Evolution of Physicochemical Structure of Waste Cotton Fiber (Hydrochar) During Hydrothermal Carbonation

• Autorzy: Sheng Shi , Meiling Zhang , Suying Zhang , Wensheng Hou , Zhifeng Yan

Identyfikatory

DOI

10.2478/aut-2019-0041

• Języki publikacji: EN

Abstrakty

EN

To study the hydrothermal behavior of cotton fiber, the carbonization process and structural evolution of discarded or waste cotton fiber (WCF) under hydrothermal conditions were investigated using microcrystalline cellulose (MCC), and glucose was used as a model compound. Results showed that high temperature was beneficial for the hydrolysis of discarded cotton fiber, and the yield of sugar was 4.5%, which was lower than that of MCC (6.51%). WCF and MCC were carbonized at 240–~260°C and 220–~240°C, respectively, whereas the carbonization temperature of glucose was lower than 220°C. The C/O ratios of WCF and glucose hydrothermal products were 5.79 and 5.85, respectively. The three kinds of hydrothermal carbonization products had similar crystal structures and oxygen-containing functional groups. The carbonized products of WCF contained many irregular particles, while the main products of glucose carbonization were 0.5-mm-sized carbon microspheres (CMSs). Results showed that glucose was an important intermediate in WCF carbonization and that there were two main pathways of hydrothermal carbonization of cotton fibers: some cotton fibers were completely hydrolyzed into glucose accompanied by nucleation and then the growth of CMSs. For the other part, the glucose ring of the oligosaccharide, formed by the incomplete hydrolysis of cotton fibers under hydrothermal conditions of high temperature and pressure, breaks and then forms particulate matter.

Słowa kluczowe

EN

waste cotton fibers; recycling; carbon microsphere; physicochemical characteristics

PL

odpady włókien bawełnianych; recykling; mikrosfera węglowa; właściwości fizykochemiczne

• Wydawca: Lodz University of Technology, Faculty of Material Technologies and Textile Design
• Czasopismo: Autex Research Journal
• Rocznik: 2020
• Tom: Vol. 20, no. 3
• Strony: 319--326
• Opis fizyczny: Bibliogr. 26 poz.

Twórcy

autor

Sheng Shi

• College of Textile Engineering, Taiyuan University of Technology, Jinzhong 030600, Shanxi, China

autor

Meiling Zhang

• College of Textile Engineering, Taiyuan University of Technology, Jinzhong 030600, Shanxi, China

autor

Suying Zhang

• College of Textile Engineering, Taiyuan University of Technology, Jinzhong 030600, Shanxi, China

autor

Wensheng Hou

• College of Textile Engineering, Taiyuan University of Technology, Jinzhong 030600, Shanxi, China

autor

Zhifeng Yan

• College of Textile Engineering, Taiyuan University of Technology, Jinzhong 030600, Shanxi, China

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).