Preparation, properties and potential applications of a photocurable varnish with pleasant limonene smell

• Autorzy: Bednarczyk P. , Wróblewska A. , Czech Z. , Malko M.W. , Rozwadowski Z. , Markowska-Szczupak A.

Identyfikatory

DOI

10.1515/pjct-2016-0023

• Języki publikacji: EN

Abstrakty

EN

Photocurable materials which are obtained on the basis of urethane acrylate resins are often used in the industry for the production varnishes or protective coatings. The main disadvantage which is connected with the utilization of these varnishes is their unpleasant smell during the process of production and curing. This work presents the photocurable varnish which was obtained on the basis of aliphatic urethane acrylate and R-(+)-limonene. The utilization of this raw materials allows to obtain the smelling coatings. The aim of this work were the studies on the influence of limonene molecules on the mechanical properties of the UV-cured coatings. These studies showed that the coatings with limonene molecules retain their properties, and are characterized by the very good adhesion, cohesion and high gloss. These kinds of varnishes can be applied for preparation of appropriate protective coatings on the surface of wood, metals, and nail plates. These protective coatings have not only pleasure smell but also can have the bactericidal and fungicidal properties. The studies performed with Escherichia coli ATCC29425 and Candida albicans confirmed these properties.

Słowa kluczowe

EN

varnishes with limonene; smelling varnishes; urethane acrylate; UV-curing coating

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2016
• Tom: Vol. 18, nr 2
• Strony: 13--19
• Opis fizyczny: Bibliogr. 20 poz., rys., tab.

Twórcy

autor

Bednarczyk P.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, Pułaskiego 10, 70-322 Szczecin, Poland

autor

Wróblewska A.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, Pułaskiego 10, 70-322 Szczecin, Poland

autor

Czech Z.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, Pułaskiego 10, 70-322 Szczecin, Poland

autor

Malko M.W.

• West Pomeranian University of Technology, Szczecin, Institute of Organic Chemical Technology, Pułaskiego 10, 70-322 Szczecin, Poland

autor

Rozwadowski Z.

• West Pomeranian University of Technology, Szczecin, Institute of Fundamental Chemistry, al. Piastów 42, 71-065 Szczecin, Poland

autor

Markowska-Szczupak A.

• West Pomeranian University of Technology, Szczecin, Institute of Inorganic Chemical Technology and Environment Engineering, Pułaskiego 10, 70-322 Szczecin, Poland

Bibliografia

• 1. Kunwong, D., Sumanochitraporn, N. & Kaewpirom, S. (2011). Curing behavior of a UV-curable coating based on urethane acrylate oligomer: the infl uence of reactive monomers. Songklanakarin J. Sci. Technol. 33(2), 201–207.
• 2. Alshuiref, A.A., Ibrahim, H.G., Abduallah, A. & Edali, M.A. (2013). Thermal and mechanical analysis of urethane acrylate graft copolymer, Part A: Urethane macromonomer base on TDI and EG. Inter. J. Chem. 5(1), DOI: 10.5539/ijc.v5n1p58.
• 3. Milinaviciute, A., Jankauskaite, V. & Narmontas, P. (2011). Properties of UV-curable hyperbranched urethane-acrylate modified acrylic monomer coatings. Mater. Sci. (Medziagotyra) 17(4). http://dx.doi.org/10.5755/j01.ms.17.4.772.
• 4. Segurola, J., Allen, N., Edge, M. & Roberts, I. (1999). Photochemistry and photoinduced chemical crosslinking activity of acrylated prepolymers by several commercial type I far UV photoinitiators. Polymer Degrad. Stabil. 65, 153–160.
• 5. Sharama, S. & Srivastawa, A.K. (2005). Free radical copolimerization of limonene with buthyl methacrylane. Synthesis and characterization. Indian J. Technol. 12, 62–67.
• 6. Świderska, J., Czech, Z. & Kowalczyk, A. (2013). Polymerization shrinkage by investigation of uv curable dental restorative composites containing multifunctional methacrylates. Pol. J. Chem. Technol. 15(2), 81–85. DOI: 10.2478/pjct-2013-0027.
• 7. Pakdel, H., Pantea, D.M. & Roy, C. (2001). Production of DL-limonene by vacuum pyrolysis of used tires. J. Analyt. Appl. Pyrol. 57, 91–107. DOI: 10.1016/S0165-2370(00)00136-4.
• 8. Mishra, G. & Srivastava, A.K. (2005). Side-Chain liquidcrystalline polymers with a limonene-co-methyl methacrylate main chain: Synthesis and characterization of polymers with phenyl benzoate. J. Appl. Polym. Sci. 102(5), 4595–4600. DOI: 10.1002/app.24130.
• 9. Mishra, R.S., Mishra, A.K. & Raju, K.V.S.N. (2009). Synthesis and property study of UV-curable hyperbranched polyurethane acrylate/ZnO hybrid coatings. Eur. Polym. J. 45, 960–966. DOI: 10.1016/j.eurpolymj.2008.11.023.
• 10. Sharama, S. & Srivastava, A.K. (2006). Radical copolymerization of limonene with N-vinylpyrrolidone: synthesis and characterization. Designed Monom. Polym. 9(5), 503–516. DOI: 10.1163/156855506778538001.
• 11. Hebeish, A., Moustafa, M.G., Hamdy, I.A., EL-Saw, S.M. & Abdel-Mohdy, F.A. (2008). Preparation of durable insect repellent cotton fabric: Limonene as insecticide. Carbohydr. Polym. 74, 268–273. DOI: 10.1016/j.carbpol.2008.02.013.
• 12. Arrieta, M.P., López, J., Ferrándiz, S. & Peltzer, M.A. (2013). Characterization of PLA-limonene blends for food packaging applications. Polym. Testing. 32, 760–769. DOI: 10.1016/j.polymertesting.2013.03.016.
• 13. Karlberg A. T., Magnusson K. & Nilsson U. (1992). Air oxidation of dlimonene (the citrus solvent) creates potent allergen. Contact Dermatitis 5, 332–340. DOI: 10.1111/j.1600-0536.1992.tb00129.x.
• 14. Ciriminna, R., Lomeli-Rodriguez, M., Cara, P.D., Lopez-Sanchez, A. & Pagliaro, M. (2014). Limonene: a versatile chemical of the bioeconomy. Chem. Commun. 50, 15288–15296. DOI: 10.1039/c4cc06147k.
• 15. Czech, Z., Kowalczyk, A. & Ortyl, J. (2013). Acrylic pressure-sensitive adhesives containing SiO2 nanoparticles. Pol. J. Chem. Technol. 15(1), 12–14. DOI: 10.1007/s11837-005-0177-z.
• 16. Czech, Z. & Kowalczyk, A. (2012). Infl uence of the unsaturated photoinitiators kind on the properties of uv-crosslinkable acrylic pressure-sensitive adhesives. Pol. J. Chem.Technol. 14(3), 83–87. DOI: 10.2478/v10026-012-0089-y.
• 17. Studer, K., Decker, Ch., Beck, E. & Schwalm, R. (2003). Overcoming oxygen inhibition in UV-curing of acrylate coatings by carbon dioxide inerting, Part I. Prog. Org. Coat. 48, 92–100. DOI: 10.1016/S0300-9440(03)00120-6.
• 18. Wilbon, P.A., Chu, F. & Tang, Ch. (2013). Progress in Renewable Polymers from Natural Terpenes, Terpenoids, and Rosin. Macromol. Rapid Commun. 34, 8−37. DOI: 10.1002/marc.201200513.
• 19. Holmes, R.S. & Misra, R.D.K. (2007). Effect of solvent type and content on monomer conversation of a model resin system as a thin fi lm. Dent. Mater. 23, 1506–1512. DOI: 10.1016/j.dental.2007.01.007.
• 20. Ciba Specialty Chemicals Inc. (2001). Coating Effects Segment, Ciba IRGACURE 184, Photoinitiator, Basle. - 10.1515/pjct-2016-0023

Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.