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Photocatalytic, Sonolytic and Sonophotocatalytic Degradation of 4-Chloro-2-Nitro Phenol

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Języki publikacji
EN
Abstrakty
EN
The photocatalytic, sonolytic and sonophotocatalytic degradation of 4-chloro-2-nitrophenol (4C2NP) using heterogeneous (TiO2) was investigated in this study. Experiments were performed in slurry mode with artificial UV 125 watt medium pressure mercury lamp coupled with ultrasound (100 W, 33+3 KHz) for sonication of the slurry. The degradation of compound was studied in terms of first order kinetics. The catalyst concentration was optimized at 1.5 gL-1, pH at 7 and oxidant concentration at 1.5 gL-1. The results obtained were quite appreciable as 80% degradation was obtained for photocatalytic treatment in 120 minutes whereas, ultrasound imparting synergistic effect as degradation achieved 96% increase in 90 minutes during sonophotocatalysis. The degradation follows the trend sonophotocatalysis > photocatalysis > sonocatalytic > sonolysis. The results of sonophotocatalytic degradation of pharmaceutical compound showed that it could be used as efficient and environmentally friendly technique for the complete degradation of recalcitrant organic pollutants which will increase the chances for the reuse of wastewater.
Rocznik
Strony
17--28
Opis fizyczny
Bibliogr. 26 poz., wykr.
Twórcy
autor
  • Department of Biotech. & Environmental Sciences Thapar University, Patiala-147004 Punjab, India
autor
  • Department of Biotech. & Environmental Sciences Thapar University, Patiala-147004 Punjab, India
autor
  • Department of Biotech. & Environmental Sciences Thapar University, Patiala-147004 Punjab, India
Bibliografia
  • [1] Agrawal, A., Pandey R.S., & Sharma, B. (2010). Water Pollution with Special Reference to Pesticide Contamination in India, Journal of Water Resource and Protection, 2 (5), 432-448.
  • [2] Andreozzi, R., Caprio, V., Insola, A., & Marotta, R. (1999). Advanced oxidation processes for water purification and recovery, Catalysis Today, 53 (1), 51-59.
  • [3] APHA Standard Methods for the Examination of Water and Wastewater (1989). New York: American Water Works Association, Standard method no. 5220 C 5-14.
  • [4] Berberidou, C., Poulios, I. Xekoukoulotakis, N.P., & Mantzavinos, D. (2007). Sonolytic, photocatalytic and Sonophotocatalytic degradation of malachite green in aqueous solutions, Applied catalysis B:Environmental, 74, 63-72.
  • [5] Dubey, S.K., Srivastava, P., Verma, A., & Rajor, A. (2009). Solar photocatalytic treatment of textile wastewater for biodegradability enhancement, International Journal of Environmental Engineering, 1 (2), 152-164.
  • [6] Evgenidou, E., Fytianos, K., & Poulios, I. (2005). Photocatalytic oxidation of dimethoate in aqueous solutions, Journal of Photochemistry and Photobiology A: Chem., 175, 29-38.
  • [7] Gharbani, P., Khosravi, M., Tabatabaii, S.M., Zare, K., Dastmalchi, S., & Mehrizad A. (2010). Degradation of trace aqueous 4-chloro-2-nitrophenol occurring in pharmaceutical industrial wastewater by ozone, International Journal of Environmental Science and Technology, 7 (2), 377-384.
  • [8] Gogate, P.R. (2008). Treatment of wastewater streams containing phenolic compounds using hybrid techniques based on cavitation: A review of the current status and the way forward, UltrasonicsSonochemistry, 15 (1), 1-15.
  • [9] González, A.S., & Martínez, S.S. (2008). Study of the sonophotocatalytic degradation of basic blue 9 industrial textile dye over slurry titanium dioxide and influencing factors, Ultrasonics Sonochemistry, 15 (6), 1038-1042.
  • [10] Ikehata, K., Naghashkar, N.J., & El-Din, M.G. (2006). Degradation of Aqueous Pharmaceuticals by Ozonation and Advanced Oxidation Processes: A Review, Ozone: Science and Engineering, 28 (6), 353-414.
  • [11] Kavitha, S.K., & Palanisamy, P.N. (2011). Photocatalytic and sonophotocatalytic degradation of reactive red 120 using dye sensitized TiO2 under visible light, World Academy of Science, Engineering andTechnology, 73, 1-6
  • [12] Kolpin, D.W., Furlong, E.T., Meyer, M.T., Thurman, E.M., Zaugg, S.D., Barber, B., & Buxton, H.T. (2002). Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, a national reconnaissance, Environment Science and Technology, 36 (6), 202-211.
  • [13] Konstantinou, I.K., & Albanis, T.A. (2003). Photocatalytic transformation of pesticides in aqueous titanium dioxide suspensions using artificial and solar light: intermediates and degradation pathways, Applied Catalysis B: Environmental, 42 (4), 319-335.
  • [14] Madhavan, J., Grieser, F., & Ashokkumar, M. (2010). Combined advanced oxidation processes for the synergistic degradation of ibuprofen in aqueous environments, Journal of Hazardous Materials, 178 (1-3), 202-208.
  • [15] Méndez-Arriaga, F., Torres-Palma, R.A., Pétrier, C., Esplugas, S., Gimenez, J., & Pulgarin, C. (2008). Ultrasonic treatment of water contaminated with ibuprofen. Water Research, 42 (16), 4243-4248.
  • [16] Mohajerani, M., Mehrvar, M., & Ein-Mozaffari, F. (2009). An overview of the integration of advanced oxidation technologies and other processes for water and wastewater treatment, International Journal ofEngineering, 3 (2), 120.
  • [17] Polar, J.A. (2007). The fate of pharmaceuticals after wastewater treatment, Florida water resourcesjournal, 26-31.
  • [18] Selli, E. (2002). Synergistic effects of sonolysis combined with photocatalysis in the degradation of an azo dye, The Royal Society of Chemistry and Owner Societies, 4 (24), 6123-6128.
  • [19] Silva, A.M.T., Nouli, E., Carmo-Apolinário, Â.C., Xekoukoulotakis, N.P. & Mantzavinos, D. (2007). Sonophotocatalytic/H2O2 degradation of phenolic compounds in agro-industrial effluents, CatalysisToday, 124 (3-4), 232-239.
  • [20] Singh, H.K, Muneer, M., & Bahnemann, D. (2003). Photocatalysed degradation of a Herbicide derivative, bromacil, in aqueous suspensions of titanium dioxide, Photochemistry Photobiology Science, 2, 151-156.
  • [21] Suzuki, Y., Waristo, Arakawa, H., Maezawa, A., & Uchida, S. (1999). Ultrasonic enhancement of photo-catalytic oxidation of surfactant, International Journal of Photoenergy, 1 (1), 60-64.
  • [22] Taghizadeh, M.T., & Abdollahi, R. (2011). Sonolytic, sonocatalytic and sonophotocatalytic degradation of chitosan in the presence of TiO2 nanoparticles. Ultrasonic Sonochemistry, 18 (1), 149-157.
  • [23] Toor, A.P., Verma, A., Singh, V., Jotshi, C.K., & Bajpai, P. K. (2005). Photocatalytic Degradation of 3,4 Dichlorophenol using TiO2 in a shallow pond slurry reactor, Indian Journal of Chemical Technology, 12, 75-81.
  • [24] Toor, A.P., Verma, A., Singh, V., Jotshi C.K., & Bajpai, P. K. (2006). Photocatalytic degradation of Direct Yellow 12 dye using UV/TiO2 in a shallow pond slurry reactor, Dyes and Pigments, 68 (1), 53-60.
  • [25] Toor, A.P., Verma, A., Singh, V., Jotshi, C.K. & Bajpai, P.K. (2007). Treatment of bleaching effluents from the pulp and paper industry by photocatalytic oxidation, Tappi Journal, 6, 9-13.
  • [26] Verma, R. (2006). PharmaceuticalWaste/ScrapManagement, http://www.pharmatutor.org/articles/pharmaceutical-wate-management,23/3/2012.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-c5b0dd52-c1e1-4787-bf2e-a678c5be2dc2
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