oxidation: its present role and potential future in hazardous waste treatment. Waste Management, 13, 361–377.
  • 9. Ince M., Senturk E., Onkal Engin G., Keskinler B. 2010. Further treatment of landfill leachate by nanofiltration and microfiltration – PAC hybrid process. Desalination, 255, 52–60.
  • 10. Koc-Jurczyk J. 2014. Removal of refractory pollutants from landfill leachate using two-phase system. Water Environtal Research, 86, 74–80.
  • 11. Koc-Jurczyk J., Jurczyk Ł. 2017. Biological treatment of landfill leachate at elevated temperature in the presence of polyurethane foam of various porosity. Clean – Soil, Air, Water, 45, 1–8.
  • 12. Miklos D.B., Remy C., Jekel M., Linden K.G., Drewes J.E., Hübner U. 2018. Evaluation of advanced oxidation processes for water and wastewater treatment – A critical review. Water Research, 139, 118–131.
  • 13. Neyens E., Baeyens J. 2003. A review of classic Fenton’s peroxidation as an advanced oxidation technique. Journal of Hazardous Materials, 98, 33–50.
  • 14. Polish Standard PN-ISO 6060:2006. Water quality – Determination of chemical oxygen demand.
  • 15. Renou S., Givaudan J.G., Poulain S., Dirassouyan F., Moulin, P. 2008. Landfill leachate treatment: Review and opportunity. Journal of Hazardous Materials, 150, 468–493.
  • 16. Singh S.K., Tang W.Z. 2013. Statistical analysis of optimum Fenton oxidation conditions for landfill leachate treatment. Waste Management, 33, 81–88.
  • 17. Umar M., Aziz H.A., Yusoff M.S. 2010. Trends in the use of Fenton, electro-Fenton and photoFenton for the treatment of landfill leachate. Waste Management, 30, 2113–2121.
  • 18. Wang H.W, Li X.Y., Hao Z.P., Sun Y.J., Wang Y.N., Li W.H., Tsang Y.F. 2017. Transformation of dissolved organic matter in concentrated leachate from nanofiltration during ozone-based oxidation processes (O3, O3/H2O2 and O3/UV). Journal of Environmental Management, 191, 244–251.
  • 19. Wang Z., Peng Y., Miao L., Cao T., Zhang F., Wang S., Han J. 2016. Continuous-flow combined process of nitritation and ANAMMOX for treatment of landfill leachate. Bioresource Technology, 214, 514–519.
  • 20. Zhao X., Wei X., Xia P., Liu H., Qu J. 2013. Removal and transformation characterization of refractory components from biologically treated landfill leachate by Fe2+/NaClO and Fenton oxidation. Separation and Purification Technology, 116, 107–113.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d0a5309c-f262-4a6c-87c1-6f855c2afa0e
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