Prevention of Hydrosphere Contamination with Electroplating Solutions through Electromembrane Processes of Regeneration

• Autorzy: Serdiuk Vasyl , Sklabinskyi Vsevolod , Bolshanina Svetlana , Ableyev Alexey , Dychenko Tetiana

Identyfikatory

DOI

10.12911/22998993/119801

• Języki publikacji: EN

Abstrakty

EN

The work studies the process of Сd²⁺ and Zn²⁺ cations transfer through a RALEX®CM-PES 11–66 cation-exchange membrane and the cations reduction as metals on the cathodes at the cathode chambers of the electrochemical units with a view to prevent the hydrosphere contamination with the electroplating solutions. Electrolysis of the solutions that imitated the possible composition of the passivating baths contained 50 g/l sodium dichromate, 10 g/l sulfuric acid and impurity ions of Сd²⁺ and Zn²⁺ in various concentrations. The designed passivation solutions with certain amount of impurity ions in the colour solution were forcibly mixed. The impact of the impurity ions concentration in the colour solution and of a forced mixing on the metal reduction was studied. Regularity in the increased metal reduction dependent on the metal concentration was found and the conditions favouring the ion migration through the cation-exchange membrane due to forced mixing were defined.

Słowa kluczowe

EN

electrolysis; electroplating solution; cation exchange membrane; cadmium cation; zinc cation; forced mixing

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2020
• Tom: Vol. 21, nr 4
• Strony: 61--69
• Opis fizyczny: Bibliogr. 21 poz., rys., tab.

Twórcy

autor

Serdiuk Vasyl

• Sumy State University, 2, Rymskogo-Korsakova st., 40007 Sumy, Ukraine

autor

Sklabinskyi Vsevolod

• Sumy State University, 2, Rymskogo-Korsakova st., 40007 Sumy, Ukraine

autor

Bolshanina Svetlana

• Sumy State University, 2, Rymskogo-Korsakova st., 40007 Sumy, Ukraine

autor

Ableyev Alexey

• Kusum Pharm LLC, 54, Skryabina st., 40022 Sumy, Ukraine

autor

Dychenko Tetiana

• Sumy State University, 2, Rymskogo-Korsakova st., 40007 Sumy, Ukraine

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).