Hydrothermal Carbonization Kinetics of Lignocellulosic Municipal Solid Waste

• Autorzy: Putra Herlian Eriska , Djaenudin Djaenudin , Damanhuri Enri , Dewi Kania , Pasek Ari Darmawan

Identyfikatory

DOI

10.12911/22998993/132659

• Języki publikacji: EN

Abstrakty

EN

Hydrothermal carbonization (HTC) is known as a thermochemical converting of wet biomass into a coal-like solid fuel (hydrochar). Hydrochar is easily crumbled. Because of hydrophobic properties, hydrochar is difficult to degrade by microorganisms. It has a calorific value comparable to lignite coal. In this study, hydrochar was made via converting the organic fraction of municipal solid waste through HTC at 190, 210, and 230°C for 30 min with feed to water ratio (FWR) 0.1, 0.2, 0.3. The feedstock processed includes food waste, paper, and wood waste, represented as a pseudo-component of the organic fraction of MSW. The high heating value (HHV), FTIR, as well as proximate and ultimate analyses were applied both to feedstock and hydrochar. The results showed that the energy density of hydrochar was elevated with increasing HTC temperature. The energy densification ratio and heating value increased by approximately 1.0–1.32 and 30%, respectively compared to raw feedstock. The lower yields of hydrochar were obtained at higher temperature. The typical char yields for lignocellulosic material range between 62–63 wt% at 190 °C and reduce to 54–57 wt% at 230 °C. Furthermore, a preliminary study of kinetic model for lignocellulose decomposition was conducted. This model was based on the mass loss rate of the lignocellulose compound in HTC of MSW. Three first-order reactions were given to illustrate the hydrochar yield at of 190, 210, and 230°C. The activation energy of lignocellulose decomposition was 76.26 kJ/mol, 51.86 kJ/mol, 12,23 kJ/mol for lignin, cellulose, and hemicellulose decomposition, respectively.

Słowa kluczowe

EN

activation energy; hydrothermal carbonization; lignocellulose; MSW; municipal solid waste

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2021
• Tom: Vol. 22, nr 3
• Strony: 188--198
• Opis fizyczny: Bibliogr. 32 poz., rys., tab.

Twórcy

autor

Putra Herlian Eriska

• Research Unit for Clean Technology, Indonesian Institute of Sciences, Jl. Cisitu Sangkuriang No. 21 D Bandung 40135, Indonesia

• https://orcid.org/0000-0001-9659-0938

autor

Djaenudin Djaenudin

• Research Unit for Clean Technology, Indonesian Institute of Sciences, Jl. Cisitu Sangkuriang No. 21 D Bandung 40135, Indonesia

autor

Damanhuri Enri

• Faculty of Civil and Environmental Engineering, Bandung Institute of Technology, Jl. Ganesha No. 10 Bandung 40132, Indonesia

autor

Dewi Kania

• Faculty of Civil and Environmental Engineering, Bandung Institute of Technology, Jl. Ganesha No. 10 Bandung 40132, Indonesia

autor

Pasek Ari Darmawan

• Faculty of Mechanical and Aerospace Engineering, Bandung Institute of Technology, Jl. Ganesha No. 10 Bandung 40132, Indonesia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).