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Effect of Cu Addition on Oxide Growth of Al-7 mass%Mg Alloy at High Temperature

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Języki publikacji
EN
Abstrakty
EN
Effect of Cu addition on oxide growth of Al-7 mass%Mg alloy at high temperature was investigated. As-cast microstructures of Al-7 mass%Mg and Al-7 mass%Mg-1 mass%Cu alloys showed α-Al dendrites and area of secondary particles. The 1 mass%Cu addition into Al-7 mass%Mg alloy formed Mg32(Al, Cu)49 ternary phase with β-Al3Mg2. The total fraction of two Mg-containing phases in Cu-added alloy was higher than the β-Al3Mg2 fraction in Cu-free alloy. From measured weight gains depending on time at 500°C under an air atmosphere, it was shown that all samples exhibited significant weight gains depending on time. Al-7mass%Mg1mass%Cu alloy showed the relatively increased oxidation rate when compared with Cu-free alloy. All the oxidized cross-sections throughout the entire oxidation time showed coarse and dark areas regarded as oxides grown from the surface to inside, but bigger oxidized areas were formed in the Al-7mass%Mg-1mass%Cu alloy containing higher fraction of Mg-based phases in the as-cast microstructure. As a result of compositional analysis on the oxide clusters, it was found that the oxide clusters contained Mg-based oxides formed through internal oxidation during a long time exposure to oxidizing environments.
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autor
  • Korea Institute of Industrial Technology (KITECH), Advanced Materials and Process R&D Department, Incheon 21999, Republic of Korea
  • Korea Institute of Industrial Technology (KITECH), Advanced Materials and Process R&D Department, Incheon 21999, Republic of Korea
  • Korea Institute of Industrial Technology (KITECH), Advanced Materials and Process R&D Department, Incheon 21999, Republic of Korea
  • Korea Institute of Industrial Technology (KITECH), Advanced Materials and Process R&D Department, Incheon 21999, Republic of Korea
autor
  • Korea Institute of Industrial Technology (KITECH), Advanced Materials and Process R&D Department, Incheon 21999, Republic of Korea
autor
  • Korea Institute of Industrial Technology (KITECH), Advanced Materials and Process R&D Department, Incheon 21999, Republic of Korea
Bibliografia
  • [1] J. R. Davis, ASM International, Aluminum and Aluminum Alloys, Materials Park 1993.
  • [2] H. Watanabe, K. Ohori, Y. Takeuchi, Trans. Iron Steel Inst. Jpn. 27, 730 (1987).
  • [3] J. L. García-Hernández, C. G. Garay-Reyes, I. K. Gómez-Barraza, M. A. Ruiz-Esparza-Rodríguez, E. J. Gutiérrez-Castañeda, I. Estrada-Guel, M. C. Maldonado-Orozco, R. Martínez-Sánchez, J. Mater. Res. Technol. 8 (6), 5471 (2019).
  • [4] M. Mihara, C. D. Marioara, S. J. Andersen, R. Holmestad, E. Kobayashi, T. Sato, Mater. Sci. Eng. A, 658, 91 (2016).
  • [5] S. H. Ha, B. H. Kim, Y. O. Yoon, H. K. Lim, T. W. Lee, S. H. Lim, S. K. Kim, Int. J. Metalcast. 13, 121 (2019).
  • [6] G. Wu, K. Dash, M. L. Galano, K. A. Q. O’Reilly, Corros. Sci. 155, 97 (2019).
  • [7] B. H. Kim, S. H. Ha, Y. O. Yoon, H. K. Lim, S. K. Kim, D. H. Kim, Mater. Lett. 228, 108 (2018).
  • [8] H. Okamoto, J. Phase Equilibria 19, 598 (1998).
  • [9] T. S. Parel, S. C. Wang, M. J. Starink, Mater. Des. 31, S2 (2010).
  • [10] C. W. Bale, E. Bélisle, P. Chartrand, S. A. Decterov, G. Eriksson, A. E. Gheribi, K. Hack, I. H. Jung, Y. B. Kang, J. Melançon, A. D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer, M. A. Van Ende, Calphad 54, 35 (2016).
  • [11] S. H. Ha, B. H. Kim, Y. O. Yoon, H. K. Lim, T. W. Lee, S. H. Lim, S. K. Kim, Sci. Adv. Mater. 10, 697 (2018).
  • [12] D. Ajmera, E. Panda, Corros. Sci. 102, 425 (2016).
Uwagi
1. This work was supported by funding (No. 20011420) from Ministry of Trade, Industry and Energy, Korea.
2. Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-cd5b955d-6500-4d81-b003-9b648d7951d1
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