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Structure and Properties of Nd-Fe-B Alloy Subjected to HDDR Process

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EN
Abstrakty
EN
In this paper the Hydrogenation, Disproportionation, Desorption and Recombination (HDDR) route was tested, for the Nd-Fe-B master alloy, as a prospective procedure for recycling of sintered scrap neodymium magnets. The HDDR method is based on the hydrogen induced reversal phase transformation of Nd-Fe-B alloy: Nd2Fe14B + (2±x) H2 = 2NdH2±x + Fe2B + 12Fe. Microstructural observations (SEM), phase constitution studies (XRD) and measurement of magnetic properties (VSM) were done to investigate the HDDR transformation progress. It was observed that disproportionation reaction starts at the grain boundaries, where the Nd-rich phase is located. Average grain size was reduced and coercive material was produced as a result of the HDDR process. Obtained results are similar to literature data.
Twórcy
  • Warsaw University of Technology, The Faculty of Materials Science and Engineering , 02-507 Warszawa , 141 Wołoska Street, Poland
autor
  • Warsaw University of Technology, The Faculty of Materials Science and Engineering , 02-507 Warszawa , 141 Wołoska Street, Poland
autor
  • Warsaw University of Technology, The Faculty of Materials Science and Engineering , 02-507 Warszawa , 141 Wołoska Street, Poland
autor
  • P.P.H.U. Polblume Zbigniew Miazga, 05-502 Piaseczno, 35 11-Go Listopada Street, Poland
Bibliografia
  • [1] M. Schluep, Ch. Hagelueken, R. Kuehr, F. Magalini, C. Maurer, Ch. Meskers, E. Mueller, F. Wang, Recycling From E-Waste To Resources - United Nations Environment Programme, Oktoberdruck AG Berlin 2009.
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  • [8] K. Güth, T. G. Woodcock, L. Schultz, O. Gutfleisch, Recycling of sintered Nd-Fe-B magnets by the d-HDDR route, in: Proceedings of the 22nd International Workshop on Rare- Earth Permanent Magnets and their Applications 2012.
  • [9] A. Walton, A. I. Bevan, V. S. J. Mann, J. D. Speight, I. R. Harris, A. J. Williams, H. Yi, The Use of Hydrogen to Separate and Recycle NdFeB Magnets from Electronic Waste, in: Proceedings of the 22nd International Workshop on Rare- Earth Permanent Magnets and their Applications 2012.
  • [10] G. C. Hadjipanayis, Bonded Magnets. Proceedings of the NA TO Advanced Research Workshop on Science and Technology of bonded magnets, Springer Netherlands, 2003.
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  • [12] A. J. Williams, P. J. McGuiness, I. R. Harris, J. Less-Common Met. 171, 149 (1991)
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  • [14] O. Gutfleisch, J. Phys. D: Appl. Phys. 33, 157 (2000).
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  • [16] Y. Shinba, T. J. Konno, K. Ishikawa, K. Hiraga, M. Sagawa, J. Appl. Phys. 97, 053504 (2005).
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-cb228350-3d84-43a2-a153-1ae26eca7462
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