Electrospinning of Poly(acrylonitrile-acrylic acid)/β Cyclodextrin Nanofibers and Study of their Molecular Filtration Characteristics

• Autorzy: Amiri P , Bahrami S H

Warianty tytułu

PL

Elektroprzędzenie nanowłókien poli(akrylonitrylo - kwas akrylowy)/β cyklodekstran i badanie ich molekularnych charakterystyk filtracji

• Języki publikacji: EN

Abstrakty

EN

Acrylonitrile acrylic acid copolymer was synthesised using suspension polymerisation and β-cyclodextrin was mixed with this copolymer in different ratios. then poly(acrylonitrileacrylic acid)/-cyclodextrin (PANAA/-CD) nanowebs were produced using the electrospinning process. The effect of different electrospinning parameters such as polymer concentration, distance, flow rate and voltage on nanofibre properties was studied. The presence of CD molecules in the PANAA solutions did not affect the diameter of nanofibres significantly. The presence of CD molecules in the PANAA/CD nanofibres produced was studied by means of Fourier transform infrared (FTIR) spectroscopy. The molecular filtration capability of the nanowebs produced was studied using phenolphthalein as a model organic molecule, by means of a UV-Vis Spectrophotometer. Results show that the nanofibres produced are able to remove phenolphthalein effectively from the solution. These nanowebs have the potential to be used as a molecular filter and/or nanofilter for filtration/purification/separation purposes.

PL

Syntezę kopolimeru akrylonitrylu i kwasu akrylowego przeprowadzono w zawiesinie, β-cyklodextran był mieszany z kopolimerem w zróżnicowanych ilościach. Następnie runo (PANAA/-CD) było wytwarzane metodą elektroprzędzenia. Badano wpływ różnych parametrów procesu, takich jak stężenie polimeru, odległość od filiery, szybkość przepływu i napięcie, na właściwości nanowłókien. Obecność molekuł CD w roztworach PANAA nie wpływała istotnie na średnicę nanowłókien. Badania przeprowadzono stosując metodę spektroskopii FTIR. Zdolność runa do filtracji molekularnej badano przy zastosowaniu fenoloftaleiny oraz spektrofotometrii UV-Vis. Badania wykazały, że wyprodukowane nanowłókna są zdolne do eliminacji fenoloftaleiny z roztworu. Wyprodukowane runa potencjalnie mogą być wydajnie zastosowane jako filtry molekularne oraz dla filtracji, oczyszczania i separacji.

Słowa kluczowe

EN

electrospinning; cyclodextrin; poly(acrylonitrile-acrylic acid); molecular filtration

PL

elektroprzędzenie; cyklodekstryny; spektroskopia FTIR; sączenie molekularne; stężenie polimeru; nanowłókna

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2014
• Tom: Vol. 22, no. 1 (103)
• Strony: 14--21
• Opis fizyczny: Bibliogr. 27 poz., rys., wykr., tab.

Twórcy

autor

Amiri P

• Iran, Tehran, Amirkabir University of Technology, Department of Textile Engineering

autor

Bahrami S H

• Iran, Tehran, Amirkabir University of Technology, Department of Textile Engineering

Bibliografia

• 1. Kanani AG, Bahrami SH, Taftei HA, Rabbani S, Sotoudeh M. Effect of chitosanpolyvinyl alcohol blend nanofibrous web on the healing of excision and incision full thickness wounds. Nanobiotechnol IET 2010; 4: 109–117.
• 2. Gholipour Kanani A, Bahrami SH. Review on Electrospun Nanofibers Scaffold and Biomedical Applications Trends Biomater. Artif. Organs 2010; 24: 93-115.
• 3. Martina M, Hutmacher DW. Biodegradable polymers applied in tissue engineering research: a review. Polymer International Polym. Int. 2007; 56: 145–157.
• 4. Meinel J, Germershaus O, Luhmann T, Merkle HP, Meinel L. Electrospun matrices for localized drug delivery: Current technologies and selected biomedical applications. Eur. J. Pharm. Biopharm. 2012; 81: 1–13.
• 5. Homaeigohar S, Koll J, Lilleodden ET, Elbahri M. The solvent induced interfiber adhesion and its influence on the mechanical and filtration properties of polyethersulfone electrospun nanofibrous microfiltration membranes. Separation and Purification Technology 2012; 98: 456-463.
• 6. Greiner A, Wendorff JH. Functional Self- Assembled Nanofibers by Electrospinning. Adv. Polym. Sci. 2008; 219: 107- 171.
• 7. Martin Del Valle EM. Cyclodextrins and their uses: a review. Process Biochemistry 2004; 39: 1033-1046.
• 8. Tonelli AE. Nanostructuring and functionalizing polymers with cyclodextrins. Polymer 2008; 49: 1725-1736.
• 9. Crinia G, Morcellet M. Synthesis and applications of adsorbents containing cyclodextrins. J. Sep. Sci. 2002; 25: 789–813.
• 10. Li L, Hsieh YL. Ultra-fine polyelectrolyte fibers from electrospinning of poly(acrylic acid). Polymer 2005; 46: 5133–5139.
• 11. Bai J, Yang Q, Li M, Zhang C, Yiaoxian L. Synthesis of poly(N-vinylpyrrolidone)/ β-cyclodextrin composite nanofibers using electrospinning techniques. J. Mater. Process. Technol. 2008; 208: 251–254.
• 12. Bai J, Yang Q, Li M, Wang S, Zhang C, Yiaoxian L. Preparation of composite nanofibers containing gold nanoparticles by using poly(N-vinylpyrrolidone) and β cyclodextrin. Mater. Chem. Phys. 2008; 111: 205–208.
• 13. Ramaseshan R, Sundarrajan S, Liu YJ, Barhate RS, Lala NL, Ramakrishna S. Functionalized polymer nanofiber membranes for protection from chemical warfare stimulants. Nanotechnology 2006; 17: 2947–2953.
• 14. Kaur S, Kotaki M, Ma Z, Gopal R, Ramakrishna S. Oligosaccharide functionalized nanofibrous membrane. Int. J. Nanosci. 2006; 5: 1–11.
• 15. Uyar T, Kingshott P, Besenbacher F. Electrospinning of cyclodextrin pseudopolyrotaxane nanofibers. Angew. Chem. Int. Ed. 2008; 47: 9108– 9111.
• 16. Uyar T, Balan A, Toppare L, Besenbacher F. Electrospinning of cyclodextrin functionalized poly(methylmethacrylate) (PMMA) nanofibers. Polymer 2008; 50: 475–480.
• 17. Uyar T, Besenbacher F. Electrospinning of cyclodextrin functionalized polyethylene oxide (PEO) nanofibers. Eur. Polym. J. 2009; 45: 1032– 1037.
• 18. Guo J, Sun J, Zhu S, Cao H, Zhao D, Wang L, Yang H. Supramolecular inclusion complexes of biodegradable cholesteryl-( e-caprolactone)n functionalized polymer with α-cyclodextrin. J. Appl. Polym. Sci. 2007; 105: 1700-1706.
• 19. Uyar T, Hacaloglu J, Besenbacher F. Electrospun polystyrene fibers containing high temperature stable volatile fragrance/ flavor facilitated by cyclodextrin inclusion complexes. React. Funct. Polym. 2009; 69: 145–150.
• 20. Uyar T, Nur Y, Hacaloglu J, Besenbacher F. Electrospinning of functional poly(methylmethacrylate) (PMMA) nanofibers containing cyclodextrin– menthol inclusion complexes. Nanotechnology 2009; 20, 10: 125703.
• 22. Uyar T, Havelund R, Nur Y, Hacaloglu J, Besenbacher F, Kingshott P. Molecular filters based on cyclodextrin functionalized electrospun fibers. Journal of Membrane Science 2009; 332: 129–137.
• 23. Bajaj P, Sen K, Bahrami Hajir S. Solution polymerization of acrylonitrile with vinyl acids in dimethylformamide. Journal of Applied Polymer Science 1996; 59: 1539–1550.
• 24. Ramakrishna S, Fujihara K, Teik-Cheng Lim WT, Ma Z. An introduction to electrospinning and nanofibers. World Scientific Publishing, Singapore, 2005.
• 25. Frenot A, Chronakis I. Polymer nanofibers assembled by electrospinning. Colloid and Interface Science 2003; 8: 64–75.
• 26. Devasia Renjith, Reghunadhan Nair CP, Sadhana R, Babu NS, Ninan KN. Fourier transform infrared and wide-angle X-ray diffraction studies of the thermal cyclization reactions of high-molar-mass poly(acrylonitrile-co-itaconic acid). J. Appl. Polym. Sci. 2006; 100: 3055-3062.
• 27. Goel A, Nene SN. Modifications in the phenolphtalein method for spectrophotometric estimation of Beta Cyclodextrin. Starch 1995; 47, 10: 399-400.