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The rapidly declining quality of ores and concentrates produced by Lubin Concentrator (KGHM) makes the flotation concentrates exceptionally difficult-to-process by flash smelting. Currently, a hydrometallurgical process, using sulfuric acid with the presence of oxidants as a leaching medium, seems to be either a reasonable alternative or a complementary option to pyrometallurgy. The unique lithological, mineralogical and chemical properties of the concentrate were considered in a selection of the process route. Results of a pressure leaching of the copper sulfide concentrate from Lubin Concentrator (ZWR Lubin) with oxygenated aqueous H2SO4 solutions are presented. The effect of temperature from 120 to 200 °C, initial concentration of H2SO4 from 60 to 100 g/dm3, and oxygen partial pressure ranging from 0.5 to 2.0 MPa were investigated. The pressure leaching appeared to be an efficient process for recovering copper from the Lubin concentrate. At optimal leaching conditions (140 °C, 100 g/dm3 H2SO4, 1.0 MPa O2) 96% of Cu was extracted after 4 h.
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781--792
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Bibliogr. 24 poz., rys., tab.
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- Wroclaw University of Technology, Faculty of Chemistry, Division of Analytical Chemistry and Chemical Metallurgy, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
autor
- Wroclaw University of Technology, Faculty of Chemistry, Division of Analytical Chemistry and Chemical Metallurgy, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
autor
- Wroclaw University of Technology, Faculty of Chemistry, Division of Analytical Chemistry and Chemical Metallurgy, Wybrzeże Wyspiańskiego 27, 50-370 Wrocław, Poland
Bibliografia
- CHMIELEWSKI T., KALETA R., 2011. Galvanic interactions of sulfide minerals in leaching of flotation concentrate from Lubin concentrator, Physicochem. Probl. Miner. Process., 46, 21-34.
- CHMIELEWSKI T., 2007. Atmospheric leaching of shale by-product from Lubin concentrator, Physicochem. Probl. Miner. Process., 41, 337-348.
- CHMIELEWSKI T., BOROWSKI K., GIBAS K., OCHROMOWICZ K., WOŹNIAK B., 2011. Atmospheric leaching of copper flotation concentrate with oxygenated sulphuric acid solutions, Physicochem. Probl. Miner. Process., 47, 193-206.
- DREISINGER D., 2006. Copper leaching from primary sulphides: Options for biological and chemical extraction of copper, Hydrometallurgy, 83, 10-20.
- GUPTA C.K., MUKHERJEE T.K., 1990. Hydrometallurgy in extraction processes, Vol. I and II, CRC Press.
- HABASHI F., 1999. Textbook of hydrometallurgy, Metall. Extract. Quebec.
- HABASHI F., 2005. Recent Advances in the Hydrometallurgy of Copper, Proc.Int. Copper Hydrometallurgy Work- shop “Hydrocoper 2005” (Menacho J.M., Casas de Prada J.M., Eds.), Santiago, Chile, pp. 43-55.
- HABASHI F., 2007. Abandoned but not forgotten – the recent history of copper hydrometallurgy, The John Dutrizac Symposium on Copper Hydrometallurgy, Proceedings 6th International Copper-Cobre International Conference, August 3-20, 2007, Toronto, Canada, vol. IV, Met. Soc.
- JANSEN M., TAYLOR A., 2000. Key elements in the selection of sulphide leach processes for copper concentrate leaching, Alta Cu 2000, August 2000, Int. Proj. Dev. Serv. Pty Ltd.
- KONSTANTYNOWICZ-ZIELIŃSKA J. 1990. Petrology and genesis of the copper shale of the Foresudetic Monocline. Rudy i Metale Nieżelazne, 35(5-6), 128-133 (in Polish).
- KUKUĆ R., BAZAN B., 2013. Improvement of technology indices of DoC Lubin Plant within the context of decreasing copper content in ore, Proceedings of the Mineral Engineering Conference MEC2013, Kowalczuk P.B. (Ed.), Świeradów-Zdrój, Poland, 16-19 September 2013, 95-108 (in Polish).
- ŁUSZCZKIEWICZ A., CHMIELEWSKI T., 2006. Technology of chemical modification of middlings in flotation circuits of copper ores, Rudy i Metale Nieżelazne, R51(1), 2-10 (in Polish).
- ŁUSZCZKIEWICZ A., CHMIELEWSKI T., 2008. Acid treatment of copper sulfide middlings and rougher concentrates in the flotation circuit of carbonate ores, Int. J. Min. Process., 88, 45-52.
- MARSDEN J.O., WILMOT J.C., 2007a. Medium-temperature pressure leaching of copper concentrates – Part I: Chemistry and initial process development, Min. Metall. Processing, 24(4), 193-204.
- MARSDEN J.O., WILMOT J.C., 2007b. Medium-temperature pressure leaching of copper concentrates – Part II: Development of direct electrowinning and acid-autogenous process, Min. Metall. Processing, 24(4), 205- 217.
- MARSDEN J.O., WILMOT J.C., 2007c. Medium-temperature pressure leaching of copper concentrates – Part III: Commercial demonstration at Bagdad, Arizona, Min. Metall. Processing, 24(4), 218-225.
- MARSDEN J.O., WILMOT J.C., 2007d. Medium-temperature pressure leaching of copper concentrates – Part IV: Application at Morenci, Arizona, Min. Metall. Processing, 24(4), 226-236.
- MARSDEN J.O., 2007e. Sulphate-based flowsheet options for hydrometallurgical treatment of copper sulphide concentrates, The John Dutrizac Symposium on Copper Hydrometallurgy, Proceedings 6th International Copper-Cobre Conference, August 25-30, 2007, Toronto, Canada, vol. IV, Met. Soc., 77-100.
- MUSZER, A., WÓDKA, J., CHMIELEWSKI, T., MATUSKA, S., 2013. Covellinisation of copper sulphide minerals under pressure leaching conditions, Hydrometallurgy, 137, 1-7.
- PEACEY J.I., GUO X.J., ROBLES E., 2003. Copper Hydrometallurgy – Current Status, Preliminary economics, Future Direction and Positioning versus Smelting, Copper 2003 - Cobre 2003, vol.VI, (Book 1) Santiago – Chile (Riveros P.A., Dixon D., Dreisinger D., Eds.), pp. 205-222.
- RAMACHANDRAN V., LAKSHMANAN V.I., KONDOS P.D., 2007. Hydrometallurgy of copper sulphide concentrate, The John Dutrizac Symposium on Copper Hydrometallurgy, Proceedings 6th International Copper-Cobre Conference, August 25-30, 2007, Toronto, Canada, vol. IV, Met. Soc., pp. 101-128.
- RYDZEWSKI A., 1996. Lithology of the deposit rocks. In: A. Piestrzyński (Ed.) Monography of KGHM Polska Miedź S.A., CPBM Cuprum Sp. z o.o. Publisher, Lubin, 137-141 (in Polish).
- WÓDKA J., CHMIELEWSKI T., ZIÓŁKOWSKI B., 2007. Pressure leaching of shale ore in oxygenated sulphuric acid, Physicochem. Probl. Miner. Process., 41, 349-364.
- The World Copper Factbook, 2015. International Copper Study Group, www.icsg.org (May 2016)
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Bibliografia
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