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Abstrakty
In this study, flocculation behaviors of natural stone powder suspensions were determined by applying classical jar tests. The flocculation tests were performed in the presence of different types of polymers at different polymer dosages and pHs. Then, the settling rates and residual turbidity values of suspensions were recorded. The flocculation performance of flocculants possessing unique molecular architecture (UMA) and conventional polyacrylamide based flocculants was investigated for the solidliquid separation of natural stone processing wastewater. The effects of flocculant type, dosage and pH were examined. The results obtained from this study indicated that in terms of the settling rate and turbidity, the medium anionic SPP 508 flocculant of 28% charge density showed a better flocculation performance compared to other conventional and UMA flocculants at natural pH. The SPP 508 flocculant gave the lowest turbidity value of 3 NTU (Nepheleometric turbidity Unit) at dosage of 0.3 mg/dm3, while the highest settling rate (870 mm/min) for the suspensions tested was achieved at 1 mg/ dm3 dosage for the same flocculant. However, the lowest settling rate was obtained by high cationic flocculant (Enfloc 440 C). All flocculants showed a good flocculation performance for the settling rate and turbidity at pH 8 and 10.
Słowa kluczowe
Rocznik
Tom
Strony
169--184
Opis fizyczny
Bibliogr. 38 poz., rys.
Twórcy
autor
- Mining Engineering Department, Eskisehir Osmangazi University, 26480, Eskisehir, Turkey
autor
- Mining Engineering Department, Eskisehir Osmangazi University, 26480, Eskisehir, Turkey
Bibliografia
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- 2. ARSLAN E.I., ASLAN S., IPEK U., ALTUN S., YAZIOGLU S. 2005, Physico-chemical treatment of marble processing wastewater and recycling of its sludge. Waste Management Research, 23, 550–559.
- 3. BAYRAKTAR I., ONER M., KARAPINAR N., SAKLAR S. 1996, Wastewater treatment in the marble industry. In M. Kemal., V. Arslan, A. Akar, & M. Canbazoğlu (Eds.), Changing scopes in mineral processing, 673–677, Rotterdam,NL: Balkema.
- 4. BENTLI I., 2010, The effect of electrolytes in flocculation of coal washing plant talings,Ekoloji, 71–77.
- 5. BESRA L., SENGUPTA D.K., ROY S.K., 2000, Particle characteristics and their influence on dewatering of kaolin, calcite and quartz suspensions, Int. J. Miner. Process. 59, 89–112.
- 6. BESRA L., SENGUPTA D.K., ROY S.K., AY P., 2004, Influence of polymer adsorption and conformation on flocculation and dewatering of kaolin suspension, Separation and Purification technology, 37, 231–246.
- 7. BIGGS S., HABGOOD M., JAMESON G.J., YAN Y., 2000, Aggregate structures formed via a bridging flocculation mechanism, Chemical Engineering Journal., 80, 13–22.
- 8. BOLTOA.B., GREGORY J., 2007, Organic Polyelectrolytes in Water Treatment, Water Research, 41, 2301–2324.
- 9. BRATBY J., 2006,Coagulation and Flocculation in Water and Wastewater Treatment, Published by IWA Publishing, London.
- 10. CENGIZ I., SABAH E., ERKAN Z.E., 2004, A study on the flocculation performances of traditional and UMA technology polymers, Madencilik,43, 15–23.
- 11. CENGIZ I., SABAH E., OZGEN S., AKYILDIZ H., 2009, Flocculation of Fine Particles in Ceramic Wastewater Using New Types of Polymeric Flocculants, Journal of Applied Polymer Science, 112, 1258–1264.
- 12. CELIK, M.Y., SABAH E., 2008,Geological and technical characterization of Iscehisar (Afyon-Turkey) marble deposits and the impact of marble waste on environmental pollution. Journal of Environmental Management, 87, 106–116.
- 13. ERSOY, B., 2005, Effect of pH and Polymer Charge Density on Settling Rate and Turbidity of Natural Stone Suspensions, International Journal of Mineral Processing, 75, 207– 216.
- 14. GERGORY, J., 2005, Particles in water: Properties and Process, University College London, UK.
- 15. GREGORY J., GUIBAI L., 1991, Effects of dosing and mixing conditions on polymer flocculation of concentrated suspensions, Chemical Engineering Communications, V: 108, 3–21.
- 16. GREGORY J., BARANY S., 2011, Adsorption and flocculation by polymers and polymer mixtures, Advances in Colloid and Interface Science, 169, 1–12.
- 17. HENDERSON J.M., WHEATLEY A.D. 2007, Factors Affecting the efficient flocculation of tailings by polacrylamides, Coal Preparation, 1987, V 4, 1-49.
- 18. HOCKING M.B., KLIMCHUK K.A., LOWEN S., 1999, Polymeric flocculants and flocculation, Polymer Reviews, 39:2, 177-203.
- 19. HOGG R., 2000, Flocculation and dewatering. International Journal of Mineral Processing, V:58, pp223-236.
- 20. HOGG R., 1999, The role of polymer adsorption kinetics in flocculation, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 146, 253–263.
- 21. IPEKOGLU U., 1997, Dewatering and Methods. Dokuz Eylül University, Mining Faculty Impress, No: 179, İzmir.
- 22. KILIC H., 2012, Treatment of Natural Stone Wastewaters by Flocculation and Floc-Flotation Methods, MSc Thesis, Eskişehir Osmangazi University, Turkey.
- 23. MPOFU P., ADDAI-MENSAH J., RALSTON J., 2003, Investigation of the effect of polymer structure type on flocculation, rheology and dewatering behavior of kaolinite dispersions, Int. J. Miner. Process. 71, 247–268.
- 24. NISHKOV, I., MARINOV, M. 2003,Calcium carbonate microproducts from marble treatment waste. In L.Kuzey, I.Niskov, A. Boteva, D. Mochev (Eds.), Mineral processing in the 21st century (pp. 700–705), Djev Trade, Sofia.
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- 28. PEFFERKORN, E.,1999, Polyacrylamide at solid/liquid interfaces, Journal of Colloid and Interface Science, 216, 197-220.
- 29. RATTANAKAWIN, C., HOGG R., 2001, Aggregate size distributions in flocculation, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 177, 87–98.
- 30. ROSSINI, M., GARRIDO J., GARCIA, GALLUZZO, M., 1999, Optimization of the coagulationflocculation treatment influence of rapid mix parameters, Wat. Res., 33,8: 1817–1826.
- 31. SABAH, E., ACIKSOZ, C., 2012, Flocculation Performance of Fine Particles in Travertine Slime Suspension, Physicochemical Problems of Mineral Processing 48(2), 555–566.
- 32. SABAH, E. and ERKAN Z.E.,2006, Interaction mechanism of flocculants with coal waste slurry, Fuel, 85, 350–359.
- 33. SABAH E., CENGIZ I., 2004, An evaluation procedure for flocculation of coal preparation plant tailings, Water Research, 38, 1542–1549.
- 34. SEYRANKAYA A., MALAYOGLU U., AKAR A. 2000, Flocculation conditions of marble from industrial wastewater and environmental consideration, In G. Ozbayoglu (Ed.), Mineral processing In the verge of the 12st century, 645–652, Rotterdam, NL: Balkema.
- 35. SOMASUNDARAN P., DAS K.K., 1998. Flocculation and selective flocculation - An overview. In:Atak, S., Onal., G., Celik, M.S., (Editors), Proceedings of 7th International Mineral Processing Symposium (Innovation in mineral and coal processing), Istanbul, Turkey, Balkema, 81–91.
- 36. SOMASUNDARAN P., KRISHNAKUMAR S., 1997, Adsorption of surfactants and polymers at the solid-liquid interface, Colloids Surfaces A: Physicochemical and Engineering Aspects, 491–513.
- 37. SWORSKA A., LASKOWSKI J.S., CYMERMAN G., 2000 a, Flocculation of the Syncrude fine tailings Part I. Effect of pH, polymer dosage and Mg2+ and Ca2+ cations, International Journal of Mineral Processing, 60 143–152.
- 38. SWORSKA A., LASKOWSKI J.S., CYMERMAN G., 2000 b, Flocculation of the Syncrudefine tailings Part II. Effect of hydrodynamic conditions, International Journal of Mineral Processing, 60, 153–161.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-cdbdfcc8-aa9d-4587-8fbf-5ce125f9f3a9