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The study investigated the suitability of waste rubber powder (WRP) use as filler in adhesive formulation for plywood application. Melamine Urea Formaldehyde (MUF) was employed as resin for formulating the wood adhesive. To improve chemical properties and bonding quality of adhesive, WRP was treated by different chemicals like 20% nitric acid, 30% hydrogen peroxide and acetone solution. The treated WRP were analysed by XRD and it showed that inorganic compounds were removed and carbon was remained as major component under the treatment of 20% HNO3. The treatment improved the mechanical properties like shear strength and formaldehyde emission of plywood (high shear strength and low formaldehyde emission). The physico-chemical interaction between the wood, resin and filler was investigated using fourier transform infrared spectroscopic (FTIR) technique and the interactions among N-H of MUF and C=O of wood and WRP were identified. The morphology of wood-adhesive interface was studied by field emission scanning electron microscope (FESEM) and light microscope (LM). It showed that the penetration of adhesives and fillers through the wood pores was responsible for mechanical interlocking. Therefore, chemically treated WRP proved its potential use as filler in MUF based adhesive for making plywood.
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Rocznik
Tom
Strony
41--47
Opis fizyczny
Bibliogr. 37 poz., rys., wykr., wz.
Twórcy
autor
- Universiti Malaysia Pahang, Faculty of Chemical and Natural Resources Engineering, Lebuhraya Tun Razak, 26300 Gambang, Kuantan, Pahang, Malaysia
autor
- Universiti Malaysia Pahang, Faculty of Chemical and Natural Resources Engineering, Lebuhraya Tun Razak, 26300 Gambang, Kuantan, Pahang, Malaysia
autor
- Universiti Malaysia Pahang, Faculty of Chemical and Natural Resources Engineering, Lebuhraya Tun Razak, 26300 Gambang, Kuantan, Pahang, Malaysia
autor
- Universiti Malaysia Pahang, Faculty of Chemical and Natural Resources Engineering, Lebuhraya Tun Razak, 26300 Gambang, Kuantan, Pahang, Malaysia
autor
- College of Applied Sciences, Department of Engineering, 311 Sohar, Oman
Bibliografia
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- 23. Tamez Uddin, M., Rukanuzzaman, M., Maksudur Rahman Khan, M. & Akhtarul Islam, M. (2009). Adsorption of methylene blue from aqueous solution by jackfruit (Artocarpus heteropyllus) leaf powder: A fixed-bed column study. J. Environ. Manage. 90(11), 3443-3450. DOI: 10.1016/j. jenvman.2009.05.030.
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- 27. Blanton, T.N. & Barnes, C.L. (2005). Quantitative analysis of calcium oxide desiccant conversion to calcium hydroxide using X-ray diffraction. Adv. X-ray Anal. 28, 45-51.
- 28. Alexandre-Franco, M., Fernández-González, C., Alfaro- -Domínguez, M., Palacios Latasa, J.M. & Gómez-Serrano, V. (2010). Devulcanization and Demineralization of Used Tire Rubber by Thermal Chemical Methods: A Study by X-ray Diffraction. Energy Fuels 24(6), 3401-3409. DOI: 10.1021/ef901523t.
- 29. Darmawan, S., Sofyan, K., Pari, G. & Sugiyanto, K. (2010). Effect of activated charcoal addition on formaldehyde emission of medium density fiberboard. J. For. Res. 7(2), 100-111.
- 30. Kumar, A., Gupta, A., Sharma, K., Nasir, M. & Khan, T.A. (2013). Influence of activated charcoal as filler on the properties of wood composites. Int. J. Adhes. Adhes. 46, 34-39. DOI: 10.1016/j.ijadhadh.2013.05.017.
- 31. Mansouri, H.R. & Pizzi, A. (2007). Recycled micronized polyurethane powders as active extenders of UF and PF wood panel adhesives. Holz als Roh und Werkstoff 65(4), 293-299. DOI: 10.1007/s00107-006-0168-y.
- 32. Bono, A., Maizura, N., Salah, S. & Chiw, H.K. (2011). The Performance of Melamine-Urea-Formaldehyde Resin with Palm Kernel as Filler. Adv. Mater. Res. 233-235, 3-10. DOI: 10.4028/www.scientific.net/AMR.233-235.3.
- 33. Babcock, G.E. & Smith, A.K. (1947). Extending phenolic resin plywood glues with proteinaceous materials. Ind. Eng. Chem. 39(1), 85-88. DOI: 10.1021/ie50445a029.
- 34. Qiao, L., Easteal, A.J., Bolt, C.J., Coveny, P.K. & Franich, R.A. (1999). The effects of filler materials on poly (vinyl acetate) emulsion wood adhesives. Pigment Resin Technol. 28(6), 326-330. DOI: 10.1108/03699429910302300.
- 35. Singh, A., Dawson, B., Rickard, C., Bond, J. & Singh, A. (2008). Light, confocal and scanning electron microscopy of wood-adhesive interface. Microsc. Anal. 22(3), 5-8.
- 36. De Meijer, M., Thurich, K. & Militz, H. (1998). Comparative study on penetration characteristics of modern wood coatings. Wood Sci. Technol. 32(5), 347-365. DOI: 10.1007/ BF00702791.
- 37. Kim, S., Kim, H.J., Xu, G.Z. & Eom, Y.G. (2007). Environment-friendly adhesives for fancy veneer bonding of engineered flooring to reduce formaldehyde and TVOC emissions. Mokchae Konghak 35(5), 58-66.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-ca6dc5ab-1e26-4d92-892c-cc574b70a306