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Viscosity calculations of mold slag in continuous casting

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Wybrane pełne teksty z tego czasopisma
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Purpose: This paper deals with the mold slag viscosity calculations. Design/methodology/approach: The study involved the analysis of the impact of the chemical composition and temperature on the viscosity. Calculations were performed using models Riboud - Zhao, Urbain, Kondratiev and the computer program FactSage using module viscosity. The results of this works charakterize the effect of temperature, addition of CaF2 and Na2O on the viscosity for two types of slag. Findings: Slag 1 contained CaO/SiO2 = 0.78 and the addition of Na2O, slag 2 contained CaO/SiO2 = 1.32 wihout Na2O addition. Computer simulations revealed differences in the obtained values of viscosity. The use of the classical models: Riboud - Zhao and Urbain showed that at temperature 1200°C slag 2 contains larger content of CaO has the lowest viscosity at temperature 1500°C. The addition CaF2 causes a similar effect on viscosity of both slags. The use of the Fact Sage software showed that the addition of Na2O has a large influence on the viscosity. Slag 2 CaO/SiO2 = 1.32 although more than slag 1 is obtained at temperature 1500°C higher viscosity values. Research limitations/implications: Mathematical modeling of liquid mold slag viscosity based on classical and structural models and with the use of commercial software requires verification methods using scanning microscopy and nuclear magnetic resonance. Practical implications: The computer calculations of the mold slag viscosity shown that the selection of the chemical composition of the slag is important for the species of the cast steel and the speed of casting. Results of calculations show that the change in viscosity of the slag in the process result from the content composition: CaO/SiO2, CaF2 and Na2O content. Originality/value: The results of the calculations indicate the reaction of CaF2 with Na2O, probably results of this reaction is NaF, which prevents the formation of cuspidine which has a high melting point, its presence increases the melting point of the slag.
Rocznik
Strony
164--170
Opis fizyczny
Bibliogr. 15 poz.
Twórcy
autor
  • Faculty of Foundry Engineering, University of Science and Technology, ul. Reymonta 23, 30-059 Kraków, Poland
Bibliografia
  • [1]Y.A. Meng, B.G. Thomas, Modelling transient slag - layer phenomena in the shell – mold gap in continuous casting of steel, Metallurgical and Materials Transactions B 34 (2003) 707 725.
  • [2]A. Yamauchi, T. Emi, S. Seetharaman, A mathematical model for prediction of thickness of mould flux film for continuous casting mold, ISIJ International 42 (2002) 1084-1093.
  • [3]Y. Meng, B.G. Thomas, A.A. Polycarpou, A. Prasad, H. Henein, Mould slag property measurements to characterize CC mould - shell gap phenomena, Canadian Metallurgical Quartely 45 (2006) 79 94.
  • [4]G. Eriksson, A.D. Pelton, Critical evaluation and optimisation of the thermodynamic properties and phase diagrams of the CaO - Al2O3, Al2O3 - SiO2 and CaO - SiO2 - Al2O3 systems, Metallurgical and Materials Transactions 24B (1993) 807-816.
  • [5]Ch.H. Choi, S.-K. Jo, S.-H. Kim, K.-R. Lee, J.-T. Kim, Effect of CaF2 on thermodynamics of CaO - CaF2 - SiO2 - MgO slags, MetMetallurgical and Materials Transactions B 35 (2004) 115-120.
  • [6]K.C. Mills, The estimation of slag proporties,Short course presented as part of Southern African Pyrometallurgy, 2011.
  • [7]L. Forsbacka, Doctoral Thesis, Helsinki University of Technology, Departament of Materials Science and Engineering, TKK-MT-196, 2007.
  • [8]L. Forsbacka, L. Holappa, A. Kondratiev, E. Jak, Experimental study and modeling of viscosity of chromium containing slags, Steel Reserch International 78 (2007) 129-136.
  • [9]A. Kondratiev, P. Hayes, E. Jak, Development of quasi - chemical viscosity model for fully liquid slags in the Al2O3 - CaO - FeO - MgO - SiO2 system, Materials Engineering. [10]www.factsage.com, 15.09.2012.
  • [11]S. Sukenaga, N. Sato, K. Kawakami, K. Nakashima, Viscosities of CaO-SiO2-Al2O3 (R2O or RO Melts), ISIJ International 46 (2006) 352-358.
  • [12]M. Nakamoto, Y. Miyabayashi, L. Holappa, T. Tanaka,A model for estimating viscosities of aluminosilicate melts containing alkali oxides, ISIJ International 47 (2007) 1409-1415. [13]A. Kondratiev, E. Jak, Review of experimental data and modeling of the viscosities of fully liquid slags in the Al2O3-CaO-FeO-SiO2 system, Metallurgical and Materials Transactions B 32 (2001) 1015-1025.
  • [14]A.I. Zaitsev, N.V. Korolyov, B.M. Mogutnov, Phase equilibria in the CaF2-Al2O3-CaO system, Journal of Materials Science 26 (1991) 1588-1600 (in Russia).
  • [15]S. Wraight, Viscosity of CaO - CuxO - MgO - SiO2 slags, Proceedings of the VII International Conference on “Molten Slags Fluxes and Salts”, The South African Institute of Mining and Metallurgy, 2004.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-d03cde1f-5346-4df5-bdd7-724d7672d58f
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