SCMNPs@Uridine/Zn: An efficient and reusable heterogeneous nanocatalyst for the rapid one-pot synthesis of tricyclic fused pyrazolopyranopyrimidine and 3-methyl carboxylate substituted pyrano[2,3-c]pyrazole derivatives under solvent-free conditions

• Autorzy: Wei Jia , Gui Wenjun , Cui Yanjun , Zhang Zhifang , Yousif Qahtan A.

Identyfikatory

DOI

10.2478/pjct-2020-0013

• Języki publikacji: EN

Abstrakty

EN

SCMNPs@Uridine/Zn is utilized as an environmental-friendly and efficient heterogeneous nanocatalyst for two one-pot four-component condensation reactions, containing hydrazine hydrate, arylaldehyde, ethyl acetoacetate, and barbituric acid to yield tricyclic fused pyrazolopyranopyrimidine derivatives (5a-q), and hydrazine hydrate, arylaldehyde, malononitrile, and dimethyl acetylenedicarboxylate/diethyl acetylenedicarboxylate to yield 3-methyl carboxylate substituted pyrano[2,3-c]pyrazole derivatives (8a-y) under solvent-free conditions with high to excellent yields. The main advantages of this process are easy work-up, short reaction times, no chromatographic purifications, and recyclability of the catalyst for a minimum of six runs without any signifcant decrease in yields of the products. Also, the prepared catalyst SCMNPs@Uridine/Zn was synthesized and fully characterized by various techniques including Fourier transform infrared spectroscopy (FT-IR), energy dispersive X-ray (EDX), thermogravimetric analysis (TGA), X-ray diffraction (XRD), vibrating sample magnetometer (VSM) and Raman spectroscopy.

Słowa kluczowe

EN

nanocatalyst; synthesis of tricyclic; carboxylate; efficient heterogeneous

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2020
• Tom: Vol. 22, nr 2
• Strony: 20--33
• Opis fizyczny: Bibliogr. 47 poz., rys., tab.

Twórcy

autor

Wei Jia

• Gansu Agricultural University, Institute of Agricultural Resources Chemistry and Application, College of Science, Gansu Province, 730000, China

autor

Gui Wenjun

• Gansu Agricultural University, Institute of Agricultural Resources Chemistry and Application, College of Science, Gansu Province, 730000, China

autor

Cui Yanjun

• Gansu Agricultural University, Institute of Agricultural Resources Chemistry and Application, College of Science, Gansu Province, 730000, China

autor

Zhang Zhifang

• Gansu Agricultural University, Institute of Agricultural Resources Chemistry and Application, College of Science, Gansu Province, 730000, China

autor

Yousif Qahtan A.

• University of Al-Qadisiyah, College of Science, Department of Chemistry, Republic of Iraq

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).