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Comparative study on removal of metallurgical silicon impurities by different acid leaching methods

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Języki publikacji
EN
Abstrakty
EN
Hydrometallurgy is considered a promising method to produce solar-grade silicon (SOG-Si) from metallurgical-grade silicon (MG-Si) due to its advantages of low cost, simple operation, and easy control. In this paper, the effects of particle size of MG-Si, type of acid, leaching time, temperature, and liquid-to-solid ratio on the purification efficiency were investigated in an external field environment with the addition of ultrasound. The purification efficiencies of the two acid-leaching methods were compared. It was found that the simultaneous use of HCl + HNO3 was more effective than using only HCl for impurity removal in MG-Si: the extraction efficiencies of impurities Fe and Al were increased by 2.2% and 13.4%, respectively. The impurity contents in MG-Si before and after calcination pretreatment were also compared. This paper is expected to help researchers select the appropriate hydrometallurgical technique to reduce the impurity content in MG-Si.
Rocznik
Strony
art. no. 162331
Opis fizyczny
Bibliogr. 19 poz., rys., tab., wykr.
Twórcy
autor
  • Chengdu University of Technology
autor
  • Chengdu University of Technology
Bibliografia
  • BRAGA, A., MOREIRA, S.P., ZAMPIERI, P.R., BACCHIN, J., MEI, P.R., 2008. New processes for the production of solar-grade polycrystalline silicon: A review. Solar Energy Materials and Solar Cells, 92(4), 418-424.
  • CHU, T.L., CHU, S.S., STOKES, E.D., 1980. Large grain silicon films on metallurgical silicon substrates for photovoltaic applications. Solar Energy Materials, 2(2), 265-275.
  • COMPAAN, A. D., 2006. Photovoltaics: Clean power for the 21st century. Solar Energy Materials & Solar Cells, 90(15), 2170-2180.
  • EBRAHIMFAR, F., 2019. Purification of Metallurgical-Grade Silicon by Acid Leaching. Silicon, 11(4), 1979-1987.
  • HOPKINS, R.H., ROHATGI, A., 1986. Impurity effects in silicon for high-efficiency solar cells. Journal of Crystal Growth, 75(1), 67-79.
  • JUNEJA, J. M., MUKHERJEE, T. K., 1986. A study of the purification of metallurgical grade silicon. Hydrometallurgy, 16(1), 69-75.
  • JUNG, H.R., SHIN, S.W., SURYAWANSHI, M., YEO, S. J., YUN, J.H., MOON, J. H., KIM, J.H., 2017. Phase evolution pathways of kesterite Cu2ZnSnS4 and Cu2ZnSnSe4 thin films during the annealing of sputtered Cu-Sn-Zn metallic precursors. Solar Energy, 145, 2-12.
  • MA, X., JIAN, Z., WANG, T., LI, T., 2009. Hydrometallurgical purification of metallurgical grade silicon. Rare Metals, 28(3), 5.
  • MARGARIDO, F., BASTOS, M.H., FIGUEIREDO, M.O., MARTINS, J.P., 1994. The structural effect on the kinetics of acid leaching refining of Fe-Si alloys. Materials Chemistry & Physics, 38(4), 342-347.
  • NORMAN, C.E, ABSI, E.M, THOMAS, R.E., 1984. Solar grade Si substrates by the powder-to-ribbon process. Conf. Rec. IEEE Photovoltaic Spec. Conf.; (United States), 63, 859.
  • RUI, Z., WANG, Y., ZHANG, J., XU, J., LI, H., CHEN, X., XING, W.D., 2012. Hydrometallurgical Purification of Metallurgy Grade Silicon by Acid Leaching. Advanced Materials Research, 549, 428-431.
  • SAKATA, T., MIKI, T., MORITA, K., 2002. Removal of iron and titanium in poly-crystalline silicon by acid leaching. Nippon Kinzoku Gakkaishi/Journal of the Japan Institute of Metals, 66(5), 459-465.
  • SANTOS, I., GONCALVES, A., SANTOS, C.S., ALMEIDA, M., AFONSO, M., CRUZ, M.J., 1990. Purification of metallurgical grade silicon by acid leaching. Hydrometallurgy, 23(2-3), 237-246.
  • SARTI, D., & EINHAUS, R., 2002. Silicon feedstock for the multi-crystalline photovoltaic industry. Solar Energy Materials & Solar Cells, 72(1-4), 27-40.
  • SWANSON, R. M. (2004). A vision for crystalline silicon solar cells. 14(5), 443.
  • WANG, Y., SHENG, Y., XIAO, C., HE, X., WANG, J., 1995. Theoretical analysis and technology optimization for hydrometallurgical purification of silicon material. Acta ENergiae Solaris Sinica, 16(2), 174-180.
  • YIN, S., & HE, X.-M. (2002). Solar-grade silicon material is prepared by combining cold plasma with hydrometallurgy. Journal of Functional Materials, 33(3), 305-306.
  • YOSHIKAWA, K., KAWASAKI, H., YOSHIDA, W., IRIE, T., KONISHI, K., NAKANO, K., UTO, T., ADACHI, D, KANEMATSU, M., UZU, H., YAMAMOTO, K., 2017.. Nature Energy, 2, 17032.
  • ZHAN-LIANG, Y.U., WEN-HUI, M.A., DAI, Y.N., YANG, B., WANG, J.X., 2007. Removal of iron and aluminum impurities from metallurgical grade-silicon with hydrometallurgical route. Transactions of Nonferrous Metals Society of China, 17, 1030-1033.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c8a914a4-3b96-4983-8342-24a3ac1d6d1e
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