The effect of anodic polarization of 304 stainless steel in choline chloride-based DES solvent on its surface morphology and corrosion resistance

• Autorzy: Marczewski Marek , Tylus Włodzimierz , Winiarska Juliusz

Identyfikatory

DOI

10.15199/40.2024.4.2

Warianty tytułu

PL

Wpływ polaryzacji anodowej stali nierdzewnej 304 w rozpuszczalniku DES na bazie chlorku choliny na morfologię powierzchni i odporność na korozję

• Języki publikacji: EN

Abstrakty

EN

AISI 304 alloy steel was polarized anodically in a deep eutectic solvent based on choline chloride and oxalic acid (1 : 1 molar ratio) at the temperature range of 25–75°C and the current density range of 2.5–45 mA cm−2. No improvement in visual parameters (gloss) was observed with increasing temperature. That was due to the formation of numerous pits on the surface as evidenced by SEM microscopy. AFM showed at lower temperatures the evenly distributed shallow pits, while at higher temperatures – less numerous but larger ones. XPS and ICP-AES analysis showed that the anodic polarization process increased the content of oxidized chromium on the surface and indicated high degree of iron leaching from the material. Morphology of this passive layer, which thickness was calculated to 3.3 nm, was characterized by uniform mixture of Cr(III) oxide and hydroxide. In contrast to chemically etched steel, polarization in DES produced surface layer enriched with Cr2O3 (56% instead of 28% total share) with lower share of Cr(OH)3 (41% instead of 70% total share). Anodic polarization process in proposed DES was responsible for a slight increase in corrosion resistance of 304 steel.

PL

Stal stopową AISI 304 poddano polaryzacji anodowej w rozpuszczalniku eutektycznym złożonym z chlorku choliny i kwasu szczawiowego (1 : 1 molowo) w temperaturze 25–75°C i przy gęstości prądu 2,5– 45 mA cm−2. Nie zaobserwowano poprawy połysku wraz ze wzrostem temperatury procesu ze względu na powstanie licznych wżerów na powierzchni, widocznych za pomocą mikroskopii SEM. Analiza AFM wykazała, że w niższych temperaturach wżery są płytkie i równomiernie rozmieszczone, a w wyższych są większe i mniej liczne. Analizy XPS i ICP-AES ujawniły, że na skutek polaryzacji anodowej wzrasta ilość utlenionego chromu w powierzchni stali, czemu towarzyszy nadmierne roztwarzanie żelaza ze stopu. Morfologia wytworzonej warstwy pasywnej, o grubości około 3,3 nm, to jednorodna mieszanina tlenku i wodorotlenku Cr(III). W porównaniu z trawioną chemicznie stalą polaryzacja anodowa w DES skutkuje wytworzeniem warstwy powierzchniowej wzbogaconej w Cr2O3 (56% zamiast 28% zawartości) i z mniejszym udziałem Cr(OH)3 (41% zamiast 70%). Proces polaryzacji anodowej stali 304 w zaproponowanym DES przyczynił się do poprawy odporności na korozję.

Słowa kluczowe

EN

stainless steel; electropolishing; anodic polarization; deep eutectic solvents (DES); passive layer; XPS; EIS; SEM; AFM

PL

stal nierdzewna; polerowanie elektrochemiczne; polaryzacja anodowa; rozpuszczalniki eutektyczne; warstwa pasywna; XPS; EIS; SEM; AFM

• Wydawca: Wydawnictwo SIGMA-NOT
• Czasopismo: Ochrona przed Korozją
• Rocznik: 2024
• Tom: nr 4
• Strony: 96--105
• Opis fizyczny: Bibliogr. 30 poz., rys., tab., wykr.

Twórcy

autor

Marczewski Marek

• Group of Surface Technology, Department of Advanced Material Technologies, Faculty of Chemistry, Wrocław University of Science and Technology, Wrocław, Poland

• https://orcid.org/0000-0002-2728-5363

autor

Tylus Włodzimierz

• Group of Surface Technology, Department of Advanced Material Technologies, Faculty of Chemistry, Wrocław University of Science and Technology, Wrocław, Poland

• https://orcid.org/0000-0001-6780-5100+

autor

Winiarska Juliusz

• Group of Surface Technology, Department of Advanced Material Technologies, Faculty of Chemistry, Wrocław University of Science and Technology, Wrocław, Poland

• https://orcid.org/0000-0003-0761-1579

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