Structural and optical properties of VO2+ doped methacrylic acid ethylacrylate (MAA:EA) copolymer films

• Autorzy: Kumar Y. M. , Bhyagyasree K. , Gopal N. O. , Ramu C.

Identyfikatory

DOI

10.1515/msp-2018-0014

• Języki publikacji: EN

Abstrakty

EN

Pure and VO²⁺ doped methacrylic acid ethylacrylate (MAA:EA) copolymer films were prepared by using a solution casting method. Various techniques including X-ray diffraction, Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, scanning electron microscopy and electron paramagnetic resonance were employed for characterization of the samples. XRD patterns showed some degree of crystallinity of the doped polymer films due to interaction of the MAA:EA copolymer with VO²⁺. FT-IR spectral studies of pure and VO²⁺ doped MAA:EA copolymer films displayed significant structural changes within the doped copolymer film indicating the complexation. The optical absorbance of the pure and VO²⁺ doped films were measured in the 200 nm to 800 nm wavelength range. The values of the absorption edge and indirect band gaps were calculated. The optical band gap decreased with the increase of mol% of VO²⁺. From the EPR spectra, the spin- Hamiltonian parameters (g and A) were evaluated. The values of the spin-Hamiltonian parameters confirmed that the vanadyl ions were present in MAA:EA copolymer films as VO²⁺ molecular ions in an octahedral site with a tetragonal compression (C_4v). The morphology of the copolymer samples was examined by scanning electron microscopy. The enhanced crystalline nature of the doped copolymer was identified from SEM analysis.

Słowa kluczowe

EN

absorption edge; direct band gap; indirect band gap; methacrylic acid ethylcrylate; electron paramagnetic resonance

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2018
• Tom: Vol. 36, No. 1
• Strony: 34--41
• Opis fizyczny: Bibliogr. 32 poz., rys., tab.

Twórcy

autor

Kumar Y. M.

• Department of Physics, Vikrama Simhapuri University PG Centre, Kavali 524201, India

autor

Bhyagyasree K.

• Department of Physics, Vikrama Simhapuri University PG Centre, Kavali 524201, India

autor

Gopal N. O.

• Department of Physics, Vikrama Simhapuri University PG Centre, Kavali 524201, India

autor

Ramu C.

• Department of Physics, Vikrama Simhapuri University PG Centre, Kavali 524201, India

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).