Biobased poly(3-hydroxybutyrate acid) composites with addition of aliphatic polyurethane based on polypropylene glycols

• Autorzy: Zarzyka Iwona , Czerniecka-Kubicka Anna , Hęclik Karol , Dobrowolski Lucjan , Krzykowska Beata , Białkowska Anita , Bakar Mohamed

Identyfikatory

DOI

10.37190/ABB-01987-2021-02

• Języki publikacji: EN

Abstrakty

EN

Poly(3-hydroxybutyrate) (P3HB) is the most important of the polyhydroxyalkanoates. It is biosynthesized, biodegradable, biocompatible, and shows no cytotoxicity and mutagenicity. P3HB is a natural metabolite in the human body and, therefore, it could replace the synthetic, hard-to-degrade polymers used in the production of implants. However, P3HB is a brittle material with limited thermal stability. Therefore, in order to improve its mechanical properties and processing parameters by separating its melting point and degradation temperature, P3HB-based composites can be produced using, for example, linear aliphatic polyurethanes as modifiers. The aim of the study is a modification of P3HB properties with the use of linear aliphatic polyurethanes synthesized in reaction of hexamethylene diisocyanate (HDI) and polypropylene glycols (PPG) by producing their composites. Prepared biocomposites were tested by the scanning electron microscopy (SEM), differential scanning calorimetry (DSC) and thermogravimetry (TGA). Furthermore, selected mechanical properties were evaluated. It has been confirmed that new biocomposites showed an increase in impact strength, relative strain at break, decrease of hardness and higher degradation temperature compared to the unfilled P3HB. The biocomposites also showed a decrease in the glass transition temperature and the degree of crystallinity. Biocomposites obtained with 10 wt.% polyurethane synthesized with polypropylene glycol having 1000 g · mole–1 and HDI have the best thermal and mechanical properties.

Słowa kluczowe

EN

P3HB composites; polyurethanes; hexamethylene diisocyanate; polypropylene glycol; thermal properties; mechanical properties; morphology

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Acta of Bioengineering and Biomechanics
• Rocznik: 2022
• Tom: Vol. 24, no. 1
• Strony: 75--89
• Opis fizyczny: Bibliogr. 24 poz., rys., tab., wykr.

Twórcy

autor

Zarzyka Iwona

• Faculty of Chemistry, Rzeszow University of Technology, Rzeszów, Poland.

autor

Czerniecka-Kubicka Anna

• Department of Experimental and Clinical Pharmacology, Medical College of Rzeszów University, The University of Rzeszów, Rzeszów, Poland.
• Interdyscyplinary Center Preclinical and Clinical Research, The University of Rzeszów, Rzeszów, Poland.

autor

Hęclik Karol

• Faculty of Chemistry, Rzeszow University of Technology, Rzeszów, Poland.

autor

Dobrowolski Lucjan

• Faculty of Chemistry, Rzeszow University of Technology, Rzeszów, Poland.

autor

Krzykowska Beata

• Faculty of Chemistry, Rzeszow University of Technology, Rzeszów, Poland.

autor

Białkowska Anita

• Faculty of Chemical Engineering and Commodity Science, University of Technology and Humanities, Radom, Poland.

autor

Bakar Mohamed

• Faculty of Chemical Engineering and Commodity Science, University of Technology and Humanities, Radom, Poland.

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