Effects of Yttrium (Y) Substitution by Cerium (Ce) on Microstructure and Corrosion Behavior of Near-Equiatomic Alniy Medium-Entropy Amorphous Alloy Ribbons

• Autorzy: Zhang Shuyan , Zhang Zhibin , Wang Xin , Gao Yangyang , Liang Xiubing

Identyfikatory

DOI

10.24425/amm.2022.137800

• Języki publikacji: EN

Abstrakty

EN

Through partially replacing Y element, Ce was added into near-equiatomic AlNiY medium-entropy amorphous alloy (denoted as MEAA) ribbons by the melt spinning process in this study. The differences of microstructure, thermal stability, hardness and corrosion resistance of Al_33.3Ni_33.3Y_33.4-xCe_x(x = 0, 2, 5, 8, 13) alloy ribbons were investigated by X-ray diffraction (XRD), scanning electron microscope (SEM), differential scanning calorimeter (DSC) and Vickers-type hardness tester. The anti-corrosion performance in 3.5 wt.% NaCl solution of alloy ribbons was investigated elaborately through the general potentiodynamic polarization curves (Tafel) and electrochemical impedance spectroscopy (EIS). Results suggested that all ribbon samples could remain amorphous structure and the hardness are all above 510 HV_0.1. With the increase of Ce content, the thermal stability begins to be gradually lower. However, according to the analysis of crystallization kinetics, all types of MEAA ribbons presents the relatively prominent thermal stability compared with traditional Al-based amorphous alloys. The corrosion current density raises firstly, then shows a decreasing trend, and has a slight increase at last. Therefore, appropriate content of Ce element can improve the corrosion protection performance of alloy ribbons and the 5 at.% Ce MEAA ribbons exhibited the excellent corrosion resistance in this study.

Słowa kluczowe

EN

medium-entropy amorphous alloys; corrosion behavior; thermal stability analysis; microstructure; cerium content

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2022
• Tom: Vol. 67, iss. 2
• Strony: 637--643
• Opis fizyczny: Bibliogr. 36 poz., fot., rys., tab.

Twórcy

autor

Zhang Shuyan

• Zhejiang University, Ocean College, Zhoushan 316021, Peoples Republic of China
• Defense Innovation Institute, Academy of Military Sciences of the PLA of China, Beijing 100071, Peoples Republic of China

• https://orcid.org/0000-0002-1653-6809

autor

Zhang Zhibin

• Defense Innovation Institute, Academy of Military Sciences of the PLA of China, Beijing 100071, Peoples Republic of China

autor

Wang Xin

• Defense Innovation Institute, Academy of Military Sciences of the PLA of China, Beijing 100071, Peoples Republic of China

autor

Gao Yangyang

• Zhejiang University, Ocean College, Zhoushan 316021, Peoples Republic of China

autor

Liang Xiubing

• Zhejiang University, Ocean College, Zhoushan 316021, Peoples Republic of China

• https://orcid.org/0000-0002-3193-6165

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Uwagi

1. This project was supported by the National Key Research and Development Program of China (grant no. 2018YFC1902400) and National Natural Science Foundation of China (Grant No. 51975582).

2. Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).