Dwuwymiarowa chromatografia gazowa – rozwój techniki na przestrzeni lat

• Autorzy: Gąsior D.

Warianty tytułu

EN

Two-dimensional gas chromatography – technique development over the years

• Języki publikacji: PL

Abstrakty

PL

Dwuwymiarowa chromatografia gazowa jest prężnie rozwijającą się techniką analityczną, charakteryzuje się zwiększoną zdolnością rozdzielczą oraz większą czułością w porównaniu do standardowej jednowymiarowej techniki chromatografii gazowej, co pozwala na znaczne obniżenie granicy wykrywalności analitów. Bardzo dobrze sprawdza się w przypadku analiz skomplikowanych próbek o złożonym składzie. W pracy scharakteryzowana została zasada, w oparciu o którą funkcjonuje dwuwymiarowa chromatografia gazowa, ze szczególnym uwzględnieniem budowy modulatorów jako istoty całego systemu. Omówiony został sposób prezentacji wyników oraz etap ich wizualizacji. Technika dwuwymiarowej chromatografii gazowej wykorzystywana jest coraz powszechniej, między innymi w analizie produktów ropopochodnych, analizie środowiskowej do oznaczania związków toksycznych dla organizmów, w analizie produktów żywnościowych oraz w kryminalistyce. W artykule przedstawiono wybrane przykłady aplikacyjne omawianej techniki.

EN

Two-dimensional gas chromatography is rapidly developing analytical technique, which is characterized by an increased resolving ability and higher sensitivity compared to standard technique of one-dimensional gas chromatography, which allows for a significant reduction in the limit of detection of analytes. This technique is ideally suited for the analysis of complicated samples with complex composition. The paper characterizes the principle of functioning of the two-dimensional gas chromatography, with particular emphasis on the construction of modulators, which are the essence of the system. Presentation of the results and the step of visualization were explained. Two-dimensional gas chromatography technique is increasingly popular, inter alia, in the petroleum products analysis, environmental analysis for the determination toxic compounds to the organisms, in the food products analysis and in the criminology. The article presents some examples of application of the technique.

Słowa kluczowe

PL

analiza chemiczna; chromatografia gazowa; chromatografia dwuwymiarowa; modulacja; rozdzielczość; technika „hart-cutting”

EN

chemical analysis; gas chromatography; two-dimensional chromatography; modulation; resolution; heart-cutting method

• Wydawca: Wydawnictwo Instytut Śląski Sp. z o.o.
• Czasopismo: Prace Instytutu Ceramiki i Materiałów Budowlanych
• Rocznik: 2013
• Tom: R. 6, nr 13
• Strony: 22--36
• Opis fizyczny: Bibliogr. 54 poz., rys., wykr.

Twórcy

autor

Gąsior D.

• Instytut Ceramiki i Materiałów Budowlanych, Warszawa, Oddział Inżynierii Procesowej Materiałów Budowlanych, Opole

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