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Abstrakty
This work is focused on dewatering of barite-containing clay waste from a barite beneficiation plant by coagulation and flocculation to enhance the dewatering rate and recycling of process water. A flocculation performance of co-polymers (Superfloc A-130 and A-100) was compared with coagulants (Al2SO418H2O, CaCl2 and FeCl36H2O). The best results were obtained with an anionic co-polymer, i.e. Superfloc A-130. The settling rate increased 635-fold in the case of using anionic co-polymer Superfloc A-130 in comparison with the natural settling rate of the same wastewater. In laboratory tests, an optimum thickener design was developed for the barite clay wastewater. In this paper, sedimentation studies on the barite clay wastes are presented for the first time, both as the laboratory studies and industrial applications.
Słowa kluczowe
Rocznik
Tom
Strony
351--364
Opis fizyczny
Bibliogr. 24 poz., rys., tab.
Twórcy
autor
- Department of Polymer Engineering, Hitit University, Corum, Turkey
Bibliografia
- 1. ABD-EL RAHMAN M.K., 2000, Dewatering of phosphatic clay waste by flocculation, Chemical Engineering Technology, 23(5): 457–461.
- 2. CENGIZ I., SABAH E., OZGEN S., AKYILDIZ H., 2009, Flocculation of fine particles in ceramic wastewater using new types of polymeric flocculants, Journal of Applied Polymer Science, 112: 1258–1264.
- 3. DENIZ V., 2000, Recovery of barite from BASER Co. barite processing plant slimes by using MGS, GEOSOUND Science Technology Bulletin Earth Science, 36: 207–212.
- 4. DENIZ, V., 2013, Use of co-polymer flocculants for eliminate of the environmental effects of wastewater of a coal washer and design of a thickener for supplies of fresh water, Energy Sources (Part A): Recovery, Utilization, and Environmental Effects, 35 (22): 2132–2140.
- 5. ERSOY B., 2011. Influence of pH and chloride-based metal salts on coagulation/dispersion behavior of talc suspension, Separation Science & Technology, 46: 1519–1527.
- 6. FOWLER M., MORKEL J., 2010, The effect of cation and organic addition on the settling and compaction behaviour of clay-rich slimes, Journal of South Africa Intuition Mining & Metallurgy, 110: 99–106.
- 7. GREGORY J., 1985, The use of polymeric flocculants, Proceedings of the Engineering Foundation Conferences on Flocculation, Sedimentation and Consolidation, Georgia, USA, American Institute of Chemical Engineer, New York, USA, 253–263.
- 8. HOGG R., 2000, Flocculation and dewatering, International Journal of Mineral Processing, 58: 223–236.
- 9. KOMINEK E.G., LASH L.D., 1979, Sedimentation, Handbook of Separation Techniques for Chemical Engineers (ed. by Schweitzer, P.A), McGraw-Hill, New York.
- 10. KURSUN I., 2010, Determination of flocculation and adsorption-desorption characteristic of a Na-feldspar concentrate in the presence of different polymers, Physicochemical Problems of Mineral Processing, 44(1), 127−142.
- 11. KURAMA H., KARAGUZEL C., 2012, The effect of zeta potential on the sedimentation behavior of natural stone processing effluent, Physicochemical Problems of Mineral Processing, 49(2), 575−586.
- 12. NASSER M.S., JAMES A.E., 2006, The effect of polyacrylamide charge density and molecular weight on the flocculation and sedimentation behaviour of kaolinite suspensions, Separation Purification Technology, 52: 241–252.
- 13. OZKAN A., 2003, Coagulation and flocculation characteristics of talc by different flocculants in the presence of cations, Minerals Engineering, 16: 59–61.
- 14. PATIENCE M., ADDAI-MENASH J., RALSTON J., 2003, Investigation of the effect of polymer type on flocculation, rheology and dewatering behaviour of kaolinite dispersions, International Journal of Mineral Processing, 71: 247–268.
- 15. RICHARDSON P.F., CONNELY L.J., 1988, Industrial coagulant and flocculants, Reagents in mineral technology (Eds. by Somasundaran P. & Modugil B.M), Surfactant Science Series, 27: 519–528.
- 16. SABAH E., ACIKSOZ C., 2012, Flocculation performance of fine particles in travertine slime suspension, Physicochemical Problems of Mineral Processing, 48(2), 555−566.
- 17. SABAH E., YESILKAYA L., 2000, Evaluation of the settling behavior of Kırka borax concentrator tailings using different type of polymers, Journal of Ore Dressing, 2: 1–12.
- 18. SCHEINER B.J., WILEMON G.M., 1987. Applied flocculation efficiency: a comparison of polyethylene oxide and polyacrylamides, Flocculation in Biotechnology & Separation Systems. 4: 175–185.
- 19. SINGH B.P., BESRA L., PRASAD A.R., 1999, Coagulation and flocculation study of iron ore fines, Separation Science & Technology, 34(5): 743–753.
- 20. SOMASUNDARAN P., MOUDGIL B.M., 1988, Reagents in Mineral Technology, 27, Marcel–Dekker, New York.
- 21. TAO D., PAREKH B.K., ZHAO Y., ZHANG P., 2010, Pilot-scale demonstration of Deep ConeTM paste thickening process for phosphatic clay/sand disposal, Separation Science & Technology, 45: 1418–1425.
- 22. TALMAGE W.B., FITCH E.B., 1958, Determining thickener unit areas, Industrial Engineering Chemical, 47: 38–41.
- 23. TUNCAN A. 1995, Determination of physico-chemical properties of some clay minerals in laboratory, Seventh National Clay Symposium, Ankara/Turkey, 187–199 (in Turkish).
- 24. WENTWORTH C.K., 1922, A scale of grade and class terms for clastic sediments, Journal of Geology, 30: 377–392.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d07cb0f6-095d-4e25-a1c8-c8f2cb280997