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Although pyrite is one of the more abundant the earth crust, it has low economic value. When it reports to the concentrate during flotation along with the valuable minerals, it decreases the grade of the valuable minerals and leads to an increase in smelting costs. Numerous modifications have been suggested in the literature to increase the selective recovery of pyrite containing base metal-sulfide ores. The use of ultrasonic applications is one such method. In this study, the effect of the ultrasonic application on the flotation behavior of galena and pyrite mineral was investigated through systematic Hallimond Tube experiments. In the initial phase of the experiments, the optimum flotation conditions (particle size, pH, amount of air, and amount of reagent) were determined for the two minerals. Subsequent experiments were carried out under these optimums to distinguish the effect of the ultrasonic application. The influence of how the ultrasonic application was applied (i.e. before and during the conditioning stage or before the re-flotation of the concentrate) was also studied. It was observed that the ultrasonic application had a strong activating influence if it was administered before or during the conditioning stage. The effect was similar to whether the minerals were floated individually or from their mixtures. However, when it was applied to a flotation concentrate before reflotation, it selectively displayed a depressant action for the pyrite to the extent that no depressants were needed. The results conclusively showed that the ultrasonic application could drastically improve the selectivity of the complex ores.
Słowa kluczowe
Rocznik
Tom
Strony
538--547
Opis fizyczny
Bibliogr. 37 poz., rys., tab., wykr.
Twórcy
autor
- Dokuz Eylul University, Department of Mining Engineering, Izmir, Turkey
autor
- Dokuz Eylul University, Department of Mining Engineering, Izmir, Turkey
autor
- Dokuz Eylul University, Department of Mining Engineering, Izmir, Turkey
autor
- Izmir Institute of Technology, Department of Chemical Engineering, Izmir, Turkey
Bibliografia
- ALDRICH, C. and FENG, D., 1999. Effect of treatment preconditioning of pulp on the flotation of sulphide ores. Technical Note. Minerals Engineering, 12(6), 701-707.
- ANSARI, A., PAWLIK, M., 2007. Floatability of chalcopyrite and molybdenite in the presence of lignosulfonates. Part I. Adsorption studies. Minerals Engineering, 20(6), 600-608.
- BICAK, O., EKMEKCI, Z., BRADSHAW, D.J., HARRIS, P.J., 2007. Adsorption of guar gum and CMC on pyrite. Minerals Engineering, 20(10), 996-1002.
- BULUT, G. and ATAK S., 2002. Role of dixanthogen on the pyrite flotation: solubility, adsorption studies and EH, FTIR measurements. Minerals-Metallurgical Processing, 19, 81-86
- CAO, Q., CHENG, J., FENG, Q., WEN, S., LUO, B. 2017. Surface cleaning and oxidative effects of ultrasonication on the flotation of oxidized pyrite. Powder Technology, 311, 390-397.
- CAO, Z., CHEN, X., PENG, Y., 2018. The role of sodium sulfide in the flotation of pyrite depressed in chalcopyrite flotation. Minerals Engineering, 119, 93-98.
- CELIK, M.S., HANCER, M., MILLER, J.D., 2002. Flotation chemistry of boron minerals. Journal of Colloid and Interface Science, 256(1), 121-131.
- CHANDRA, A.P., GERSON, A.R., 2010. The mechanisms of pyrite oxidation and leaching: a fundamental perspective. Surface Science Reports, 65(9), 293-315.
- CHEN Y., TRUONG, V.N.T., BUA X., XIEA, G., 2020. A review of effects and applications of ultrasound in mineral flotation. Ultrasonics Sonochemistry, 60, 104739.
- CILEK, E.C., OZGEN, S., 2009. Effect of ultrasound on separation selectivity and efficiency of flotation. Minerals Engineering, 22(14), 1209-1217.
- DONSKOI, E., COLLINGS, A.F., POLIAKOV, A., BRUCKARD, W.J., 2012. Utilisation of ultrasonic application for upgrading of hematitic/goethitic iron ore fines. International Journal of Mineral Processing, 114-117, 80-92.
- DRZYMALA, J., 1999. Characterization of materials by Hallimond Tube flotation, Part 3. Maximum size of floating and interacting particles. International Journal of Mineral Processing, 55(3), 203-218.
- FARMER, A.D., COLLINGS, A.F., JAMESON, G.J., 2000. Effect of ultrasound on surface cleaning of silica particles. International Journal of Mineral Processing, 60(2), 101-113.
- GAUDIN A.M., 1976. Flotation. American Instıtute of Mining, Metallurgical, and Petroleum Engineers. New York. 1, 300-356
- GHADYANI, A., NOAPARAST, M., TONKABON, S.Z.S., 2018. A Study on the effects of ultrasonic irradiation as preapplication method on high-ash coal flotation and kinetics. International Journal of Coal Preparation and Utilization, 8(7), 374-391.
- GUNGOREN, C., OZDEMIR, O., OZKAN, S.G., 2017. Effects of temperature during ultrasonic conditioning in quartzamine flotation. Physicochemical Problems of Mineral Processing, 53(2), 687-698.
- GUNGOREN, C., OZDEMIR, O., WANG, X., OZKAN, S.G., MILLER, J.D., 2019. Effect of ultrasound on bubble-particle interaction in quartz-amine flotation system. Ultrasonics Sonochemistry, 52, 446-454.
- HUANG, P., CAO, M., LIU, Q., 2013. Selective depression of pyrite with chitosan in Pb–Fe sulfide flotation. Minerals Engineering, 46(47), 45-51.
- HOSSEINI S. H., FORSSBERG E. 2007. Physicochemical studies of smithsonite flotation using mixed anionic/cationic collector. Minerals Engineering, 20, 621-624.
- JIAO, F., CUI, Y., WANG, D., QIN, W., 2019. Effect of sodium salt of N,N-dimethyldi-thiocarbamate on the flotation separation of marmatite from galena. Physicochemical Problems of Mineral Processing, 55(2), 389-399.
- JIA, Y., HUANG, X., HUANG, K., WANG, S., CAO, Z., ZHONG, H., 2019. Synthesis, flotation performance and adsorption mechanism of 3-(ethylamino)-N-phenyl-3-thioxopropanamide onto galena/sphalerite surfaces. Journal of Industrial and Engineering Chemistry, 77, 416-425.
- KANG, W. Z., XUN, H.-X., KONG, X.-H., LI, M.-M., 2009. Effects from changes in pulp nature after ultrasonic conditioning on high-sulfur coal flotation. Mining Science and Technology (China), 19(4), 498-507.
- KURSUN, H., 2014. A study on the utilization of ultrasonic preapplication in zinc flotation. Separation Science and Technology, 9(18), 2975-2980.
- LI, Y., CHEN, J., KANG, D., GUO, J., 2012. Depression of pyrite in alkaline medium and its subsequent activation by copper. Minerals Engineering, 26, 64-69.
- MOSLEMI, H., GHARABAGHI, M., 2017. A review on electrochemical behavior of pyrite in the froth flotation process. Journal of Industrial and Engineering Chemistry, 47, 1-18.
- MU, Y., PENG, Y., LAUTEN, R.A., 2016. The depression of pyrite in selective flotation by different reagent systems– A Literature review. Minerals Engineering, 96-97, 143-156.
- OSASERE, O.F., 2000. Relation of contact angle data to Hallimond Tube flotation of coal with coagulants and flocculants. Fuel, 79(2), 193-199.
- OZKAN, S., 2002. Beneficiation of magnesite slimes with ultrasonic treatment. Minerals Engineering, 15(1-2) 99-101.
- OZKAN, S.G. and KUYUMCU, H.Z., 2006. Investigation of mechanism of ultrasound on coal flotation. International Journal of Mineral Processing, 81(3), 201-203.
- OZKAN, S.G. and GUNGOREN C., 2012. Enhancement of colemanite flotation by ultrasonic preapplication. Physicochemical Problems of Mineral Processing, 48(2), 455-462.
- OZUN, S, HASSASA B.V., MILLER J. D., 2019. Collectorless flotation of oxidized pyrite. Colloids and Surfaces A, 561, 349–356.
- TAGUTA, J., O'CONNOR, C.T., FADZEAN. B.M., 2018. Investigating the interaction of thiol collectors and collector mixtures with sulphide minerals using thermochemistry and microflotation. Minerals Engineering, 119, 99-104.
- VASANTHAKUMAR, B., RAVISHANKAR, H., SUBRAMANIAN, S., 2017. Selective bio-flotation of sphalerite from galena using mineral–adapted strains of Bacillus subtilis. Minerals Engineering, 110, 179-184.
- VIDELA, A.R., MORALES, R., SAINT-JEAN, T., GAETE, L., VARGAS, Y., MILLER., J.D., 2016. Ultrasound application on tailings to enhance copper flotation recovery. Minerals Engineering, 99, 89-95.
- WILLS, B.A. and NAPIER- MUNN, T.J. 2006. Wills’ Mineral Processing Technology: An Introduction to the Practical Aspects of Ore Treatment and Mineral Recovery. 7th Edition. Publisher: Butterworth-Heinemann. 12, 266-344.
- ZHAO, H.L., WANG, D.X., CAI, Y.X., ZHANG, F.C., 2007. Removal of iron from silica sand by surface cleaning using power ultrasound. Minerals Engineering, 20(8), 816-818.
- ZHOU, Z.A., XU, Z., FINCH, J.A., MASLIYAH, J. H., CHOW, R. S., 2009. On the role of cavitation in particle collection in flotation–A critical review II. Minerals Engineering, 22(5), 419-433.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-cbaeb3ab-063e-4596-8b4c-49cbe79604a1